Patents Represented by Attorney, Agent or Law Firm Mary K. Cameron
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Patent number: 7926867Abstract: A lengthwise extended component contains of a support that possesses flow channels in the direction of its longitudinal axis. The support additionally possesses external surfaces that are offset to each other in the direction of the longitudinal axis as well as a lateral external surface. These external surfaces are provided with a layer of a thermally expansible and curable composition. Reinforcing components of this type are suitable for stiffening and/or reinforcing hollow supports, such as the A-, B- or C-pillars, the roof edges or the rocker panels of vehicles, especially passenger cars.Type: GrantFiled: December 5, 2007Date of Patent: April 19, 2011Assignees: Henkel AG & Co., KGaA, Bayerische Motoren Werke AktiengesellschaftInventors: Stefan Kochert, Jochen Becker, Ralph Dalhaeuser, Andres Stiller, Alexander Straub, Thomas Hogger, Mark Riess, Josef Reindl, Juergen Kempf, Niklas Eberle, Robert Schalausky
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Patent number: 7919181Abstract: The invention relates to a metal sheet, or a component made of a metallic material, comprising a layer system on the surface with at least the following layers: a) a conversion layer, comprising no more than 1 mg chromium per m2, b) a layer of a cross-linked organic polymer system with a thickness in the range of 0.5 to 2.5 ?m, comprising, in relation to the total mass of said layer, 2 to 25 wt. % of an electrically conductive pigment having a specific weight of 3 g/cm3 maximum, however no more than 5 wt. % of the electrically conductive pigment having a specific weight of more than 3 g/m3. A coating material and a coating method for the production of the layer b).Type: GrantFiled: July 1, 2009Date of Patent: April 5, 2011Assignee: Henkel AG & Co. KGaAInventors: Eva Wilke, Manuela Göske-Krajnc, Reiner Wark, Guadalupe Sanchis Otero, Stephan Müller, Marcel Roth, Wolfgang Lorenz, Karsten Hackbarth, Andreas Kunz
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Patent number: 7902298Abstract: High-temperature-curing reactive compositions based on natural and/or synthetic elastomers containing olefinic double bonds, and on vulcanizing agents, are described, which contain at least one liquid polyene having a molecular weight between 400 and 80,000 and at least one liquid polybutadiene having a narrow molecular weight distribution and a microstructure of 10 to 20% vinyl-1,2 double bonds, 50 to 60% trans-1,4 double bonds, and 25 to 35% cis-1,4 double bonds in the molecule. These compositions furthermore contain a vulcanizing system of sulfur and accelerators and/or, if applicable, quinone oximes. These compositions are suitable for use as a single-component adhesive, sealant, or coating compound in automobile manufacture, with high tensile shear strength and high impact peel strength even, in particular, at low temperatures.Type: GrantFiled: July 31, 2008Date of Patent: March 8, 2011Assignee: Henkel AG & Co. KGaAInventors: Rainer Kohlstrung, Klaus Rappmann
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Patent number: 7851025Abstract: The present invention describes a method for the post-treatment of fully sealed anodized aluminum parts, especially for the automotive industry, characterized in that an aqueous silicate solution is applied to fully sealed anodized aluminum layers, where said fully sealed anodized aluminum layer has a film thickness of at least 5 ?m and a film weight of at least 13 g/m2, respectively. Said solution preferably contains an alkali metal (M) silicate with not more than 2.0 wt.-% of SiO2, in which the ratio of SiO2:M2O is preferably not more than 2. This treatment increases the alkaline stability according to the standardized corrosion tests in the automotive industry without any further treatment or organic coating applied to said treated aluminum surface.Type: GrantFiled: June 27, 2007Date of Patent: December 14, 2010Assignee: Henkel AG & Co. KGaAInventor: John Lawlor
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Patent number: 7741413Abstract: The present invention relates to adhesion-improved, curable compositions comprising a cyclic ether, a cyclic thiocarbonate, an amine and a carboxylic acid. A method of making such compositions and their use in adhesives, sealants and coatings are also provided.Type: GrantFiled: January 8, 2007Date of Patent: June 22, 2010Assignee: Henkel KGaAInventors: Yukio Isobe, Masashi Horikiri, Atsushi Sudo, Takeshi Endo, Olaf Lammerschop, Thomas Huver
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Patent number: 7736743Abstract: Compositions containing at least one liquid epoxy resin, at least one solid epoxy resin, at least one propellant, at least one curing agent and at least one mica-containing filler produce expandable, thermally curable binder systems which may be used without the addition of hollow glass beads for the production of stiffening and reinforcing laminates and for the production of stiffening and reinforcing moldings. Said laminates according to the invention are suitable for the stiffening and reinforcing of components, in particular in the automotive industry, such as car body frames, doors, boot lids, engine bonnets and/or roof parts. In addition, the mouldings that may be produced from said binders are suitable for the stiffening and reinforcing of hollow metal structures, in particular of hollow car body parts such as body frames, body supports and posts or doors in the automotive industry.Type: GrantFiled: July 18, 2005Date of Patent: June 15, 2010Assignee: Henkel KGaAInventors: Xaver Muenz, Larissa Bobb
