Patents Represented by Attorney, Agent or Law Firm Marvin S. Siskind
  • Patent number: 6524745
    Abstract: An electrochemically stabilized Ca—Ni hydrogen storage alloy material for use as the active negative electrode material of an alkaline electrochemical cell. The alloy material includes at least one modifier element which stabilizes the alloy material from degradation during electrochemical cycling in an alkaline cell, by protecting calcium within the alloy and preventing dissolution of calcium into the alkaline electrolyte. The alloy has the formula (Ca1−x−yMxNi2y)Ni5−zQz, where M is at least one element selected from the group consisting of misch metal, rare earth metals, zirconium and mixtures of Zr with Ti or V, Q is at least one element selected form the group consisting of Si, Al, Ge, Sn, In, Cu, Zn, Co, and mixtures thereof, x ranges between about 0.02 and 0.2, y ranges between about 0.02 and 0.4, and z ranges from about 0.05 to about 1.00.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: February 25, 2003
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa T. Young
  • Patent number: 6519951
    Abstract: A complete infrastructure system for the generation, storage, transportation, and delivery of hydrogen which makes a hydrogen ecosystem possible. The infrastructure system utilizes high capacity, low cost, light weight thermal hydrogen storage alloy materials having fast kinetics. Also, a novel hydrogen storage bed design which includes a support/heat-transfer component which is made from a highly porous, high thermal conductivity, solid material such as a high thermal conductivity graphitic foam. Finally a material including at least one particle having atomically engineered local chemical and electronic environments, characterized in that the local environments providing bulk nucleation.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: February 18, 2003
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa T. Young
  • Patent number: 6517970
    Abstract: A low temperature hydrogen storage alloy which is not pyrophoric upon exposure to ambient atmosphere, particularly even after hydrogen charge/discharge cycling.
    Type: Grant
    Filed: June 4, 2001
    Date of Patent: February 11, 2003
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa T. Young, Baoquan Huang
  • Patent number: 6503659
    Abstract: A layered hydrogen absorbing alloy electrode for an alkaline electrochemical cell. The layered electrode comprises a outer layer comprising a metal oxide, metal sulfide or mixtures thereof. The outer layer reduces the internal pressure of electrochemical cell.
    Type: Grant
    Filed: July 13, 1999
    Date of Patent: January 7, 2003
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Stanford R. Ovshinsky, Srinivasan Venkatesan, Boyko Aladjov, Kevin Fok, Thomas J. Hopper, Lynn Taylor
  • Patent number: 6500583
    Abstract: Practice of this invention provides, at least, a method of making a hydrogen storage material comprising the steps of: 1. forming a molten mixture comprising nickel and at least one other transition metal element, the combination of which will form a TiNi alloy and including in said molten mixture from about 0.1 at. % to about 10 at. % of one or more elements which will form an alloy which is immiscible in the TiNi-type alloy; and (b) cooling said molten mixture to form a solid alloy-system material by rapid solidification of said molten mixture at a cooling rate of at least 103° C. per second.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: December 31, 2002
    Assignees: Energy Conversion Devices, Inc., Crucible Materials Corp.
    Inventors: Jason Ting, Ulrike Habel, Michael W. Peretti, William B. Eisen, Rosa Young, Benjamin Chao, Baoquan Huang
  • Patent number: 6491866
    Abstract: Hydrogen propelled vehicles and fundamentally new magnesium-based hydrogen storage alloy materials which for the first time make it feasible and practical to use solid state storage and delivery of hydrogen to power internal combustion engine or fuel cell vehicles. These exceptional alloys have remarkable hydrogen storage capacity of well over 6 weight % coupled with extraordinary absorption kinetics such that the alloy powder absorbs 80% of its total capacity within 10 minutes at 300° C. and a cycle life of at least 500 cycles without loss of capacity or kinetics.
