Abstract: A membrane is provided for separating aliphatically unsaturated hydrocarbons from hydrocarbon mixtures, the membrane comprising a hydrophilic polymer which contains metals capable of complexing with aliphatically unsaturated hydrocarbons and a hydrophilic salt of a Group I metal.

Abstract: In accordance with the process of this invention, an improved titanium dioxide rutile-based catalyst for molecular oxidation of a hydrocarbon to form the corresponding carboxylic anhydrides is prepared by the steps of (a) forming a catalyst precursor by depositing on titanium dioxide solids in the rutile form a discontinuous monolayer amount of at least one source of a Group IA metal oxide; (b) calcining the thus-formed catalyst precursor under conditions sufficient to convert the Group IA metal oxide source into the corresponding Group IA metal oxide; (c) depositing upon the calcined catalyst precursor a catalytically effective amount of at least one vanadium oxide source which is convertible into vanadium oxide upon heating; and (d) calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.

Abstract: According to the process of this invention, alcohols are recovered from aqueous acid solution by permeation of the alcohol through a perfluorinated ionomer membrane. An improved process for the manufacture of alcohols by acid absorption of olefins is also disclosed, the improvement residing in the use of a perfluorinated ionomer membrane to selectively permeate alcohols from the concentrated aqueous strong acid solution thereof co-produced in their synthesis from olefins.

Abstract: An improved process for preparing ketones by contacting a secondary aliphatic alcohol in the vapor phase with a trimetallic catalyst containing molybdenum, rhenium and a Group VIII noble metal.

Abstract: In accordance with the process of this invention, an improved catalyst for molecular oxidation of a hydrocarbon to form the corresponding carboxylic anhydrides is prepared by the steps of (a) forming a catalyst precursor by depositing on titanium dioxide solids in the anatase form a discontinuous monolayer amount of at least one source of a Group VIB metal oxide; (b) calcining the thus-formed catalyst precursor under conditions sufficient to convert the Group VIB metal oxide source into the corresponding group VIB metal oxide; (c) depositing upon amount of at least one vanadium oxide source which is calcining the vanadium-deposited solids under conditions sufficient to convert the vanadium compound into vanadium oxide.

Abstract: Shear stable antimisting properties are provided to a wide variety of formulations comprising aqueous liquids through the use of a viscoelastic surfactant which comprises a surfactant compound having a hydrophobic moiety chemically bonded to an ionic, hydrophilic moiety and an electrolyte having a moiety that is capable of associating with the surfactant ion. Optionally, an additional amount of electrolyte can be added to the viscoelastic surfactant to further reduce misting. The viscoelastic surfactant can also be a nonionic surfactant.