Patents Represented by Attorney Marc S. Adler
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Patent number: 5731377Abstract: A polymer blend useful as a binder in an aqueous coating composition containing no coalescent is provided. The polymer blend comprises from about 20 to about 60 weight percent of a hard emulsion polymer, having a glass transition temperature greater than about room temperature, and from about 80 to about 40 weight percent of a soft emulsion polymer, having a glass transition temperature less than about 15 degrees Centigrade.Type: GrantFiled: January 8, 1993Date of Patent: March 24, 1998Assignee: Rohm and Haas CompanyInventor: John Michael Friel
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Patent number: 5663224Abstract: Inorganic material particles are dispersed in an aqueous medium with surface charge adjusting additives to give a moderately stable slurry or pigment grind. The dispersion can be used to prepare fully formulated compositions. Products formulated using the aqueous dispersion can be prepared to give the same performance as products including inorganic material dispersed with conventional polyelectrolyte pigment dispersants, but with higher levels of inorganic material, or superior performance properties with like levels of inorganic material.Type: GrantFiled: December 3, 1991Date of Patent: September 2, 1997Assignee: Rohm and Haas CompanyInventors: William David Emmons, Martin Vogel, Edward C. Kostansek, Jack C. Thibeault, Peter R. Sperry, Chao-Jen Chung
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Patent number: 5380447Abstract: This invention provides a process for preventing dye from depositing onto fabric, and fabric finishing compositions useful in the dye deposition inhibiting process of this invention. Specifically, a process is provided where 1) an aqueous bath is formed comprising a) water, b) dyed fabric, and c) a dye deposition inhibiting agent, 2) the dyed fabric is treated in the aqueous bath and the fabric releases a portion of the dye from the dyed fabric into the bath, and 3) the dye inhibiting agent is maintained in contact with the dyed fabric for the duration of the treating step. The dye deposition inhibiting agent is added to the process as a fabric finishing composition comprised of at least 0.1 wt % dye deposition inhibiting agent.Type: GrantFiled: July 12, 1993Date of Patent: January 10, 1995Assignee: Rohm and Haas CompanyInventors: Thomas C. Kirk, Curtis Schwartz, Barry Weinstein
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Patent number: 5328952Abstract: Multi-stage polymer process and composition having an alkali-insoluble emulsion polymer and an alkali-soluble polymer are produced by a two-stage sequential emulsion polymerization process. When the multi-stage polymers of this invention are utilized as cement modifiers, improvements in cement mortar physical properties are realized.Type: GrantFiled: February 14, 1992Date of Patent: July 12, 1994Assignee: Rohm and Haas CompanyInventors: John G. Brodnyan, Shang-Jaw Chiou, Mark P. de Grandpre
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Patent number: 5214095Abstract: Stable, aqueous emulsion copolymers with controllable siloxane crosslinking functionality are provided. These copolymers are prepared by a concurrent free radical and cationic initiated emulsion polymerization of at least one free radical initiatable monomer at least one linear siloxane precursor monomer, and at least one bifunctional silane monomer having both free radical polymerizable and silicon functional groups. The copolymers are useful in curable coatings, paints, caulks, adhesives, non-woven and ceramic compositions and as modifiers, processing aids and additives in thermoplastics, cements and asphalts.Type: GrantFiled: January 21, 1992Date of Patent: May 25, 1993Assignee: Rohm and Haas CompanyInventor: Alvin C. Lavoie
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Patent number: 5162060Abstract: A coating composition is used for coating or overlaying Portland cement concrete or metal. The composition includes a synthetic polymer latex having ureido functional groups, an amine-functional epoxy curing agent, a liquid epoxy resin, and a hydraulic cement. The coating composition has superior thermal shock resistance and low cost in comparison with epoxy/amine-type polymer concrete, and excellent strength development and chemical resistance in comparison with conventional latex-based cementitious compositions. The coating composition can be mixed from a pair of storage-stable components; a dry mix including the hydraulic cement and the epoxy resin, and optionally larger size aggregate, and a wet mix including the polymer latex and the amine curing agent.Type: GrantFiled: December 14, 1989Date of Patent: November 10, 1992Assignee: Rohm and Haas CompanyInventors: Charles W. Bredow, Frederick J. Schindler
