Abstract: A method for preparing a polymer powder which is redispersible in water by atomizing an aqueous non-polyvinyl alcohol stabilized polymer dispersion containing a dispersing aid consisting of vinyl pyrrolidone homopolymer.
Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formula R.sub.n B(OH).sub.3-n wheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine with boric acid.
Abstract: A method for making a nonwoven filter which comprises impregnating a nonwoven filter substrate with a curable binder composition, the binder composition consisting essentially of(a) 10 to 100 wt% fully hydrolyzed PVOH which has a DPn of 100 to 2300; and(b) 0 to 90 wt% aqueous polymer emulsion, on a solids basis.The preferred aqueous polymer emulsion is an ethylene-vinyl chloride (EVCl) copolymer emulsion or a vinyl acetate/-N-methylolacrylamide (VAc/NMA) copolymer emulsion, or both.
Type:
Grant
Filed:
March 17, 1992
Date of Patent:
September 14, 1993
Assignee:
Air Products and Chemicals, Inc.
Inventors:
George Davidowich, John G. Iacoviello, John S. Sadowski
Abstract: A pressure sensitive adhesive composition comprising a vinyl acetate/ethylene/acrylate copolymer emulsion containing 5 to 60 wt % tackifier resin, on a total solids basis.
Abstract: A method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of a blowing agent, cell stabilizer and a catalyst composition which comprises a quaternary ammonium carboxylate inner salt having the following formula I ##STR1## where R.sub.1 -R.sub.3 are independently C.sub.1 -C.sub.12 alkyl, C.sub.5 -C.sub.8 cycloalkyl or a heterocycle, C.sub.6 -C.sub.10 aryl or heteroaromatic. R.sub.1 and R.sub.2 or R.sub.1 -R.sub.3 together with the nitrogen atom can also be part of nitrogen containing ring system such as piperdine, morpholine, triethylenediamine, imidazole, or 1,8-diazabicyclo-[5.4.0]-undec-7-ene. R.sub.4 is a divalent R.sub.1.
Type:
Grant
Filed:
January 8, 1993
Date of Patent:
August 31, 1993
Assignee:
Air Products and Chemicals, Inc.
Inventors:
James D. Nichols, Ann C. L. Savoca, Mark L. Listemann
Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formulaR.sub.n B(OH).sub.3-nwheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine or 3-quinuclidinol with boric acid.
Type:
Grant
Filed:
June 10, 1992
Date of Patent:
August 24, 1993
Assignee:
Air Products and Chemcials, Inc.
Inventors:
Ann C. L. Savoca, Michael Louie, Mark L. Listemann
Abstract: A method for preparing a reduced density MDI based polyurethane foam by reacting a polyol with an MDI composition using at least 4 parts by weight water based on 100 parts of polyol as the blowing agent and a catalyst composition consisting essentially of the addition product of triethylenediamine and a boron compound of the formulaR.sub.n B(OH).sub.3-nwheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.
Abstract: A method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of a blowing agent, a cell stabilizer and a catalyst composition consisting essentially of at least one compound of the following formula; ##STR1## where R is hydrogen, c.sub.1 -c.sub.8 alkyl, c.sub.6 -c.sub.10 aryl or c.sub.7 -c.sub.10 aralkyl, and n is 0-3. The preferred catalyst consists essentially of of the compound when n is 0, namely 3-quinuclidinol.
Type:
Grant
Filed:
January 30, 1992
Date of Patent:
August 3, 1993
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Mark L. Listemann, Ann C. L. Savoca, Kristen E. Minnich, Kevin R. Lassila
Abstract: The invention relates to reaction injection molded elastomers derived from high molecular weight polyether polyols, an aromatic diamine chain extender, a polyisocyanate and a hydroxyl-containing organotin catalyst. The reaction injection molded (RIM) elastomers of this invention are useful, for example, as automobile body parts.
Abstract: A method for catalyzing the trimerization of an isocyanate and/or the reaction between an isocyanate and an active hydrogen-containing compound, the improvement which comprises employing a catalyst composition consisting essentially of the addition product of a tertiary amine urethane catalyst and a boron compound of the formulaR.sub.n BX.sub.3-nwheren represents 0, 1, 2 or 3,X represents F, Cl, Br, OCOR', OR" or mixtures thereof, andR, R' and R" independently represent C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8cycloalkyl, C.sub.6 -C.sub.10 aryl or mixtures thereof.
Abstract: An extrudable polyvinyl alcohol composition useful for packaging and molding applications is prepared by melt blending polyvinyl alcohol and thermoplastic polyethylene oxide to provide a product which has improved pH stability and salt solution solubility. Useful extruded articles prepared from such compositions include films and containers.A method for extruding the polyvinyl alcohol composition comprises:adding sufficient energy to the polyvinyl alcohol composition to both melt it and essentially eliminate the polyvinyl alcohol crystallinity in the melt, andsimultaneously removing energy from the melt at a rate sufficient to avoid decomposition of the polyvinyl alcohol.The thermoplastic polyethylene oxide may be added to the polyvinyl alcohol before the polyvinyl alcohol is melted and its crystallinity eliminated or blended with the thus thermally treated polyvinyl alcohol and then melt extruding the polyvinyl alcohol/polyethylene oxide blend.
