Abstract: The invention relates to a process for preparing polyester resins by first reacting a carboxylic acid or its corresponding anhydride with a saturated monohydric alcohol to form the half ester and then reacting the half ester with a polyol.
Abstract: Cold-seal adhesives are disclosed that contain no natural rubber and are capable of forming dry coatings on flexible films which adhere to one another with commercially acceptable packaging strength at room temperature by pressure contact, but also allow such layered substrata to be reeled into rolls and stored for extended periods of time without blocking. The flexible films are usable in forming packages, particularly for comestibles and pharmaceuticals, without need for heat sealing. Such cold-seal adhesives are aqueous dispersions containing 30 to 55 percent of a polyurethane ionomer reaction product, having a T.sub.g of between about -50 to 10.degree. C., of a mixture of (a) a blend of between 0 and 40 percent polyester polyol and between 60 and 100 percent polyether polyol, (b) aliphatic diisocyanate and (c) dimethylol propionic acid and preferably containing 0.05 to 4 percent of grafted amorphous silica.
Abstract: This invention is a preapplied liquid adhesive whose components, when dried and heated, react to form a polymer. Laminates made with the thermoset adhesive withstand exposure to 240.degree. F. (116.degree. C.). The adhesive combines urethane dispersions, carboxyl functional acrylic latices and tertiary amine blocking agent.
Abstract: This invention is the addition of an polyaldimine or polyketimine to the curative component of a two part polyurethane structural adhesive for bonding car, boat and truck parts.
Type:
Grant
Filed:
September 26, 1997
Date of Patent:
September 21, 1999
Assignee:
Ashland Inc.
Inventors:
Randy Allen Johnson, Timothy Allen Tufts
Abstract: This invention is a thermoplastic saturated polyester low profile additive (low profile additive) useful in sheet molding compounds for parts, especially vehicle parts. The additive has a major component derived from aromatic compounds such as terephthalic acid including recycled polyethylene terephthalate. Asymmetrical glycols are an important ingredient and can be used to digest recycled PET to make oligomeric glycols which are reacted with acids having fewer than 12 carbon atoms to make one of the low profile additives of this invention.
Abstract: Vinyl ester resins processed until low epoxy values are reached are storage stable for two weeks at 54.degree. C. (130.degree. F.). Adding a copper salt inhibitor also provides two weeks storage stability at 54.degree. C. (130.degree. F.). A synergistic effect is observed if both low epoxy values are reached and copper naphthenate inhibitor is used, extending shelf life stability to two months at 54.degree. C. (130.degree. F.).
Abstract: Cosmetic compositions which comprise waxy organosiloxanes, which are solid at room temperature, of the formulaR.sup.1 R.sub.2 Si--O--SiR.sub.2 R.sup.1 (I),in whichR can be identical or different and represents an alkyl radical having 1 to 4 carbon atoms andR.sup.1 can be identical or different and represents a linear alkyl radical having at least 16 carbon atoms,volatile organosiloxanes chosen from the group comprising hexamethyldisiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and mixtures thereof, and optionally other substances.
Abstract: A process for the continuous preparation of organopolysiloxane by condensation and/or equilibration reaction of organosilicon compounds comprisingin a first stepconveying an organosilicon compound, catalyst which is solid in the reaction mixture at least at the reaction temperature and, optionally, additives continuously from the bottom upwards through a heated cylindrical reactor which is arranged in a standing position and whose contents can be agitated mechanically andin a second steppassing the reaction mixture obtained after leaving the reactor at the upper end thereof continuously through a cylindrical reactor andin a third stepfreeing the reaction mixture obtained of catalyst after exit from the reactor.
Type:
Grant
Filed:
October 4, 1995
Date of Patent:
March 3, 1998
Assignee:
Wacker-Chemie GmbH
Inventors:
Rudolf Braun, Ludwig Hager, Johann Steiner, Horst Muller
Abstract: Polyorganosiloxane rubber compositions which cure to elastomers under the influence of heat comprise 0.01 to 1 part by weight of ammonium, alkali metal or alkaline earth metal carbamate. The green strength of the rubber compositions is increased by the addition of carbamate. At the same time, the compression set of the vulcanized rubbers are reduced.
Abstract: The organosilanes and organopolysiloxanes containing groups which form free radicals and are soluble in organic solvents, processes for their preparation, macromonomers and graft copolymers from the organosilanes and organopolysiloxanes according to the invention as free radical initiators and organic monomers which can be polymerized by free radicals, a process for the preparation of the macromonomers and graft copolymers and their use.
Abstract: Care compositions for hard surfaces, which can be prepared using organopolysiloxanes which are solid at room temperature, contain fluorine groups and can change their state of aggregation reversibly on the basis of changes in temperature.
Abstract: The present invention relates to crosslinkable compositions are described, containing(1) organosilicon compounds which have radicals containing aliphatic carbon-carbon multiple bonds, and(2) organosilicon compounds having Si-bonded hydrogen atoms, or(3) organosilicon compounds where radicals with aliphatic carbon-carbon multiple bonds and Si-bonded hydrogen atoms are present in the same compound,(4) catalysts which promote the addition of Si-bonded hydrogen onto aliphatic multiple bond, and(5) agents which retard the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperature, of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.6 are identical or different and are a hydrogen atom or a monovalent, substituted or unsubstituted hydrocarbon radical having 1 to 12 carbon atoms per radical,R.sup.
