Patents Represented by Attorney Michael J. Tully
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Patent number: 5476518Abstract: A process for treating a dyed, velvet fabric is disclosed wherein two-toned color effects between the pile and the fabric backing are achieved. The preferred fabric comprises a cellulosic (cotton or rayon) or synthetic fiber weave backing dyed preferably with a non-disperse dye, e.g. a direct dye, and pile composed of cellulose acetate fibers dyed with a disperse dye. The dyed fabric is contacted with a dilute caustic solution, e.g., sodium hydroxide, for a period of time sufficient to at least partially or totally hydrolyze the cellulose acetate of the pile fiber, which noticeably also reduces the color intensity of the pile while having little effect on the color intensity of the backing. This is followed by rinsing, neutralization and conditioning of the treated fabric.Type: GrantFiled: March 14, 1995Date of Patent: December 19, 1995Assignee: A. Wimpfheimer & Bro., Inc.Inventor: Nicholas Caleshu
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Patent number: 5240819Abstract: This invention is that of high temperature polyamides containing the hexafluoroisopropylidene group. The high temperature polyamides of the invention and photo or radiation sensitizers provide improved high temperature positive resists which can be developed in aqueous alkaline developer and thermally anneal to form heat resistant, polyoxazole relief structures suitable for use in microelectronic and printing applications. The positive photoresists of the invention have improved solubility in coating solvents and improved photospeed. The polyamides of the invention can be prepared by conventional condensation reactions; e.g. the condensation of a diamine and diacid chloride. In addition the polyamides of this invention provide high temperature protective coatings with superior adhesion properties in applications other than the photoresist area.Type: GrantFiled: March 11, 1991Date of Patent: August 31, 1993Assignee: Hoechst Celanese CorporationInventors: Werner H. Mueller, Dinesh N. Khanna, Bernd Hupfer
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Patent number: 5148776Abstract: A fuel and water injection system for an internal combustion engine in which a computer calculates the minimum fuel requirements to meet power demand and the water injection requirements to achieve smooth operation without engine knock or pre-ignition; and triggers electronic injectors mounted in the intake manifold or adjacent to the cylinders to achieve those requirements. Fuel and water injectors are connected to constant-pressure fluid supply systems such that the rate of delivery of liquid to the inlet manifold or cylinder is based on the pulse width and pulse repetition rate of the signals sent from the computer. The fuel/air ratio ranges from the minimum requirement to support the combustion process to the maximum which can be burned cleanly and efficiently. Fuel injection rates within these limits are based on the operator's demand for power as represented by his positioning of the throttle plate using the accelerator.Type: GrantFiled: September 23, 1991Date of Patent: September 22, 1992Inventor: Michael J. Connor
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Patent number: 5057564Abstract: The present invention relates to novel polymers which are adducts of an unsaturated hydrocarbon, wherein the novel polymers are produced by contacting cyclic carbonyl monomers with an unsaturated hydrocarbon to form novel cyclic carbonyl polymers having an Mn of about 500 to about 10.sup.7.Type: GrantFiled: July 23, 1990Date of Patent: October 15, 1991Assignee: Exxon Research and Engineering CompanyInventor: Stanley J. Brois
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Patent number: 4764213Abstract: A lithographic fountain solution concentrate is disclosed, the essential components of which comprises an aqueous mixture of:(a) from about 0.1 to 1.5 percent by weight of a water soluble film forming hydrophilic gum;(b) from about 0.75 to about 8.5 percent by weight of Polyvinyl Pyrrolidone;(c) from about 5.0 to about 30.0 percent by weight of a water soluble acid etchant;(d) from about 20.0 to about 50.0 percent by weight of a water soluble or water miscible glycol; and(e) from about 0.01 to about 1.25 percent by weight of a phosphate/phosphoric acid buffer system.The concentrate is adapted for further dilution by water to yield a fountain solution which when used in the printing process offers decreased scumming and blinding of printing plates while at the same time permitting a reduction in the amount of water applied to the plate. Improved print quality, reduced tendency to wet the paper, faster ink drying and improved ink/water balance is thereby achieved.Type: GrantFiled: June 16, 1986Date of Patent: August 16, 1988Assignee: Hoechst Celanese CorporationInventors: Henry Gventer, Raymond Hamilton
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Patent number: 4732836Abstract: The invention relates to new mixed ester photosensitive compounds and photosensitizer compositions comprised thereof. The photosensitive compounds and photosensitizer compositions are prepared by condensing phenolic compounds with a 1,2-naphthoquinonediazide-4-sulfonic acid halide and an organic acid halide in specific ratios. Photoresist compositions comprising the photosensitive compounds and photosensitizer compositions are also disclosed. The photosensitizer compositions exhibit excellent solution stability and resistance to precipitation when formulated in alkali-soluble resin photoresist compositions. The photoresist compositions have improved shelf life.Type: GrantFiled: May 2, 1986Date of Patent: March 22, 1988Assignee: Hoechst Celanese CorporationInventors: Robert E. Potvin, Jonas O. St. Alban, Chester J. Sobodacha
