Patents Represented by Attorney Mark F. Wachter
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Patent number: 6117488Abstract: This invention provides a method for producing a substantially non-sag liquid mixture coating on a substantially vertical surface by applying a coating having continuously increasing thickness from one edge to another edge of the liquid mixture composed of at least two miscible liquid components and situating the edge at which the surface tension of the coating liquid mixture will be greater, as the more volatile liquid component evaporates, at a higher vertical position than the other edge.Type: GrantFiled: September 25, 1998Date of Patent: September 12, 2000Inventor: Dennis Erickson
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Patent number: 5602276Abstract: A process for preparing N-hydroxyalkylaminomethylphosphonic acid or salts thereof which comprises contacting an alkanolamine, formaldehyde and a dialkyl phosphite in the presence of an alcohol under suitable reaction conditions to produce a reaction mixture, and hydrolyzing the reaction mixture under acidic or basic conditions. In one embodiment, the N-hydroxyalkylaminomethylphosphonic acid or salts thereof is catalytically oxidized to produce an N-phosphonomethylaminocarboxylic acid or salts thereof.Type: GrantFiled: July 1, 1996Date of Patent: February 11, 1997Assignee: Monsanto CompanyInventors: Michael K. Stern, Brian K. Cheng, Jerry R. Ebner, Dennis P. Riley
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Patent number: 5578190Abstract: A process for preparing glyphosate and other secondary amines of related structure in which a precursor primary amine such as aminomethylphosphonic acid is condensed with glyoxylic acid, or a related aldehyde compound, and the condensation product reduced without isolation to produce the desired product.Type: GrantFiled: April 7, 1995Date of Patent: November 26, 1996Assignee: Monsanto CompanyInventors: Thomas E. Rogers, Lowell R. Smith
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Stable emulsion flowable formulation of a 2-chloroacetamide herbicide and an imidazolinone herbicide
Patent number: 5538938Abstract: A composition and a method of preparing the same are provided wherein a 2-chloroacetamide herbicide is mixed with an imidazolinone herbicide to form a stable emulsion flowable formulation.Type: GrantFiled: October 14, 1994Date of Patent: July 23, 1996Assignee: Monsanto CompanyInventor: Charles A. Duckworth -
Patent number: 5492948Abstract: A stabilizer system for the suppression of yellowing in styrenic polymers, consisting essentially of a benzotriazole such as 2-(2'-hydroxy-3',5'-di-tert-amylphenyl)benzotriazole, a hydroxybenzocyanurate such as tris-(3,5-di-tert-butyl-4-hydroxybenzyl)isocyanurate and a condensation product of a N,N'-(2,2,6,6-tetramethylpiperidyl)-alkylenediamine and a 6-amino-2,4-dichloro-1,3,5-s-triazine such as the condensation product of N,N'-(2,2,6,6-tetramethylpiperidyl)hexamethylenediamine and 6-morpholino-2,4-dichloro-1,3,5-s-triazine. Additionally a dialkyl thiodipropionate and a zinc dialkyldithiocarbamate may be included in the stabilizer system.Type: GrantFiled: January 9, 1995Date of Patent: February 20, 1996Assignee: Monsanto CompanyInventors: Moh C. O. Chang, Chuan-Ju Chen, Allen R. Padwa
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Patent number: 5492755Abstract: Disclosed herein are pultruded articles prepared from a reinforcing material and a polyamide matrix made by the process of impregnating a reinforcing material with a polyamide forming reaction mixture and then pultruding the impregnated reinforcing material through a die while polymerizing the polyamide forming reaction mixture to form a polyamide matrix, wherein the temperature of the material being pultruded is at least about at the lower end of the melting range of the polyamide.Type: GrantFiled: August 17, 1994Date of Patent: February 20, 1996Assignee: Monsanto CompanyInventors: Patrick Binse, Christian Campener, Philip Keating
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Patent number: 5482767Abstract: A light-transmitting laminated panel having increased resistance to impact-induced rupture sequentially includes: a) a glass layer, b) an optically clear layer of a plasticized polyvinyl butyral matrix containing discrete particles of crosslinked polyvinyl butyral integrally randomly dispersed throughout the matrix which enhance the impact-resistance of the panel and are visually indistinguishable from the matrix polyvinyl butyral, and c) another glass layer, the laminated panel at a specific pummel adhesion having greater mean break height than that of a laminated panel containing layers a), b) and c) but without the impact-resistance-enhancing particles of crosslinked polyvinyl butyral in layer b). An amount up to 40 weight % of the particles is incorporated into the matrix polyvinyl butyral before preparing the laminated panel.Type: GrantFiled: September 29, 1994Date of Patent: January 9, 1996Assignee: Monsanto CompanyInventors: Aristotelis Karagiannis, Peter D. LaPorte