    Type: Grant
    Filed: July 5, 2000
    Date of Patent: December 10, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa T. Young
  • Patent number: 6492056
    Abstract: A composite hydrogen storage material including 1) an active material having hydrogen storage capacity; and 2) a catalytic material having greater catalytic activity toward the dissociation of molecular hydrogen and/or oxidation of hydrogen than that of said active material having hydrogen storage capacity. Also, a fuel cell employing anodes formed from the composite hydrogen storage material. The fuel cell has the ability to start up instantly and can accept recaptured energy such as that of regenerative braking by operating in reverse as an electrolyzer.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: December 10, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventor: Stanford R. Ovshinsky
  • Patent number: 6492057
    Abstract: An alkaline electrochemical cell having a hydrogen absorbing alloy negative electrode. The electrochemical cell comprises an alkaline electrolyte comprising an additive material which reduces cell pressure by decreasing hydrogen gas evolution.
    Type: Grant
    Filed: April 14, 1999
    Date of Patent: December 10, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Stanford R. Ovshinsky, Srinivasan Venkatesan, Boyko Alajov, Kevin Fok, Thomas J. Hopper, James L. Strebe
  • Patent number: 6478844
    Abstract: A method for making a hydrided hydrogen storage alloy powder from component material. In the present method a material is worked at the same time it is hydrided. Working preferably involves comminution of the material.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: November 12, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventor: Stanford R. Ovshinsky
  • Patent number: 6461766
    Abstract: An anti-pyrophoric hydrogen storage material having an engineered surface oxide to enhance initial activation and a method for making the same. The method for making. the hydrogen storage material includes the steps of providing a hydrogen storage powder and oxidizing the powder with a controlled oxidation reaction. In a preferred aspect hereof, the method includes providing a bulk hydrogen storage alloy; hydriding the alloy to form a comminuted material; and oxidizing the surface of the comminuted material with a controlled oxidation reaction. In another preferred aspect hereof, a passivating material is added to the comminuted material prior to the step for oxidizing to enhance initial activation. In still another preferred aspect hereof, at least one sacrificial modifier is provided in the particalized material to enhance initial activation.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: October 8, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Kwo Young, Michael A. Fetcenko, Stanford R. Ovshinsky
  • Patent number: 6452891
    Abstract: A method for initializing a phase change information storage device. The method includes the steps of: providing a data storage device having a phase change data storage medium, and exposing the phase change data storage medium with a first, energy exposure for about 1 &mgr;sec or less.
    Type: Grant
    Filed: January 26, 2000
    Date of Patent: September 17, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventor: Michael E. Hennessey
  • Patent number: 6447942
    Abstract: A fuel cell which has the ability to start up instantly and can accept recaptured energy such as that of regenerative braking by operating in reverse as an electrolyzer. The instant startup fuel cells have increased efficiency and power availability (higher voltage and current) and a dramatic improvement in operating temperature range of about −20 to 150° C.
