Patents Represented by Attorney M. L. Gibbons
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Patent number: 5386864Abstract: A composition suitable for use in producing a tire innerliner is provided. The composition comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene; carbon black, and a plasticizer oil. A vulcanized tire comprising an innerliner made from the composition is also provided.Type: GrantFiled: April 26, 1994Date of Patent: February 7, 1995Assignee: Exxon Chemical Patents Inc.Inventors: Bernard J. Costemalle, James V. Fusco
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Patent number: 5356950Abstract: A grafted polymer of an isomonoolefin and an alkylstyrene, such as a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene, is provided. Processes for preparing the grafted polymer are also provided.Type: GrantFiled: April 26, 1993Date of Patent: October 18, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Donald A. White, Hsien C. Wang
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Patent number: 5333662Abstract: A composition suitable for use in producing a tire innerliner is provided. The composition comprises a halogencontaining copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a paraalkylstyrene; carbon black, and a plasticizer oil. A vulcanized tire comprising an innerliner made from the composition is also provided.Type: GrantFiled: July 21, 1992Date of Patent: August 2, 1994Assignee: Exxon Chemical Patents Inc.Inventors: Bernard J. Costemalle, James V. Fusco
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Patent number: 5332787Abstract: A process is provided for vulcanizing a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene utilizing a vulcanization mixture comprising a basic zinc carbonate hydroxide.Type: GrantFiled: November 30, 1992Date of Patent: July 26, 1994Assignee: Exxon Chemical Patents Inc.Inventor: Irwin J. Gardner
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Patent number: 5246778Abstract: A hose composition is provided which comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene, fillers, rubber compounding additives and a curing agent. A hose comprising at least a portion made from this hose composition is also provided.Type: GrantFiled: August 17, 1992Date of Patent: September 21, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Bernard J. Costemalle, Robert C. Keller, Donald F. Kruse, James V. Fusco, Marcel A. Steurs
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Patent number: 5244961Abstract: A non-vulcanized thermoplastic composition comprising a polyamide and an elastomeric halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene is prepared by blending the polyamide and elastomeric copolymer in the presence of specified metal compounds in an amount insufficient for vulcanizing the composition. Optionally, the resulting composition may be subjected to vulcanization.Type: GrantFiled: September 19, 1991Date of Patent: September 14, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Thomas C. Yu, Hsien C. Wang, Kenneth W. Powers
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Patent number: 5238990Abstract: A thermoplastic composition is provided which comprises a polyamide, a grafted polymer of an isomonoolefin and an alkylstyrene, such as a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene, and optionally a polyolefin polymer.Type: GrantFiled: June 5, 1991Date of Patent: August 24, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Thomas C. Yu, Donald A. White, Hsien C. Wang
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Patent number: 5200469Abstract: A crosslinked, unsaturated elastomeric polymer of a C.sub.4 to C.sub.7 isomonoolefin and a C.sub.4 to C.sub.14 conjugated multiolefin is produced by curing the corresponding uncrosslinked polymer having a low level of chemically bound halogen with a curing agent which reacts only with the halogen (e.g., zinc oxide) in combination with a bifunctional dienophile (e.g., a bismaleimide). The uncrosslinked elastomeric polymer is particularly suitable for use in the pharmaceutical industry, for example, for container closures. Shaped rubbery products comprising the crosslinked copolymer are also provided.Type: GrantFiled: April 18, 1990Date of Patent: April 6, 1993Assignee: Exxon Chemical Patents Inc.Inventor: Pierre Hous
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Patent number: 5191022Abstract: A covulcanizable polymer blend of a highly unsaturated rubbery polymer and a sulfer imide-modified teropolymer of ethylene, a higher alpha olefin and a non-conjugated diene is provided. Processes for preparing the blend and vulcanizing the blend are also provided.Type: GrantFiled: March 9, 1990Date of Patent: March 2, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Donald A. White, Stanley J. Brois, Bruce D. Allison
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Patent number: 5187240Abstract: N-halothiosulfonamide-modified non-rubbery thermoplastic polyolefins are provided. The modified polyolefin products are prepared by reaction of a non-rubbery thermoplastic polyolefin polymer with an N-halothiosulfonamide in the absence or, preferably, in the presence of a catalyst. The preferred catalyst for use in the preparation of these products are salts of weak acids of specified metals.Type: GrantFiled: December 12, 1990Date of Patent: February 16, 1993Assignee: Exxon Chemical Patents Inc.Inventor: Donald A. White
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Patent number: 5182350Abstract: Ozone resistant vulcanizable copolymers of isoolefins with non-conjugated dienes of the general formula: ##STR1## where R.sub.1 is ##STR2## and R.sub.2 is alkyl of 1 to 6 carbon atoms and vulcanizates thereof. The copolymers are prepared by polymerization in the presence of Lewis acids.Type: GrantFiled: October 30, 1990Date of Patent: January 26, 1993Assignee: Exxon Chemical Patents IncInventors: James V. Fusco, Hsien-Chang Wang, Kenneth W. Powers