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Patent number: 5478412Abstract: A plastic sheet, preferably of plasticized partial polyvinyl butyral, for a laminated safety glazing, having means dispersed on its surface, preferably comprising a multiplicity of spaced projections, capable of resisting adhesion to a rigid panel, such as glass, of such a glazing when the sheet is laminated to the panel, the area of the sheet surface without such dispersed means having high affinity for adhesion. The projections physically block adhesion of a dispersed area of the sheet to the panel in that the means on the sheet surface have no or weak interfacial adhesion. The multiplicity of space projections also have low or no affinity for adhesion when in blocking contact with each other or with another plasticized partial polyvinyl butyral surface and thereby increase blocking resistance.Type: GrantFiled: June 7, 1993Date of Patent: December 26, 1995Assignee: Monsanto CompanyInventors: Robert H. M. Simon, Peter H. Farmer
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Patent number: 5455103Abstract: A thermoplastic interlayer, such as of polyvinyl butyral, has a regular pattern of deairing channels formed in each side which are angularly arranged with respect to each other wherein, to avoid moire, the angle of intersection is at least 25 degrees, preferably 90 degrees.Type: GrantFiled: January 24, 1994Date of Patent: October 3, 1995Assignee: Monsanto CompanyInventors: John C. Hoagland, Harold H. Hopfe
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Patent number: 5437916Abstract: Flexible printed circuits comprising cobalt circuitry electrolessly deposited on an activated ink coating prepared by heating a wet ink comprising a polymer, e.g. a vinyl polymer such as polyvinyl chloride or polyvinyl alcohol or an unsaturated polymer such as polybutadiene, and a Group 1B or 8 compound, e.g. palladium dichloride, which is adapted to drying at room temperature to a catalytically inert ink. Selective areas of the ink activated by application of heat or light are catalytic to electroless deposition of cobalt.Type: GrantFiled: July 8, 1994Date of Patent: August 1, 1995Assignee: Monsanto CompanyInventors: Albert W. Morgan, James P. Brozek, James D. Capistran, Michael T. O'Connor, Jr.
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Patent number: 5434232Abstract: A mixed bisimide having the formula: ##STR1## wherein D, A and Z are as defined in the specification, produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid anhydride and a halogenated compound containing an anhydride group and aromatic or bicyclo groups to form a bisamic acid composition and then dehydrating such composition to ring close the end groups. The halogenated end groups (Z) of the mixed bisimide component render the bisimide reaction product of the ring closing reaction flame retardant.Type: GrantFiled: September 26, 1994Date of Patent: July 18, 1995Assignee: Monsanto CompanyInventor: Christian J. Petit
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Patent number: 5427861Abstract: A laminated glazing panel having improved resistance to light exposure comprising: A) a glass sheet; B) an IR reflective or electrically conductive multi-layered coating on the glass sheet which includes a cap layer of Cr.sub.x O.sub.y where X.ltoreq.2 and y.ltoreq.5; and C) a plasticized sheet containing polyvinyl butyral in interfacial contact with the cap layer, such sheet containing one or more carboxylic acid metal salts wherein the metal is predominantly divalent, in amount effective to control the potential level of adhesion of said plasticized sheet to another glass sheet to which it is eventually laminated; such glazing panel when laminated with said another glass sheet exhibiting pummel adhesion, measured on the side of the plasticized sheet contacting component B), of at least 3 after at least 2000 hours exposure in a Fadeometer or Weatherometer.Type: GrantFiled: August 12, 1991Date of Patent: June 27, 1995Assignee: Monsanto CompanyInventor: John J. D'Errico
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Patent number: 5425977Abstract: A thermoplastic interlayer having a first air removal surface which includes a multiplicity of microscopic embossments of substantially identical shape integrally projecting from the plane of one side of the interlayer in a regular pattern and a second air removal surface on the other side of the interlayer which is different from the first air removal surface and includes a multiplicity of microscopic peaks and valleys of varying heights and depths arranged in an irregular, non-linear pattern; the height, R.sub.z, of the embossments and peaks being less than about 75 microns and the distance, S.sub.m, between embossments and peaks being less than about 650 microns. During deairing in forming a safety glazing, the first air removal surface is partially transferred to and imposed on the second air removal surface to provide deair paths of reduced obstruction.Type: GrantFiled: January 18, 1994Date of Patent: June 20, 1995Assignee: Monsanto CompanyInventor: Harold H. Hopfe