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Patent number: 7709058Abstract: A process for coating metals, selected from aluminum and its alloys, zinc and its alloys, and galvanized or alloy-galvanized steel, in which the metal is given a weather-resistant protective coating, wherein the metal is cleaned if necessary, and thereafter subjected to a conversion treatment; optionally flushed with water and/or dried; brought into contact with a coating agent which comprises aliphatic cross-linking urethane resins, cross-linking agents, anti-corrosion pigments, one or more organic solvents and/or water and, if desired, other active or auxiliary substances; and then cured.Type: GrantFiled: August 7, 2007Date of Patent: May 4, 2010Assignee: Henkel KGaAInventors: Andreas Kunz, Eva Wilke, Wolfgang Lorenz, Hans Clodt
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Patent number: 7670442Abstract: A process for iron phosphating ferrous metal substrates having undesirable ferrous oxides thereon, such as that formed by laser cutting, that eliminates at least the pickling step in the phosphating process and provides good paint adhesion, and compositions of matter useful in the process.Type: GrantFiled: June 28, 2007Date of Patent: March 2, 2010Assignee: Henkel AG & Co. KGaAInventor: Daniel A. Service
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Patent number: 7651556Abstract: A protective coating is formed on a metallic material surface by applying a treating agent comprising water, an alkali silicate, and, optionally, a lubricating component to the surface and drying the treating agent. The coating film thereby formed has excellent anti-galling and rust preventive properties. If a lubricating component is present, the coating film also has excellent self-lubricating properties.Type: GrantFiled: January 26, 2004Date of Patent: January 26, 2010Assignee: Henkel AG & Co. KGaAInventors: Shinobu Komiyama, Yugo Tsuiki, Akihiro Seo
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Patent number: 7578921Abstract: An article of manufacture and a process for making the article by generating corrosion-, heat- and abrasion-resistant ceramic coatings comprising titanium and/or zirconium dioxide using direct and alternating current on anodes comprising aluminum and/or titanium. Optionally, the article is coated with additional layers, such as paint, after deposition of the ceramic coating.Type: GrantFiled: October 25, 2004Date of Patent: August 25, 2009Assignee: Henkel KGaAInventor: Shawn E. Dolan
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Patent number: 7569132Abstract: An article of manufacture and a process for making the article by the anodization of aluminum and aluminum alloy workpieces to provide corrosion-, heat- and abrasion-resistant ceramic coatings comprising titanium and/or zirconium oxides, and the subsequent coating of the anodized workpiece with polytetrafluoroethylene (“PTFE”) or silicone containing coatings. The invention is especially useful for forming longer life PTFE coatings on aluminum substrates by pre-coating the substrate with an anodized layer of titanium and/or zirconium oxide that provides excellent corrosion-, heat- and abrasion-resistance in a hard yet flexible film.Type: GrantFiled: October 25, 2004Date of Patent: August 4, 2009Assignee: Henkel KGaAInventor: Shawn E. Dolan
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Patent number: 7510613Abstract: Metal surfaces are treated with acidic aqueous compositions to form conversion coatings. The acidic aqueous compositions contain fluorometallate anions, divalent and/or trivalent cations of certain elements such as zinc, phosphorus-containing inorganic oxyanions, phosphonate anions containing phosphorus atoms directly bonded to carbon atoms, and water-soluble and/or water-dispersible organic polymers and/or polymer-forming resins.Type: GrantFiled: September 24, 2001Date of Patent: March 31, 2009Assignee: Henkel AG & Co. KGaAInventor: Kevin K. Meagher
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Patent number: 7479177Abstract: The invention involves a composition for forming a combined conversion and lubricating coating on a metal substrate with which the composition is brought into contact. The composition comprises (a) an oxyethylated aliphatic alcohol whose aliphatic hydrocarbon moiety contains 18 or more carbon atoms and (b) dissolved phosphate anions. Preferably the composition also comprises inorganic boron, an alkali metal salt of a fatty acid, and an accelerator for phosphate coating.Type: GrantFiled: February 27, 2004Date of Patent: January 20, 2009Assignee: Henkel AG & Co. KGaAInventor: Richard J. Church
