Patents Represented by Attorney M. D. Bittman
  • Patent number: 4743708
    Abstract: A process for separating a C.sub.10 aromatic isomer, particularly paradiethylbenzene, from a feedstream containing a mixture of C.sub.10 aromatic isomers by contacting the feedstream with a bed of the adsorbent zeolite beta. The adsorbed C.sub.10 aromatic isomer is removed from the adsorbent by desorption.
    Type: Grant
    Filed: March 24, 1986
    Date of Patent: May 10, 1988
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Daniel D. Rosenfeld, Lawrence G. Daniel
  • Patent number: 4701315
    Abstract: A zeolite related to zeolite L and having a characteristic cylindrical morphology may be prepared from a crystallization gel comprising (in mole ratios of oxides):K.sub.2 O/SiO.sub.2 --0.22-0.36H.sub.2 O/K.sub.2 O--25-90SiO.sub.2 /Al.sub.2 O.sub.3 --6-15and preferably with the mole ratio H.sub.2 O/K.sub.2 O+Al.sub.2 O.sub.3 +SiO.sub.2 being at least 8. The cylindrical Zeolite L may be used as a catalyst base in aromatization of acyclic hydrocarbons with high benzene yields being sustained over commerically feasible periods.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: October 20, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventor: Theodorus M. Wortel
  • Patent number: 4686048
    Abstract: A process is disclosed for treating cat cracker bottoms sludge to remove the cat cracker bottoms hydrocarbons from the catalyst fines in the sludge to provide treated fines which are environmentally safe for landfill. The process involves mixing the sludge with a hydrocarbon diluent, separating the fines from the diluent-sludge mixture, then mixing the separated fines and remaining diluent with water and distilling off the remaining diluent to obtain the treated fines.
    Type: Grant
    Filed: December 23, 1981
    Date of Patent: August 11, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventors: George A. Atherton, Ghazi B. Dickakian, Edward D. Grant, Jr.
  • Patent number: 4655796
    Abstract: The sorption process involves combining a simulated countercurrent flow system with a stationary magnetically stabilized fluidized bed to achieve continuous adsorption-desorption to separate components of a feedstream.
    Type: Grant
    Filed: September 30, 1983
    Date of Patent: April 7, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventor: James C. Pirkle, Jr.
  • Patent number: 4594145
    Abstract: A process for reforming a full boiling range naptha feed to enhance benzene yield is disclosed which first separates the feed into a C.sub.6 fraction containing at least 10% by volume of C.sub.7 + hydrocarbons and a C.sub.7 + fraction, then subjecting the C.sub.6 fraction to a catalytic aromatization process and subjecting the C.sub.7 + fraction to a catalytic reforming process, followed by recovering the aromatics produced.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: June 10, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventor: John C. Roarty
  • Patent number: 4593133
    Abstract: A zeolite related to zeolite L and having a characteristic cylindrical morphology may be prepared from a crystallization gel comprising (in mole ratios of oxides):K.sub.2 O/SiO.sub.2 : 0.22-0.36H.sub.2 O/K.sub.2 O: 25-90SiO.sub.2 /Al.sub.2 O.sub.3 : 6-15and preferably with the mole ratio H.sub.2 O/K.sub.2 O+Al.sub.2 O.sub.3 +SiO.sub.2 being at least 8. The cylindrical Zeolite L may be used as a catalyst base in aromatization of acyclic hydrocarbons with high benzene yields being sustained over commercially feasible periods.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: June 3, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventor: Theodorus M. Wortel
  • Patent number: 4578372
    Abstract: There is disclosed a process for preparing magnetizable particles comprising Zeolite Y wherein magnetizable particles are introduced into a vessel containing the reaction mixture used to form Zeolite Y and, during heating, the vessel is rotated so that the Zeolite Y is formed as a layer on the surface of the magnetizable particles.