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Patent number: 5409774Abstract: Disclosed herein is a composite structure comprising a layer of a gas filled cellular insulation material combined with a layer of impact resistant thermoplastic sheet material wherein an ABS sheet having a substantial number of rubber particles in range of from about 4 to about 10 microns (LR ABS) is interposed between the gas filled cellular material and the thermoplastic sheet.Type: GrantFiled: July 1, 1993Date of Patent: April 25, 1995Assignee: Monsanto CompanyInventors: Craig W. Pehlert, Paul J. Drenzek, Glenn B. Hilton
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Patent number: 5393887Abstract: A mixed bisimide having the formula: ##STR1## wherein D, A and Z are as defined in the specification, produced by reacting a diamine with an ethylenically unsaturated dicarboxylic acid anhydride and a halogenated compound containing an anhydride group and aromatic or bicyclo groups to form a bisamic acid composition and then dehydrating such composition to ring close the end groups. The halogenated end groups (Z) of the mixed bisimide component render the bisimide reaction product of the ring closing reaction flame retardant.Type: GrantFiled: October 4, 1993Date of Patent: February 28, 1995Assignee: Monsanto CompanyInventor: Christian J. Petit
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Patent number: 5374385Abstract: A process for the reactive pultrusion of a reinforcing material and a polyamide matrix wherein a reinforcing material is impregnated with a polyamide forming reaction mixture and then pultruded through a die while the polyamide forming reaction mixture is polymerized to form a polyamide matrix, wherein the temperature of the material being pultruded is at least about at the lower end of the melting range of the polyamide.Type: GrantFiled: November 25, 1992Date of Patent: December 20, 1994Assignee: Monsanto Europe S.A.Inventors: Patrick Binse, Christian Campener, Philip Keating
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Patent number: 5358722Abstract: Ferritin analogs comprising an apoferritin protein shell and a core substantially devoid of ferrihydrite, e.g. of inorganic composition such as aluminum hydroxide or organic composition such as acetaminophen. The protein shell can be removed from ferritin analog to produce spherules having a substantially monomodal nominal diameter between about 45 and 90 Angstroms.Type: GrantFiled: January 25, 1993Date of Patent: October 25, 1994Assignee: Monsanto CompanyInventor: Bruce F. Monzyk
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Patent number: 5356745Abstract: The adhesion between layers of polyester and plasticized polyvinyl butyral is improved by the presence of a surface film of plasma-polymerized chlorosilane (e.g. dichlorosilane) at the interface between the layers.Type: GrantFiled: November 15, 1989Date of Patent: October 18, 1994Assignee: Monsanto CompanyInventors: Francis A. Sliemers, George P. Nance
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Patent number: 5346569Abstract: A process for deairing an interface region by applying on the surface of a plastic sheet a multitude of spaced plastic projections formed of a plastic material different from that of the sheet, assembling the sheet with the spaced projections in face to face contact with at least one rigid panel such as glass, and evacuating air from the interface region between the rigid panel and the plastic sheet through spaces between the projections.Type: GrantFiled: May 17, 1993Date of Patent: September 13, 1994Assignee: Monsanto CompanyInventor: Robert H. M. Simon
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Patent number: 5342653Abstract: A method of producing plasticized partial polyvinyl butyral sheet having a desired level of potential adhesion to glass which comprises: i) providing partial polyvinyl butyral resin having a high affinity for adhesion to glass when in sheet form under laminating conditions of elevated temperature and pressure, ii) mixing the resin with plasticizer to form a heat-shapable formulation, iii) extruding the formulation to form a sheet, and iv) applying a multiplicity of spaced anti-adhesion projections to the surface of the sheet to an extent effective to counteract the high adhesion of the sheet to glass between projections.Type: GrantFiled: June 7, 1993Date of Patent: August 30, 1994Assignee: Monsanto CompanyInventors: Robert H. M. Simon, Peter H. Farmer