Patents Represented by Attorney Michael P. Dilworth
  • Patent number: 7244857
    Abstract: A method for reacting alkanolamine with ester in the presence of a metal silicate compound and, optionally, a catalyst, to produce a hydroxyalkyl amide composition with a decreased level of alkanolamine and residual catalyst.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: July 17, 2007
    Assignee: Crompton Corporation
    Inventors: E. Brian Fox, Timothy L. Lambert
  • Patent number: 7189875
    Abstract: Disclosed herein is a process for the preparation of alkylated diarylamines comprising adding to said diarylamine an olefin mixture containing highly reactive fractions, as well as fractions exhibiting a relatively lower chemical reactivity, in the presence of an acidic clay catalyst at a temperature low enough to prevent substantial deactivation of the catalyst until the addition is complete and then increasing the temperature to increase the alkylation rate of the less reactive fractions.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: March 13, 2007
    Assignee: Crompton Corporation
    Inventors: Karl J. Duyck, Timothy L. Lambert
  • Patent number: 7160845
    Abstract: Dithiocarbamate derivative compounds, useful as multifunctional additives for lubricating oils and fuels, are provided and are derived from a reaction product obtained from (a) a di(hydrocarbyl)thiocarbamate intermediate derived from the reaction of a dihydrocarbylamine and carbon disulfide; (b) an amide of the general formula R7CONH2 wherein R7 is an alkylene group having 2 to about 30 carbon atoms; and (c) an effective amount of a carbonyl-containing compound.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: January 9, 2007
    Assignee: Crompton Corporation
    Inventors: John R. Baranski, Theodore E. Nalesnik
  • Patent number: 7160944
    Abstract: A process for making an aqueous emulsion of polyolefin employs a functionalized emulsification facilitating compound. The aqueous emulsion can be used to prepare a hybrid polyolefin-polyurethane dispersion useful, inter alia, as an adhesion-promoting coating for polymers such as the polyolefins.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: January 9, 2007
    Assignee: Crompton Corporation
    Inventors: Ibrahim Bechara, Pavel Ilmenev, Oleg Tselnik
  • Patent number: 7153895
    Abstract: Disclosed are methods for the formation of a rubber/filler/curative/plasticizer compacted masterbatch which may be performed in two ways. In one embodiment, a rubber and a filler are intimately mixed for a time and under shear conditions sufficient to form a free flowing associated composition, then the composition is mixed with a plasticizer and a curative to form the compacted masterbatch. Alternatively, the starting material may be an already-formed free flowing associated composition of rubber, filler and optional curative, which is mixed with a plasticizer and optional curative to form the compacted masterbatch.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: December 26, 2006
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Joseph M. Hochheiser, Emmanuel G. Kontos, Richard W. Tomlinson
  • Patent number: 7144951
    Abstract: A process is disclosed that comprises solution grafting a hydrocarbon polymer prepared from at least C2 to C28 polymerizable hydrocarbon, said polymer having a number average molecular weight in the range of from about 5,000 to about 500,000, with an ethylenically unsaturated C3 to C10 carboxylic acid material, using a free radical initiator, in the presence of an aromatic ester oil of the formula (I) wherein R1, R2, R3, R4, R5, and R6 are independently selected from the group consisting of hydrogen, —COOR7, —COOR8, —COOR9, —COOR10, —COOR11, and —COOR12, provided that no more than 5 of R1, R2, R3, R4, R5 and R6 are hydrogen, and R7, R8, R9, R10, R11, and R12 are independently selected from the group consisting of alkyl and alkylesters
    Type: Grant
    Filed: September 14, 2001
    Date of Patent: December 5, 2006
    Assignee: Crompton Corporation
    Inventors: Karl Duyck, Theodore E. Nalesnik, Uyen Thanh Tran
  • Patent number: 7145038
    Abstract: A process for alkylation of a diphenylamine compound in an ionic liquid. The use of an ionic liquid permits convenient separation of the alkylated reaction product from the reaction mixture.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: December 5, 2006
    Assignee: Chemtura Corporation
    Inventor: Steven J. Hobbs
  • Patent number: 7129306
    Abstract: A process is disclosed for the preparation of a poly(?-olefin) polymer wherein the process comprises polymerizing at least one ?-olefin in the presence of hydrogen and a catalytically effective amount of catalyst comprising the product obtained by combining a metallocene catalyst with a cocatalyst, the metallocene catalyst being at least one meso compound of general formula: wherein: A1 and A2 are independently selected from the group consisting of mononuclear and polynuclear hydrocarbons; M1 is a metal from group IVb, Vb, or VIb of the Periodic Table; R1 and R2 are independently selected from the group consisting of hydrogen, C1–C10 alkyl, C1–C10-alkoxy, C6–C10 aryl, C6–C10 aryloxy, C2–C10 alkenyl, C7–C40 arylalkyl, C7–C40 alkylaryl, C8–C40 arylalkenyl and halogen; R7 is selected from the group consisting of: ?BR11, ?AlR11, —Ge—, —Sn—, —O—, —S—, ?SO, ?SO2, ?NR11, ?CO, ?PR11 and ?P(O)R11, where R11, R12, and R13 are independently selected from the group consisting of hydrogen, halogen, C1–C10 alky
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: October 31, 2006
    Assignee: Crompton Corporation
    Inventor: Anthony-Joseph DiMaio
  • Patent number: 7087557
    Abstract: A salicylate is disclosed, which has detergent and anti-oxidant properties, for use as a metal based detergent additive. An alkyl salicylic acid is derived from the alkylation of salicylic acid with styrene. The neutralization and subsequent overbasing of neutral salt results in an alkaline detergent, such as calcium or magnesium salicylate. The resulting detergent is a salicylic acid having multi-styrenated chains, which provide oil solubility. A method for making such a detergent is also disclosed.