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Patent number: 7473324Abstract: Autodeposition of a coating containing an epoxy resin is accomplished over a metal substrate that has been coated with a zinc phosphate conversion coating without significant removal of the zinc phosphate conversion coating.Type: GrantFiled: December 12, 2002Date of Patent: January 6, 2009Assignee: Henkel KGaAInventor: Elizabeth J. Siebert
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Patent number: 7473717Abstract: Expandable thermosettable compositions containing at least one epoxy resin, at least one finely divided thermoplastic polymer powder, at least one blowing agent, at least one curing agent, and at least one filler are suitable for the production of thermosetting laminated bodies with a tacky surface. These laminated bodies can be produced and handled in a simple manner and are suitable for stiffening and reinforcing flat structural components, in particular vehicle body structural components, such as vehicle body frames, doors, trunk lids, engine hoods and/or roof components in automobile construction. The expandable thermosettable compositions are also suitable for the production of thermosetting, thermally expandable shaped articles for reinforcing hollow structural members by the injection molding process. In preferred embodiments, the composition is injected onto a metallic or thermoplastic carrier.Type: GrantFiled: June 14, 2004Date of Patent: January 6, 2009Assignee: Henkel AG & Co. KGaAInventors: Xaver Muenz, Thomas Leeb, Rajat K. Agarwal, Gregory A. Ferguson, Michael Puckett
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Patent number: 7462582Abstract: A waterborne composition for forming protective coatings to provide, by a simple method comprising coating and drying onto a metal surface, a coating that is uniform with little unevenness and that has an excellent galling resistance and workability that are at least as good as the corresponding properties afforded by conversion treatment methodologies, contains water-soluble inorganic salt and smectite-type clay mineral. The lubrication performance of the coating can also be improved when said composition additionally contains a lubricating component.Type: GrantFiled: February 11, 2003Date of Patent: December 9, 2008Assignee: Henkel AG & Co. KGaAInventors: Shinobu Komiyama, Hidehiro Yamaguchi, Akihiro Seo
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Patent number: 7452454Abstract: Using aqueous electrolytes containing complex fluorides or oxyfluorides such as fluorozirconates and fluorotitanates, ferrous metal articles and non-metallic articles having a first coating containing aluminum may be rapidly anodized to form a second protective surface coating. White coatings may be formed on articles using pulsed direct current or alternating current.Type: GrantFiled: October 25, 2004Date of Patent: November 18, 2008Assignee: Henkel KGaAInventor: Shawn E. Dolan
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Patent number: 7452428Abstract: The invention relates to a method and coating agents used in the method which provide good adherence to and good corrosion protection of metal substrates; the coating coating agents are cross-linkable via radical polymerization. Adhesion promoting compounds are present in the conversion layer in a quantity of about 0.01 to 40 weight percent and contain, on average, one reactive unsaturated group and at least one H-active group per molecule.Type: GrantFiled: June 13, 2005Date of Patent: November 18, 2008Assignee: Henkel KGaAInventors: Matthias Koch, Kerstin Motzkat
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Patent number: 7452852Abstract: Paint residues may be removed from spraying equipment and the like by flushing with aqueous compositions containing alkoxylated aromatic alcohols wherein the aromatic ring moieties of such alcohols do not bear any alkyl substituent containing more than 4 carbon atoms. Preferably, the aqueous compositions also contain an alkanolamine or other base. The alkoxylated aromatic alcohols contain an average of at least about 2 oxyalkylene moieties (preferably, oxyethylene moieties) per molecule.Type: GrantFiled: March 24, 2005Date of Patent: November 18, 2008Assignee: Henkel KGaAInventor: Neil R. Wilson
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Patent number: 7414012Abstract: A waterborne lubricant, useful in the plastic working of metals, which imparts a lubricating behavior to the surface of metals in the absence of a conversion coating contains (A) water-soluble inorganic salt and (B) wax, wherein these components are dissolved or dispersed in water and the (B)/(A) solids weight ratio is 0.3 to 1.5. The (C) metal salt of a fatty acid can also be present at a (C)/(A) solids weight ratio of 0.01 to 0.4. The water-soluble inorganic salt (A) can be selected from the sulfates, silicates, borates, molybdates, and tungstates. The wax (B) can be a synthetic wax having a melting point of 70 to 150° C. A lubricating coating is formed by application to give a post-drying add-on of 0.5 to 40 g/m2. A method for using said lubricant is also provided.Type: GrantFiled: February 7, 2003Date of Patent: August 19, 2008Assignee: Henkel KGaAInventors: Yasuo Imai, Syuji Nagata, Masayuki Yoshida