Type:
Grant
Filed:
October 18, 1991
Date of Patent:
April 27, 1993
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Amir Famili, Finn L. Marten, James F. Nangeroni
Abstract: The invention relates to reaction injection molded elastomers derived from high molecular weight polyether polyols, an aromatic diamine chain extender, a polyisocyanate and a hydroxyl-containing organotin catalyst. The reaction injection molded (RIM) elastomers of this invention are useful, for example, as automobile body parts.
Abstract: A wiped film evaporation process for reducing the amount of residual organic polyisocyanate, especially toluene diisocyanate, in a polyurethane prepolymer reaction product mixture. An inert sweeping gas is added to the evaporation process, preferably after first passing through a holdup volume of the prepolymer which has passed through the evaporation zone.
Type:
Grant
Filed:
July 9, 1991
Date of Patent:
April 13, 1993
Assignee:
Air Products and Chemicals, Inc.
Inventors:
William E. Starner, Bernard A. Toseland, Reinaldo M. Machado
Abstract: A method for preparing a polyurethane foam which comprises reacting an organic polyisocyanate and a polyol in the presence of a blowing agent, a cell stabilizer and a catalyst composition consisting essentially of at least one compound of the following formula: ##STR1## where R is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.10 aralkyl, and n is 0-3. The preferred catalyst consists essentially of the compound when n is 0, namely 3-quinuclidinol.
Abstract: Vinyl acetate and an N-vinyl formamide are copolymerized to yield poly(vinyl acetate)-co-poly(N-vinyl formamide) which is base hydrolyzed to poly(vinyl alcohol)-co-poly(N-vinyl formamide). Two phase hydrolysis of particles of poly(vinyl alcohol)-co-poly(N-vinyl formamide) as a slurry in methanol yields particles of poly(vinyl alcohol)-co-poly(vinylamine).Provided is a copolymer of the following general formula ##STR1## where m is 0 to 15 mole %,n is 50 to 99 mole %, x is 0 to 30 mole %, and y is 1 to 50 mole %.
Abstract: An aqueous vinyl acetate/N-methylolacrylate copolymer emulsion for RF curable Type I wood adhesive compositions prepared by the polymerization of vinyl acetate and N-methylolacrylamide in the presence of 1 to 5 wt% tetramethylol glycoluril and a stabilizing system consisting essentially of 3 to 5 wt% polyvinyl alcohol, the weight percentages being based upon vinyl acetate monomer.
Abstract: Preparation of a polyurethane and/or polyisocyanurate product by the reaction of a composition containing an organic polyisocyanate, an active hydrogen containing compound and water as a blowing agent using an effective amount of a molecular sieve containing sorbed amine catalyst and/or crosslinker.
Abstract: An amine-boron composition for catalyzing the urethane reaction, particularly in preparing a polyurethane foam, consisting essentially of the addition product of a tertiary amine and a boron compound of the formula R.sub.n B(OH).sub.3-n wheren=0 or 1, andR=C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.8 cycloalkyl or C.sub.6 -C.sub.10 aryl.Preferred catalysts are prepared by mixing triethylenediamine with boric acid.
Abstract: A high water, high resiliency polyurethane foam composition comprising polyisocyanate, conventional polyol, polymer polyol, diethanolamine, silicone surfactant, water and catalyst, the improvement which comprises a cycloaliphatic diamine of the following formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are independently hydrogen or a C.sub.1 -C.sub.4 alkyl group, and a catalyst composition consisting essentially of 0.05 to 0.3 parts gel catalyst and 0.075 to 0.5 parts acid-blocked blowing catalyst, per 100 parts polyol.
Abstract: A method for making an aqueous polyurethane-vinyl polymer dispersion which comprises:(a) forming a carboxy-containing, water-dispersible, isocyanate terminated polyurethane prepolymer,(b) adding a vinyl monomer composition which includes a polyethylenically unsaturated monomer to the prepolymer to form a prepolymer/monomer mixture,(c) adding a tertiary amine to the prepolymer/monomer mixture,(d) dispersing the prepolymer/monomer mixture in water,(e) adding an oil soluble free radical initiator and a chain-extender to the aqueous dispersion, and(f) polymerizing the vinyl monomer and completing chain extension of the prepolymer by heating the aqueous dispersion.
Type:
Grant
Filed:
April 26, 1991
Date of Patent:
December 22, 1992
Assignee:
Air Products and Chemicals, Inc.
Inventors:
Bheema R. Vijayendran, Richard Derby, Bruce A. Gruber