Type:
Grant
Filed:
August 23, 1996
Date of Patent:
December 30, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Jochen Dauth, Christian Herzig, Bernward Deubzer, Klaus Schnitzer, David Huettner
Abstract: Aqueous emulsions comprising(1) an organopolysiloxane with SiC-attached vinyl groups in the terminal units,(2) an organopolysiloxane with at least 3 Si-attached hydrogen atoms,(3) a catalyst promoting the addition of Si-attached hydrogen to aliphatic multiple bonds,(4) an organosilicon adhesion promoter,(5) a silicone resin,(6) an emulsifier and(7) water.
Abstract: The liquid crystalline organosiloxanes contain per molecule at least one doristeryl group bonded at the 3.beta. position and can be used as right-handed filter materials and optical media.
Abstract: In a process, according to the invention hydridic silanes such as H.sub.2 SiCl.sub.2 or SiH.sub.4 and oligomeric hydridic silanes containing up to 5 silicon atoms are admixed with a hydrocarbon stabilizer. The hydrocarbon may have functional groups selected from among carboxylic ester, aldehyde, keto, ether, thioether, tertiary amino, epoxy and cyano groups and halogen atoms.
Type:
Grant
Filed:
March 3, 1997
Date of Patent:
December 2, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Rudolf Reitmeier, Lutz Rosch, Gilbert Geisberger, Dieter Kippe
Abstract: Organosilicon compounds containing furanyl groups which contain units of the formula ##EQU1## in which R is identical or different and is a hydrogen atom or monovalent, SiC-bonded, aliphatically saturated, optionally substituted hydrocarbon radical, which can be interrupted by oxygen atoms,R.sup.1 is identical or different and is an optionally substituted hydrocarbon radical having 1 to 8 carbon atoms, which can be interrupted by 1 to 3 oxygen atoms.A is identical or different and is an SiC-bonded furanyl radical of the formula ##STR1## where R.sup.2 has the meaning given above for the radical R and R.sup.3 is a divalent hydrocarbon radical having 2 to 30 carbon atoms, which can contain one or more groups, chosen from the group consisting of ##STR2## a is 0, 1, 2 or 3, b is 0, 1 or 2 andc is 0, 1 or 2,with the proviso that the sum a+b+c is less than or equal to 3 and the organosilicon compound contains at least one radical A per molecule.
Type:
Grant
Filed:
June 27, 1995
Date of Patent:
December 2, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Christian Herzig, Bernward Deubzer, Martina Bloechl, Inge Seeger-Feichtinger
Abstract: The present invention provides crosslinkable compositions comprising(A) an organosilicon compound having radicals containing aliphatic carbon-carbon multiple bonds,(B) an organosilicon compound having Si-bonded hydrogen atoms,(C) a catalyst which promotes the addition of Si-bonded hydrogen onto aliphatic multiple bond, and optionally(D) an agent which retards the addition of Si-bonded hydrogen onto aliphatic multiple bond at room temperatureand to the use of the crosslinkable compositions for producing coatings which repel tacky substances.The present invention also relates to organosilicon compounds having Si-bonded hydrogen atoms, and to a process for their preparation.
Type:
Grant
Filed:
January 14, 1997
Date of Patent:
November 25, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Christian Herzig, Bernward Deubzer, Martina Bloechl, Robert Banfic
Abstract: A method for the multiple filling and emptying of a receptacle with pourable product having low bulk density. The method comprises the following features:a) providing a flexible and air-permeable fabric container with at least one access port as a receptacle;b) filling the fabric container with product by applying a negative pressure to the fabric container and sucking the product through an opened access port into the fabric container, until a predetermined filling weight is reached, and closing the access port;c) emptying the fabric container, by connecting an access port to a discharge device and opening the access port and sucking the product into a conduit system or a reservoir until the fabric container is evacuated and has folded up; andd) closing the access port.
Type:
Grant
Filed:
May 21, 1996
Date of Patent:
November 4, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Helmut Maginot, Franz Stadler, Peter Pfaffinger, Henry Hackbarth, Johann Lindhuber
Abstract: In the process, used sulfuric acid which contains, as minor constituents, methylsulfuric acid, dimethyl ether, methanol, aliphatic and olefinic hydrocarbons, chlorinated hydrocarbons and oligomeric siloxanes, in a first step;(1) used sulfuric acid is diluted by introducing steam and optionally by adding liquid water to a concentration of at most 55% by weight sulfuric acid and is heated to boiling at a maximum of 135.degree. C. and in a second step;(2) the sulfuric acid from the first step is reacted with an oxidizing agent at a temperature of from 20.degree. C. to 130.degree. C.
Type:
Grant
Filed:
December 9, 1996
Date of Patent:
November 4, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Konrad Mautner, Gerhard Nagy, Martin Kankowsky
Abstract: Coating compositions based on water-redispersible powders comprising water-soluble polymer and organosilicon compounds, wherein the organosilicon compounds comprise at least one low molecular weight organosilicon compound having a viscosity of not more than 5,000 mm.sup.2 /s at 25.degree. C. and at least one high molecular weight organopolysiloxane resin which has a viscosity of at least 100,000 mm.sup.2 /s at 25.degree. C. or is solid at room temperature.
Type:
Grant
Filed:
March 18, 1996
Date of Patent:
October 28, 1997
Assignee:
Wacker-Chemie GmbH
Inventors:
Richard Weidner, Volker Frey, Ingeborg Koenig-Lumer, Hans Mayer