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Patent number: 4732837Abstract: The invention relates to new mixed ester photosensitive compounds and photosensitizer compositions comprised thereof. The photosensitive compounds and photosensitizer compositions are prepared by condensing phenolic compounds with a 1,2-naphthoquinonediazide-5-sulfonic acid halide and an organic acid halide in specific ratios. Photoresist compositions comprising the photosensitive compounds and photosensitizer compositions are also disclosed. The photosensitizer compositions exhibit excellent solution stability and resistance to precipitation when formulated in alkali-soluble resin photoresist compositions. The photoresist compositions have enhanced lithographic properties.Type: GrantFiled: May 2, 1986Date of Patent: March 22, 1988Assignee: Hoechst Celanese CorporationInventors: Robert E. Potvin, Jonas O. St. Alban, Chester J. Sobodacha
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Patent number: 4726928Abstract: Resinous compositions that are stabilized against the deteriorative effect of gamma and other ionizing radiation comprises a vinyl halide resin, from 2% to 4% by weight, based on the weight of the vinyl halide resin, of an organotin mercaptoacid ester, and an epoxy compound in the amount of from 3 parts to 5 parts by weight of the epoxy compound per part by weight of the organotin mercaptoacid ester.The stabilized vinyl halide resin compositions can be used in the aseptic packaging of foods and other perishable materials.Type: GrantFiled: April 18, 1986Date of Patent: February 23, 1988Assignee: American Hoechst CorporationInventors: Adam J. Ejk, Mark A. Jachym
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Patent number: 4642263Abstract: Plastic films having improved antistatic properties are disclosed having a continuous coating on at least one surface of the film based on a composition comprising a mixture of:(a) a polymeric binder, and(b) a quarternary ammonium salt having the formula: ##STR1## wherein: R is a lower alkyl group having 1 to 3 carbon atoms;R' is an alkyl or alkenyl radical having from about 8 to 20 carbon atoms; andX.sup.- is an anion.The antistat coating composition may be applied to the film material at any suitable stage during manufacture, i.e., after extrusion of the sheet material or before, during or after orienting the sheet. The resultant film is found to possess markedly enhanced antistat properties, good clarity, good slip properties, reclaimability and adhesive properties at higher binder levels rendering it suitable for the application of other coatings.Type: GrantFiled: December 18, 1984Date of Patent: February 10, 1987Assignee: American Hoechst CorporationInventor: Edwin C. Culbertson
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Patent number: 4592953Abstract: An oriented polyester film coated on one or both sides with a crosslinked vinyl acetate polymer composition which renders the polyester film surface receptive to additional reprographic or matte coatings applied thereto, and to film containing the reclamation product of such coated film.Type: GrantFiled: December 12, 1983Date of Patent: June 3, 1986Assignee: American Hoechst CorporationInventors: Grover L. Farrar, E. C. Culbertson
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Patent number: 4585687Abstract: A primer coated, oriented polyester film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations.Type: GrantFiled: April 30, 1984Date of Patent: April 29, 1986Assignee: American Hoechst CorporationInventors: Robert G. Posey, Edwin C. Culbertson
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Patent number: 4571363Abstract: A prime coated oriented polyester film material is disclosed wherein the primer coating consists essentially of a crosslinked copolymer containing at least about 50% by weight of acrylic and/or methacrylic monomers and from about 1% to 15% by weight of a comonomer capable of inter-molecular crosslinking upon the application of heat, and from 0 to about 49% by weight of one or more halogen-free mono-ethylenically unsaturated monomers copolymerizable therewith.The priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations, and is crosslinked after application by means of heat. The resultant primed polyester film is found to provide excellent adhesion to many organic solvent based coatings subsequently applied thereto, and to be reclaimable when reprocessed during the manufacture of polyester film without giving rise to significant or intolerable discoloration or degradation of the film.Type: GrantFiled: December 12, 1983Date of Patent: February 18, 1986Assignee: American Hoechst CorporationInventors: E. C. Culbertson, Grover L. Farrar
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Patent number: 4557963Abstract: The present invention relates to a credit card or identification card fabricated from amorphous polyester sheet material wherein at least the area of said card containing embossed numerical or letter characters and the characters themselves are composed of substantially crystalline polyester. Such characters can not readily be altered by either heat treatment or by shaving them off.Type: GrantFiled: December 5, 1984Date of Patent: December 10, 1985Assignee: American Hoechst CorporationInventor: R. Scott Caines
