Patents Represented by Attorney Mervin G. Wood
  • Patent number: 7828858
    Abstract: Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: November 9, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Victor Paul Eliu, Beate Fröhling, Olof Wallquist
  • Patent number: 7794509
    Abstract: Disclosed are tricationic dye compounds, useful for dyeing hair, wool, leather, silk, cellulose or polyamides. The dye compounds are of formula (1), where the groups are as defined in the specification and claims.
    Type: Grant
    Filed: June 4, 2007
    Date of Patent: September 14, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist, Victor Paul Eliu, Kishor Ramachandra Nivalkar
  • Patent number: 7789916
    Abstract: Disclosed are triarylmethane dye compounds of formula (2) wherein R8 is C1-C12alkyl, C1-C12alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or the radical —NR6R7 or —OR8; B1 and B2, independently from each other are C6-C10aryl; or a 5-7-membered heterocyclic compound, which may be substituted by C1-C12alkyl, C1-C12alkoxy, phenyl, hydroxy, halogen, sulfonic acid, carboxylate, or by the radical —NR6R7 or —OR6; and R6 and R7 independently from each other are hydrogen; or C1-C12alkyl, which may be substituted by hydroxy or C6-C10aryl.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: September 7, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist
  • Patent number: 7790769
    Abstract: Disclosed are merocyanine derivatives of formula (1), wherein R1 and R2 independently from each other are branched C4-C22alkyl; or branched C4-C12 alkenyl; R3 and R4 independently from each other are cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; wherein at least one of R3 and R4 is cyano; R5 and R6 independently from each other are hydrogen; C1-C6alkyl; C5-C8cycloalkyl which may be substituted by one or more than one C1-C4alkyl; and R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl. The compounds are useful as UV absorbers for protecting human hair and skin against the damaging effect of UV radiation.
    Type: Grant
    Filed: December 11, 2006
    Date of Patent: September 7, 2010
    Assignee: Ciba Corporation
    Inventors: Barbara Wagner, Astrid Walther, Bernd Herzog
  • Patent number: 7771490
    Abstract: Disclosed are thiol dyes of formula (I), wherein R1, R2, R3, R4 and R5 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); A is a residue of an organic dye; and Y1 is the direct bond; C1C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene). The compounds are used to dye hair with or without reducing agents. Furthermore, the present invention relates to compositions comprising thiol dyes of formula (I) and to process for the preparation of theses compounds.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: August 10, 2010
    Assignee: Ciba Corporation
    Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
  • Patent number: 7772242
    Abstract: Disclosed is the use of the compounds of formula ?wherein Q is —OH; —OR7; —NH2; —NHR7; —NR7R8; or —N?R9; T is —COR5; —CN; or —SO2—(C6-C12)aryl; R1 is hydrogen; —OR7, —SR7; —NHR7; —NR7R8; C1-C22alkyl; C2-C12Alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl, C2-C11heteroaralkyl; C6-C10aryl; or C1-C9heteroaryl; R2 and R3 independently from each other are C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl, C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl; C3-C12cycloheteroalkyl; C2-C11heteroaralkyl, C6-C10aryl; or C1-C9heteroaryl; R4 is cyano; COR7, COOR7; CONH2; CONHR7; CONR7R8; SO2(C6-C12)aryl, C2-C12alk-1 -enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl, C3-C5heterocycloalkyl, C6-C10aryl; or C1-C9heteroaryl; R5 is —COR7; —COOR7; —OR7; —SR7, —NHR7, —NR7R8; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12alkylphenyl; C1-C12alkoxy-C6-C10aryl; C1-C12heteroalkyl; C2-C11heteroaralk
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: August 10, 2010
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Barbara Wagner, Frank Bienewald, Heinz Wolleb, Olof Wallquist, Bernd Herzog, Thomas Ehlis, Jürg Haase
  • Patent number: 7731760
    Abstract: Disclosed are certain oxazine disulfide dyes useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
    Type: Grant
    Filed: September 27, 2006
    Date of Patent: June 8, 2010
    Assignee: Ciba Corporation
    Inventors: Christian Cremer, Olof Wallquist
  • Patent number: 7731761
    Abstract: Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —C1-C10alkylene-; —C2-C12alkenylene-; —C5-C10cycloalkylene-; C5-C10arylene; —C5-C10arylene-(C1-C10alkylene)-; —C(O)—; —(CH2CH2—O)1-5—; —C(O)O—; —OCO—; —N(R1)—; —CON(R1)—; —(R1)NC(O)—; -0-; —S—; —S(O)—; —S(O)2—; —S(O)2—N(R1R2); or the direct bond; R1 and R2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C1-C14alkyl; C2-C14alkenyl; C6-C10aryl; C6-C10aryl-C1-C10alkyl; or C5-C10alkyl(C5-C10aryl); Y1 and Y2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y1 and Y2 is a residue of an organic dye; An1, An2 and An3, independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1
    Type: Grant
    Filed: July 9, 2007
    Date of Patent: June 8, 2010
    Assignee: Ciba Corporation
    Inventors: Sophie Marquais-Bienewald, Olof Wallquist, Christian Cremer, Beate Fröhling, Andreas Möck
  • Patent number: 7704284
    Abstract: Disclosed are compounds of formula (1a), wherein R1 is N+R8R9; R8 and/or R9 independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4-alkyl; or R8 and/or R9 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C1 or C2 respectively and, together with the linking nitrogen atom form a 6 to 16-membered carbocyclic ring; R2 is NR10R11; or OR10; R10 and R11, independently from each other are hydrogen; C1-C12alkyl; or phenyl-C1-C4alkyl; or R10 and/or R11 are a bivalent C3-C6alkylene radical which is linked to the carbon atoms C3 or C4 respectively and, together with the linking nitrogen or oxygen atom form a 6 to 16-membered carbocyclic ring; or R10 and R11 together with the linking nitrogen atom form a 4 to 8 membered carbocyclic ring; R3, R4, R5, R6 and R7 independently form each other are hydrogen; C1-C12alkyl; halogen; NR12R13; or a radical of formula (1a); R12 and R13 independently from each other are hydrogen; C1-C12alkyl; phenyl-C1-C4alkyl; or a radical of formula (1a2); V