    Type: Grant
    Filed: March 13, 2000
    Date of Patent: September 10, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Srinivasan Venkatesan, Boyko Aladjov, Rosa T. Young, Thomas Hopper
  • Patent number: 6447953
    Abstract: High capacity, long cycle life positive electrode modified nickel hydroxide material for use in an alkaline rechargeable electrochemical cell at least one modifier and has modified activation energy, chemical potential and electrical conductivity. Particle size, particle size distribution, electrical conductivity have been controlled by introducing modifier elements throughout the bulk of the active material and by controlling process parameters.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: September 10, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Cristian Fierro, Michael A. Fetcenko, Kwo Young, Stanford R. Ovshinsky, Beth Sommers, Craig Harrison
  • Patent number: 6444363
    Abstract: A process for making a positive battery electrode material using a secondary metal. The secondary metal is preferably treated using an non-electrolytic process and formed into an active, positive battery electrode material by a precipitation reaction.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: September 3, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Gabriel E. Benet, Charles T. Walker, Cristian Fierro, Michael A. Fetcenko, Beth Sommers, Avram Zallen
  • Patent number: 6432580
    Abstract: A process for making a nickel hydroxide material without the necessity of a preamine reactor. The process includes the steps of providing a metal and forming the metal into an active positive electrode material. The process for making a nickel hydroxide material may also include one or more blending steps. The step for forming may include concurrently combining the metal with ammonium ions and hydroxide ions. The step for forming may also include a continuously stirred precipitation reaction of metal ions. In a preferred aspect of the process hereof, the metal may be a secondary nickel source, such as a spent or virgin electrolyte solution from a nickel electrorefining process, nickel electroless plating process or nickel electroplating process.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: August 13, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Cristian Fierro, Michael A. Fetcenko, Beth Sommers, Avram Zallen
  • Patent number: 6425251
    Abstract: A hydrogen gas cooled hydrogen storage element which includes a hydrogen storage alloy material in which hydrogen flow channels are provided. The flow channels provide pathways through the hydrogen storage material to allow for high speed hydrogen gas flow. A portion of the high speed hydrogen flow is stored within the storage material which releases its heat of hydride formation. The remainder of the hydrogen flows through the hydrogen storage material at a sufficient mass flow rate to remove the heat of hydride formation.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: July 30, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Ned T. Stetson, Subramanian Ramachandran
  • Patent number: 6416903
    Abstract: A nickel hydroxide particle having a first active nickel hydroxide material and a second active nickel hydroxide material disposed about the first material, wherein the second active nickel hydroxide material has a mass at least 10% of the total particle mass. In a preferred embodiment of the invention the first active material and the second active material have a compositional difference of 1 to 25.
    Type: Grant
    Filed: July 18, 2000
    Date of Patent: July 9, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Cristian Fierro, Michael A. Fetcenko, Stanford R. Ovshinsky, Dennis A. Corrigan, Beth Sommers, Avram Zallen
  • Patent number: 6413670
    Abstract: A negative electrode alloy material including an effective amount of a catalyst to substantially increase the discharge capacity of the alloy at high discharge rates. Preferably the catalyst is palladium.
    Type: Grant
    Filed: December 2, 1998
    Date of Patent: July 2, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa Young
  • Patent number: 6378601
    Abstract: A hydrogen cooled hydrogen storage unit. The unit employs excess hydrogen flow between hydrogen storage alloy rods in the hydrogen storage unit in order to provide convective cooling thereof. The unit provides for high packing density of the storage materials. The unit also allows for efficient thermal transfer of heat energy from a central source of heat through the rods thereof during discharge of the stored hydrogen. The hydrogen storage rods of the unit are encased in an encapsulant layer which prevents entrainment of the hydrogen storage material in the high flow rate hydrogen.
    Type: Grant
    Filed: May 12, 2000
    Date of Patent: April 30, 2002
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa T. Young
  • Patent number: 6372377
    Abstract: Mechanically and thermally improved rechargeable batteries and modules. The battery is prismatic in shape with an optimized thickness to width to height aspect ratio which provides the battery with balanced optimal properties when compared with prismatic batteries lacking this optimized aspect ratio. The optimized thickness, width and height allow for maximum capacity and power output, while eliminating deleterious side affects. The battery case design allows for unidirectional expansion which is readily compensated for by applying external mechanical compression counter to that direction. In the module, the batteries are bound within a module bundling/compression means under external mechanical compression which is optimized to balance outward pressure due to expansion and provide additional inward compression to reduce the distance between the positive and negative electrodes, thereby increasing overall battery power.
    Type: Grant
    Filed: March 8, 1999
    Date of Patent: April 16, 2002
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Stanford R. Ovshinsky, Dennis A. Corrigan, Srinivasan Venkatesan, Subhash K. Dhar, Arthur Holland, Donn Fillmore, Lin Higley, Philippe Gow, Ronald Himmler, Nick Karditsas, Kenneth Laming, Anthony Osgood