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Patent number: 5162445Abstract: A copolymer of a C.sub.4 to C.sub.7 isoolefin and a para-alkylstyrene is provided as well as the corresponding halogenated, functionalized and grafted derivatives thereof. Processes for producing these copolymers are also provided.Type: GrantFiled: November 27, 1989Date of Patent: November 10, 1992Assignee: Exxon Chemical Patents Inc.Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C Chung, Anthony J. Dias, Joseph A. Olkusz
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Patent number: 5151467Abstract: N-halothiosulfonamide-modified rubber products are provided. The modified rubber products are prepared by reaction of a rubber, such as a butyl rubber or a halogenated butyl rubber, with a N-halothiosulfonamide in the absence or in the presence of a catalyst.Type: GrantFiled: October 24, 1991Date of Patent: September 29, 1992Assignee: Exxon Chemical Patents Inc.Inventor: Donald A. White
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Patent number: 5102958Abstract: A partially crosslinked, unsaturated elastomeric polymer of a C.sub.4 to C.sub.7 isomonoolefin and a C.sub.4 to C.sub.14 conjugated multiolefin is provided which has a low crosslink density. The partially crosslinked polymer is produced by curing an uncrosslinked unsaturated polymer having a low level of chemically bound halogen with a curing agent which reacts only with the halogen. Processes for preparing these partially crosslinked unsaturated polymers are also provided.Type: GrantFiled: May 30, 1991Date of Patent: April 7, 1992Assignee: Exxon Chemical Patents Inc.Inventors: Pierre Hous, Olivier H. Lacoste, James V. Fusco, Irwin J. Gardner, William M. Davis, Lawrence W. Flatley
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Patent number: 5077345Abstract: A halogenation process is provided for halogenating a polymer, in which process the halogenation reaction product is neutralized by reaction of an aqueous alkaline material in the presence of a critical limited amount of alcohol to increase the neutralization rate.Type: GrantFiled: March 1, 1990Date of Patent: December 31, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Neil F. Newman, Irwin J. Gardner
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Patent number: 5075387Abstract: A partially crosslinked, unsaturated elastomeric polymer of a C.sub.4 to C.sub.7 isomonoolefin and a C.sub.4 to C.sub.14 conjugated multiolefin is provided which has a low crosslink density. The partially crosslinked polymer is produced by curing an uncrosslinked unsaturated polymer having a low level of chemically bound halogen with a curing agent which reacts only with the halogen. Processes for preparing these partially crosslinked unsaturated polymers are also provided.Type: GrantFiled: December 22, 1989Date of Patent: December 24, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Pierre Hous, Olivier H. Lacoste, James V. Fusco, Irwin J. Gardner, William M. Davis, Lawrence W. Flatley
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Patent number: 5070624Abstract: A process for cooling rubber crumb wherein the rubber crumb is presented for cooling to a first stage pneumatic conveyor containing a hot wet first stage air stream. The rubber crumb is cooled in the first stage pneumatic conveyor to a first temperature, whereupon the cooled rubber crumb is separated from the first stage air stream and transferred to a second stage air stream of cool dry air. A second stage pneumatic conveyor transports the rubber crumb in the second stage air stream for additional cooling.Type: GrantFiled: April 20, 1990Date of Patent: December 10, 1991Assignee: Exxon Chemical Patents Inc.Inventors: Gregory M. Vero, Brenton G. Jones, Ronald C. Kowalski
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Patent number: 5063002Abstract: A method for producing particles of polymeric material by extruding hot, sticky material in a plastic state through orifices in a die plate. The extruded plastic material is cut into crumb upon exit from the orifices by a high velocity gas stream, suitably air, and the particles conveyed away from the die face. The air supply is coupled to a cutting chamber for providing the stream of air across the face of the die plate to cut and convey the crumb away from the orifices. The cutting chamber is arranged to include a restricted throat having an exit area in close proximity to the orifices and a further portion for providing an accumulation zone adjacent the orifices, the accumulation zone having a cross-sectional area which increases from the exit area of the throat to a product discharge zone remote from the orifices in a downstream direction.Type: GrantFiled: February 14, 1990Date of Patent: November 5, 1991Assignee: Exxon Chemical Patents Inc.Inventor: Norman E. Luker
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Patent number: 5063268Abstract: A composition suitable for use in producing tire treads, is provided. The composition comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene; a rubber, such as, styrene-butadiene rubber, carbon black, and a plasticizer oil. Tires comprising treads made of the composition are also provided.Type: GrantFiled: June 8, 1990Date of Patent: November 5, 1991Assignee: Exxon Chemical Patents Inc.Inventor: Donald G. Young
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Patent number: 5042169Abstract: An interstage separator for transferring polymeric crumb from a first stage pneumatic conveyor with hot wet air, to a second stage pneumatic conveyor with cool dry air. The interstate separator is characterized by a tangential inlet for the crumb, and an enclosed separating chamber within which the crumb is separated from the first stage air stream. A transition member associated with the separator directs the crumb into a second stage air stream and, then, to a second stage pneumatic conveyor. The interstage separator transfers the rubber crumb from the first stage air stream to the second stage air stream without fouling of the associated equipment.Type: GrantFiled: April 18, 1990Date of Patent: August 27, 1991Assignee: Exxon Chemical Patents Inc.Inventor: Gregory M. Vero