    Type: Grant
    Filed: December 19, 1984
    Date of Patent: March 25, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Klaas Hoving, Johannes W. M. Walterbos
  • Patent number: 4568656
    Abstract: A process is provided for loading and uniformly distributing platinum onto a Zeolite-L. The Zeolite-L is contacted with an aqueous solution containing a platinum salt and a non-platinum metal salt, wherein the non-platinum metal salt is present in solution in an amount which is critical to preventing the formation of acid sites as well as avoiding an excess of metal ions in the form of a salt which could block the pores of the Zeolite-L. The Zeolite-L is then aged to allow the platinum to migrate and uniformly distribute throughout the Zeolite.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: February 4, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Kenneth R. Poeppelmeier, Theodore D. Trowbridge, Jar-Lin Kao
  • Patent number: 4554398
    Abstract: A process for separating a C.sub.9 aromatic isomer from a feed stream containing a mixture of C.sub.9 aromatic isomers by contacting the feed stream with a bed of the adsorbent zeolite beta. The adsorbed C.sub.9 aromatic isomer is removed from the adsorbent by desorption.
    Type: Grant
    Filed: October 29, 1984
    Date of Patent: November 19, 1985
    Assignee: Exxon Research & Engineering Co.
    Inventors: Denise M. Barthomeuf, Daniel D. Rosenfeld
  • Patent number: 4482774
    Abstract: Hydrocarbon conversion processes which use catalyst compositions comprising a core of silica with an overlying modified-silica zeolite, preferably containing aluminium, gallium or boron, show improved catalytic activity. The composites are prepared by introducing preformed silica particles, preferably with a crystallite size greater than 0.1.mu., into a reaction mixture comprising a silicon source, a source of the modifying element, and preferably an organic template such as a tetraalkylammonium compound to form the modified-silica zeolite with a constraint index of from 1 to 12. The weight ratio of the silica core to SiO.sub.2 in the reaction mixture is preferably 1:1 to 10:1.
    Type: Grant
    Filed: November 21, 1983
    Date of Patent: November 13, 1984
    Assignee: Exxon Research & Engineering Co.
    Inventor: Wicher T. Koetsier
  • Patent number: 4431521
    Abstract: A process is disclosed for improving the recovery of benzene from a reforming process by adding to the reformer effluent a heavy oil, then recovering the benzene in a flash drum.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: February 14, 1984
    Assignee: Exxon Research & Engineering Co.
    Inventors: John C. Roarty, Malcolm L. Campbell
  • Patent number: 4107344
    Abstract: A method of producing dehydrated rice flakes wherein dehydration of an aqueous slurry of substantially completely gelatinized rice starch granules and gelatinization and dehydration of a minor proportion of admixed ungelatinized rice starch granules is concurrently effected with a drum dryer. The dried sheet of substantially completely gelatinized rice material from the dryer is then subdivided into flakes or small platelets which require only the addition of hot water to quickly rehydrate to form a cooked rice product having the appearance and textural quality approaching that of freshly cooked mashed potatoes.
    Type: Grant
    Filed: May 26, 1976
    Date of Patent: August 15, 1978
    Assignee: General Foods Limited
    Inventors: George H. Beston, Donald W. Kirk
  • Patent number: RE33323
    Abstract: A process for reforming a full boiling range naptha feed to enhance benzene yield is disclosed which first separates the feed into a .[.C.sub.6 .]. .Iadd.lighter .Iaddend.fraction .[.containing at least 10% by volume of C.sub.7+ hydrocarbons.]. .Iadd., comprising at least one member selected from the group consisting of C.sub.6, C.sub.7, and C.sub.8 hydrocarbons, .Iaddend.and a .[.C.sub.7 +.]. .Iadd.heavier .Iaddend.fraction, then subjecting the .[.C.sub.6 .]. .Iadd.lighter .Iaddend.fraction to a catalytic aromatization process .[.and subjecting the C.sub.7 + fraction to a catalytic reforming process, followed by recovering the aromatics produced.]..Iadd.in the presence of a non-acidic catalyst.Iaddend..
    Type: Grant
    Filed: June 10, 1988
    Date of Patent: September 4, 1990
    Assignee: Exxon Research & Engineering Company
    Inventors: John C. Roarty, Murray Nadler