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Patent number: 4888209Abstract: A process is provided for conducting or catalyzing a chemical reaction on a surface by depositing on the surface an adherent monolayer of positively charged polymer particles containing an active agent distributed throughout the polymer and contacting the deposited adherent monolayer with a suitable reactant. The positively charged polymer particles have diameters of less than about 3 micrometers and preferably less than 1 micrometer. The polymer particles are suspended in water to form an aqueous colloidal dispersion. The dispersion is useful as a stable catalyst system and particularly useful for complete electroless deposition of a conductive metal on printed circuit board surfaces and the walls of throughholes formed therein.Type: GrantFiled: December 2, 1987Date of Patent: December 19, 1989Assignee: Rohm and Haas CompanyInventor: James W. Neely
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Patent number: 4886618Abstract: Oxygen scavengers, especially for vinyl polymerizations, comprising an aldehyde or imine of the formulaR.sub.3 Q.sub.nwherein n is 1-4; R.sub.3 is an organic radical having a valence of 1-4 or hydrogen; Q is of the formula ##STR1## wherein A is 0 or NR.sub.4 ; R.sub.2, R.sub.2, and R.sub.4 are independently selected C.sub.1-6 alkyl or aryl radicals or mixtures thereof are disclosed.A preferred composition is a mixture of aldehydes which are the reaction product of (a) ethylene urea, (b) formaldehyde, (c) isobutyraldehyde, and (d) 2-ethylhexanal in a molar ratio of (a):(b) of 1:2 and of (a) to the sum of (c) and (d) of 1:2.Type: GrantFiled: April 4, 1988Date of Patent: December 12, 1989Assignee: Rohm and Haas CompanyInventors: Ronald W. Novak, William D. Emmons
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Patent number: 4886606Abstract: Strong base ion exchange resins derived from crosslinked vinylbvenzyl chloride polymers are particularly suitable for purifying condensate waters for steam regenerating equipment. Preferred embodiments utilize gellular anion exchange resins to remove corrosion products from boiler condensate waters.Type: GrantFiled: June 13, 1988Date of Patent: December 12, 1989Assignee: Rohm and Haas CompanyInventors: David H. Clemens, Marvin J. Hurwitz, Robert W. Walker
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Patent number: 4877818Abstract: The invention is directed to a photosensitive polymer composition capable of being electrophoretically depositable as an adherent, uniform photosensitive film on a conductive surface. The photosensitive polymer composition useful for electrodeposition is formed from an aqueous solution or emulsion of at least one polymer having charged carrier groups, a photoinitiator and a source of unsaturation for crosslinking the resulting film upon exposure to actinic radiation. The photosensitive film formed from the photosensitive polymer composition is aqueous developable and resistant to strong inorganic acids and strong bases. The photosensitive polymer composition is useful in the preparation of printed circuit boards, lithographic printing plates, cathode ray tubes, as well as in chemical milling, solder resist and planarizing layer applications.Type: GrantFiled: January 11, 1988Date of Patent: October 31, 1989Assignee: Rohm and Haas CompanyInventors: William D. Emmons, Mark R. Winkle
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Patent number: 4791151Abstract: Binder, coating, and adhesive compositions having surprising film build, flow, leveling, and adhesive wet tack are provided by an aqueous dispersion comprising polymer particles having a central core surrounded by lobes. Also disclsoed are the uses and process of preparation of these unique particles.Type: GrantFiled: July 14, 1986Date of Patent: December 13, 1988Assignee: Rohm and Haas CompanyInventors: Alexander Kowalski, Joseph Wilczynski, Robert M. Blankenship, Cheun-Shyong Chou
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Patent number: 4732952Abstract: A B stageable thermosettable composition containing at least one polyepoxide and at least one linear anhydride monomer capable of forming a cyclopolymer in situ and processes for the formation of the B stage intermediate and final thermoset having a high service temperature is provided. The composition is useful in a two stage process; first to form a storage stable, flowable thermoplastic B stage intermediate by the free radical initiated vinyl polymerization of the linear anhydride in the liquid composition to a cyclic polymer and secondly to react the cyclic polymer with the poly epoxide to form a crosslinked high service temperature thermoset useful in the preparation of laminates, such as printed circuit boards, adhesives, and encapsulants.Type: GrantFiled: December 5, 1986Date of Patent: March 22, 1988Assignee: Rohm and Haas CompanyInventors: Frederick J. Hirsekorn, William D. Emmons
