Abstract: An apparatus and method for decomposing NH3. A fluid containing NH3 is passed in contact with a tubular membrane that is a homogeneous mixture of a ceramic and a first metal, with the ceramic being selected from one or more of a cerate having the formula of M′Ce1-x M″3-&dgr;, zirconates having the formula M′Zr1-xM″O3-&dgr;, stannates having the formula M′Sn1-xM′O3-&dgr;, where M′ is a group IIA metal, M″ is a dopant metal of one or more of Ca, Y, Yb, In, Nd, Gd or mixtures thereof and &dgr; is a variable depending on the concentration of dopant and is in the range of from 0.001 to 0.5, the first metal is a group VIII or group IB element selected from the group consisting of Pt, Ag, Pd, Fe, Co, Cr, Mn, V, Ni, Au, Cu, Rh, Ru and mixtures thereof. The tubular membrane has a catalytic metal on the side thereof in contact with the fluid containing NH3 which is effective to cause NH3 to decompose to N2 and H2.
Type:
Grant
Filed:
July 25, 2001
Date of Patent:
October 7, 2003
Assignee:
The United States of America as represented by the United
States Department of Energy
Abstract: An apparatus and method for monitoring a process involve development and application of a statistically qualified neuro-analytic (SQNA) model to accurately and reliably identify process change. The development of the SQNA model is accomplished in two stages: deterministic model adaption and stochastic model modification of the deterministic model adaptation. Deterministic model adaption involves formulating an analytic model of the process representing known process characteristics, augmenting the analytic model with a neural network that captures unknown process characteristics, and training the resulting neuro-analytic model by adjusting the neural network weights according to a unique scaled equation error minimization technique. Stochastic model modification involves qualifying any remaining uncertainty in the trained neuro-analytic model by formulating a likelihood function, given an error propagation equation, for computing the probability that the neuro-analytic model generates measured process output.
Type:
Grant
Filed:
November 4, 1998
Date of Patent:
March 5, 2002
Assignee:
The United States of America as represented by the United
States Department of Energy
Inventors:
Richard B. Vilim, Humberto E. Garcia, Frederick W. Chen
Abstract: A method for producing diamonds is provided comprising exposing carbonaceous material to ion irradiation at ambient temperature and pressure.
Type:
Grant
Filed:
November 30, 1999
Date of Patent:
November 13, 2001
Assignee:
The United States of America as represented by the United
States Department of Energy
Inventors:
Tyrone Daulton, Roy Lewis, Lynn Rehn, Marquis Kirk
Abstract: Electrochemical incineration of p-benzoquinone was evaluated as a model for the mineralization of carbon in toxic aromatic compounds. A Ti or Pt anode was coated with a film of the oxides of Ti, Ru, Sn and Sb. This quaternary metal oxide film was stable; elemental analysis of the electrolyzed solution indicated the concentration of these metal ions to be 3 &mgr;g/L or less. The anode showed good reactivity for the electrochemical incineration of benzoquinone. The use of a dissolved salt matrix as the so-called “supporting electrolyte” was eliminated in favor of a solid-state electrolyte sandwiched between the anode and cathode.
Type:
Grant
Filed:
December 8, 1998
Date of Patent:
March 20, 2001
Assignee:
The United States of America as represented by the United
States Department of Energy
Inventors:
Dennis C. Johnson, Linda L. Houk, Jianren Feng
Abstract: A Pipe Overpack Container for transuranic waste storage and shipment. The system consists of a vented pipe component which is positioned in a vented, insulated 55 gallon steel drum. Both the vented pipe component and the insulated drum are capable of being secured to prevent the contents from leaving the vessel. The vented pipe component is constructed of 1/4 inch stainless steel to provide radiation shielding. Thus, allowing shipment having high Americium-241 content. Several Pipe Overpack Containers are then positioned in a type B, Nuclear Regulatory Commission (NRC) approved, container. In the current embodiment, a TRUPACT-II container was employed and a maximum of fourteen Pipe Overpack Containers were placed in the TRUPACT-II. The combination received NRC approval for the shipment and storage of transuranic waste.
Type:
Grant
Filed:
February 12, 1998
Date of Patent:
December 7, 1999
Assignee:
The United States of America as represented by the United States Department of Energy
Inventors:
Richard R. Geinitz, Donald T. Thorp, Michael A. Rivera