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Patent number: 4554200Abstract: A prime coated oriented polyester film is disclosed wherein the primer coating is applied as an aqueous medium consisting essentially of a material selected from the group consisting of a water soluble alkali metal salt of an unsaturated fatty acid having from about 10 to 18 carbon atoms and mixtures of such salts or a water soluble alkali metal salt of an alkyl sulfate having from about 8 to 18 carbon atoms and mixtures of such salts. Preferred species include sodium oleate and sodium lauryl sulfate. The alkali metal salt priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations, or after stretching and prior to winding of the film. The resultant primed polyester film is found to provide excellent adhesion to many aqueous or organic solvent based printing inks subsequently applied thereto.Type: GrantFiled: September 24, 1984Date of Patent: November 19, 1985Assignee: American Hoechst CorporationInventor: R. Scott Caines
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Patent number: 4544694Abstract: Compositions of matter and processes for making the compositions of matter are described. The compositions are extrusion lubricant compositions and may be prepared by either combining appropriate initial components in predetermined amounts, or forming a homogeneous melt of a fatty acid, e.g. stearic acid, and one or more polar substances, e.g., a fatty alcohol or polyalcohol, adding a metal base material to form the metal salt of the fatty acid in situ, and adding one or more waxes such as microwaxes, paraffins and/or alpha-olefins to the mixture. The compositions are effective lubricants used in heat processing of vinyl chloride resin compositions.Type: GrantFiled: June 14, 1984Date of Patent: October 1, 1985Assignee: American Hoechst CorporationInventor: J. David Bower
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Patent number: 4533619Abstract: This invention relates to light sensitive diazonium compound condensation products stabilized against degradation caused by heat and/or prolonged storage employing, as stabilizers, an acid selected from the group consisting of benzoic acid, m-nitro benzoic acid, p(p-anilino phenylazo) benzene sulfonic acid, 4,4'-dinitro-2,2'-stilbene disulfonic acid, itaconic acid, and mixtures thereof. The invention also relates to presensitized reproduction materials comprising the acid stabilized diazonium compound condensation products.Type: GrantFiled: September 12, 1983Date of Patent: August 6, 1985Assignee: American Hoechst CorporationInventors: John E. Walls, Major Dhillon, Trisha Bentley
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Patent number: 4525419Abstract: A primer coated, oriented plastic film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the plactic film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations.Type: GrantFiled: July 26, 1984Date of Patent: June 25, 1985Assignee: American Hoechst CorporationInventors: Robert G. Posey, Edwin C. Culbertson
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Patent number: 4522670Abstract: The present invention relates to a credit card or identification card fabricated from amorphous polyester sheet material wherein at least the area of said card containing embossed numerical or letter characters and the characters themselves are composed of substantially crystalline polyester. Such characters can not readily be altered by either heat treatment or by shaving them off.Type: GrantFiled: April 4, 1983Date of Patent: June 11, 1985Assignee: American Hoechst CorporationInventor: R. Scott Caines
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Patent number: 4486483Abstract: A prime coated oriented polyester film is disclosed wherein the primer coating is applied as an aqueous medium consisting essentially of a material selected from the group consisting of a water soluble alkali metal salt of an unsaturated fatty acid having from about 10 to 18 carbon atoms and mixtures of such salts or a water soluble alkali metal salt of an alkyl sulfate having from about 8 to 18 carbon atoms and mixtures of such salts. Preferred species include sodium oleate and sodium lauryl sulfate. The alkali metal salt priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations, or after stretching and prior to winding of the film. The resultant primed polyester film is found to provide excellent adhesion to many aqueous or organic solvent based printing inks subsequently applied thereto.Type: GrantFiled: July 11, 1983Date of Patent: December 4, 1984Assignee: American Hoechst CorporationInventor: R. Scott Caines
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Patent number: 4476189Abstract: A primer coated, oriented polyester film material is provided wherein the primer is applied in an aqueous medium comprising a water dispersible copolyester consisting essentially of the condensation product of components A, B, C, and D or their polyester forming equivalents as follows:(A) about 60 to 75 mole percent of terephthalic acid;(B) about 15 to 25 mole percent of at least one dicarboxylic acid of the formula HOOC(CH.sub.2).sub.n COOH, wherein n ranges from about 1-11;(C) greater than from about 6 up to about 15 mole percent of at least one sulfomonomer containing an alkali metal sulfonate group attached to a dicarboxylic aromatic nucleus, and(D) stoichiometric quantities, i.e., about 100 mole percent of at least one aliphatic or cycloaliphatic alkylene glycol copolymerizable therewith having about from 2 to 11 carbon atoms.The copolyester priming layer may be applied to the polyester film at any suitable stage during manufacture of the film, i.e., before or during the stretching operations.Type: GrantFiled: May 16, 1983Date of Patent: October 9, 1984Assignee: American Hoechst CorporationInventors: Robert G. Posey, Edwin C. Culbertson