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Patent number: 4719145Abstract: A process is provided for conducting or catalyzing a chemical reaction on a surface by depositing on the surface an adherent monolayer of positively charged polymer particles containing an active agent distributed throughout the polymer and contacting the deposited adherent monolayer with a suitable reactant. The positively charged polymer particles have diameters of less than about 3 micrometers and preferably less than 1 micrometer. The polymer particles are suspended in water to form an aqueous colloidal dispersion. The dispersion is useful as a stable catalyst system and particularly useful for complete electroless deposition of a conductive metal on printed circuit board surfaces and the walls of through-holes formed therein.Type: GrantFiled: February 21, 1986Date of Patent: January 12, 1988Assignee: Rohm and Haas CompanyInventor: James W. Neely
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Patent number: 4698385Abstract: Compositions suitable as binders for high solids, ambient cure coatings, and coating compositions which have high humidity resistance and good weatherability are disclosed herein.Type: GrantFiled: February 23, 1984Date of Patent: October 6, 1987Assignee: Rohm and Haas CompanyInventor: Frederick J. Schindler
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Patent number: 4678596Abstract: A rinse aid formulation containing a low foam non-ionic surfactant, a low molecular weight poly(meth)acrylic acid and high molecular weight stabilizing polymer is provided. The stabilizing polymer, when at least about 85 percent neutralized, compatibilizes the low foam surfactant with the low molecular weight poly(meth)acrylic acid in water producing a stable, homogeneous aqueous dispersion. The neutralized low molecular weight poly(meth)acrylic acid improves wetting of the substrate by the rinse water and reduces spotting. The stabilizer and poly(meth)acrylic acid do not increase the foam or interfere with the defoaming properties of the surfactant.Type: GrantFiled: May 1, 1986Date of Patent: July 7, 1987Assignee: Rohm and Haas CompanyInventors: Jean Dupre, Andrea C. Keenan
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Patent number: 4652530Abstract: A quantitative, sensitive method for monitoring low concentrations of isothiazolones in aqueous systems is provided. The method involves the adsorption of the isothiazolones on a suitable adsorbent, the desorption of the adsorbed isothiazolones, the breaking of the isothiazolone ring and the formation of a blue complex by the reaction of the broken isothiazolone ring with ferric chloride and potassium ferricyanide. The concentration of the isothiazolones is then determined by conventional colorimetric techniques.Type: GrantFiled: July 15, 1985Date of Patent: March 24, 1987Assignee: Rohm and Haas CompanyInventors: Alan M. Rothman, Charles C. Crabb
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Patent number: 4631249Abstract: This invention relates to negative photoresist systems containing thermally stable polyglutarimide polymers dissolved in suitable solvents. The negative resists are useful for producing high resolution images on surfaces by exposing the resist to a wide range of exposing radiation wavelengths and by subsequently developing the unexposed resist with an organic solvent or an aqueous base developer. The polyglutarimide polymers can be formulated so that they are partially soluble in an aqueous base, compatible with aqueous base soluble photosensitizers, and developable in aqueous base solutions, thereby eliminating the need for the use of any organic solvent.Type: GrantFiled: November 14, 1985Date of Patent: December 23, 1986Assignee: Rohm & Haas CompanyInventor: Palaiyur S. Kalyanaraman
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Patent number: 4611031Abstract: A process is provided for the preparation of a graft copolymer compatibilizer useful at low levels for blending with separately prepared olefin copolymers and polymethacrylate polymers to form a stable, concentrated, polymer blend. The polymer blend, as well as the compatibilizer, are useful lubricating oil additives concentrates which contain at least 80 weight percent polymethacrylate segments. The polymer blend may be further diluted with a hydrocarbon oil to form a lubricating fluid. The polymer blend offers the benefit of the thickening power of olefin copolymers, the low temperature viscosity characteristics of polymethacrylates, and is stable for prolonged periods without phase separation.Type: GrantFiled: January 28, 1985Date of Patent: September 9, 1986Assignee: Rohm and Haas CompanyInventors: Richard A. Galluccio, Chung-Yin Lai, Christian D. Neveu
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Patent number: D334044Type: GrantFiled: July 22, 1991Date of Patent: March 16, 1993Inventor: Michael A. Lopatin
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Patent number: D342882Type: GrantFiled: July 2, 1992Date of Patent: January 4, 1994Assignee: Rohm and Haas CompanyInventors: James J. Mann, Daryl E. Gilbert