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: April 27, 2010
    Assignee: Ciba Corporation
    Inventors: Victor Paul Eliu, Beate Fröhling, Dominique Kauffmann
  • Patent number: 7692004
    Abstract: Use of metal complex compounds of formula [LnMemXp]zYq??(1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR?13R?13 wherein R13, R?13 and R?13 are as defined above for R13; —NR14R15 or —N?R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substit
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: April 6, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Gunther Schlingloff, Torsten Wieprecht, Frank Bachmann, Josef Dannacher, Marie-Josée Dubs, Menno Hazenkamp, Grit Hänsler (-Richter), Brigitte Schmidt, Albert Schneider, Peter Weingartner
  • Patent number: 7682404
    Abstract: The present invention concerns coloring keratin fibers, especially human hair, with colored metal complexes.
    Type: Grant
    Filed: May 3, 2006
    Date of Patent: March 23, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Nicole End, Kai-Uwe Schöning, Beate Fröhling
  • Patent number: 7678381
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics comprising an effective stabilizing amount of at least one compound selected from the group consisting of formula (I)-(III) where G1 and G2 are independently alkyl of 1 to 4 carbon atoms or are together pentamethylene, Z1 and Z2 are each methyl, or Z1 and Z2 together form a linking moiety which may additionally be substituted by an ester, ether, hydroxy, oxo, cyanohydrin, amide, amino, carboxy or urethane group, X is an inorganic or organic anion, and where the total charge of cations h is equal to the total charge of anions j; and an organic UV filter selected from (c1) dibenzoylmethane derivatives; (c2) cinnamic acid esters; (c3) camphor derivatives; and (c4) trianilino-s-triazine derivatives.
    Type: Grant
    Filed: October 25, 2004
    Date of Patent: March 16, 2010
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Joseph Anthony Lupia, Oliver Reich, Karla Wilzer
  • Patent number: 7645886
    Abstract: The invention relates in a first embodiment to a method for the manufacture of esters of the formula (I), or especially of amides of the formula (II), wherein the symbols have the meanings given in the specification, as well as other intermediates and compounds useful in the synthesis of tryptamines and other substances mentioned in the title. The synthesis methods and intermediates are useful in the synthesis of pharmaceuticals.
    Type: Grant
    Filed: December 12, 2003
    Date of Patent: January 12, 2010
    Assignee: Ciba Specialty Corporation
    Inventors: Ulrich Berens, Oliver Dosenbach, Daniel Sprenger
  • Patent number: 7632795
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain sterically hindered amine salt compounds. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: December 15, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood, Wanda H. Martin
  • Patent number: 7618644
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain dialkylhydroxyamine stabilizers, dialkylhydroxylamine stabilizer salts, nitrone stabilizers or amine oxide stabilizers. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: November 13, 2008
    Date of Patent: November 17, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood
  • Patent number: 7618618
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain dialkylhydroxyamine stabilizers, dialkylhydroxylamine stabilizer salts, nitrone stabilizers or amine oxide stabilizers. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: September 17, 2007
    Date of Patent: November 17, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood
  • Patent number: 7615503
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain sterically hindered amine salt compounds. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: November 10, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood, Wanda H. Martin
  • Patent number: 7612010
    Abstract: Use of metal complex compounds of formula (1) and/or (1?) [LnMemXp]zYq??(1), [L?nMemXp]zYq??(1?), wherein all substituents are as defined in the claims, as catalysts for oxidation reactions, and also novel metal complex compounds and novel ligands.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: November 3, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Gunther Schlingloff, Torsten Wieprecht, Uwe Heinz, Albert Schneider, Marie-Josée Dubs, Frank Bachmann, Menno Hazenkamp, Thomas Ehlis, Cornelia Vincenzi, Josef Dannacher
  • Patent number: 7612026
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain sterically hindered amine salt compounds. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: November 3, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood, Wanda H. Martin
  • Patent number: 7589035
    Abstract: Disclosed are stabilized body care products, household products, textiles and fabrics which comprise certain sterically hindered amine salt compounds. Dyed products and articles are effectively stabilized against color degradation. The products are for example skin-care products, hair-care products, dentifrices, cosmetics, laundry detergents and fabric softeners, non-detergent based fabric care products, household cleaners and textile-care products.
    Type: Grant
    Filed: March 19, 2009
    Date of Patent: September 15, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Joseph A. Lupia, Joseph Suhadolnik, Mervin G. Wood, Wanda H. Martin