    Type: Grant
    Filed: July 22, 2003
    Date of Patent: August 8, 2006
    Assignee: Crompton Co./Cie
    Inventors: Ronald J. Muir, William D. Olson
  • Patent number: 7083165
    Abstract: In a side bearing pad assembly two housings are provided, each having a bore of such size and orientation that the housings slide telescopically one within the other. When assembled the bores constitute a single internal cavity which houses resilient members. Each housing is mounted onto a load bearing member. The biasing resilient members urge the load bearing members apart when a compressive load is imposed on either of such members. The resilient members respond in a non-linear manner to force exerted on them.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: August 1, 2006
    Assignee: Uniroyal Chemical Company, Inc.
    Inventor: Richard L. Palinkas
  • Patent number: 7045654
    Abstract: A process is disclosed for the production of alkyl salicylic acids wherein the process comprises reacting salicylic acid with an olefin having at least four carbon atoms at elevated temperature in the presence of a perfluoroalkylsulfonic acid, an alkylsulfonic acid, or an acidic clay as a catalyst.
    Type: Grant
    Filed: October 21, 2003
    Date of Patent: May 16, 2006
    Assignee: Crompton Corporation
    Inventor: Steven J. Hobbs
  • Patent number: 7037974
    Abstract: A poly(?-olefin) copolymer obtained from the polymerization of at least one ?-olefin having from 2 to about 20 carbon atoms and at least one bulky olefin, the process comprising polymerizing the monomers in the presence of hydrogen and a catalytically effective amount of a catalyst comprising the product obtained by combining a metallocene procatalyst with a cocatalyst; lubricant compositions comprising such poly(?-olefin) copolymer; and a method for improving the viscosity index of a lubricant composition using such poly(?-olefin) copolymer.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: May 2, 2006
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Anthony DiMaio, Thomas P. Matan
  • Patent number: 7022220
    Abstract: Disclosed herein is a method for inhibiting the premature polymerization of ethylenically unsaturated monomers comprising adding to said monomers an effective amount of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds. Also disclosed is a composition of matter comprising: A) an ethylenically unsaturated monomer and B) an effective inhibiting amount, sufficient to prevent premature polymerization during distillation or purification of said ethylenically unsaturated monomer, of at least one inhibitor selected from the group consisting of C-nitrosoaniline and quinone imine oxime compounds used together with an effective amount of oxygen or air to enhance the inhibiting activity of said inhibitor.
    Type: Grant
    Filed: November 10, 2003
    Date of Patent: April 4, 2006
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Brigitte Benage, Gerald J. Abruscato, Andrew J. Eisenstein
  • Patent number: 7009072
    Abstract: The invention is a process for producing alkaline earth metal salicylates for use as lubricant detergents and to compositions prepared by the process. The process comprises two steps. Step 1 is the alkylation of salicylic acid is conducted using C14 or greater linear ?-olefins to produce alkyl salicylic acids in commercially acceptable yields. The alkylation conditions produce predominately mono-substituted para alkyl salicylic acids that are oil soluble. Step 2 is the oil soluble acid is subsequently neutralized and overbased by carbonation of lime using CO2 in the presence of a promoter and a surfactant. The reaction mixture after overbasing is filtered and solvents are removed by distillation. Alternatively, alkyl salicylic acid can be reacted with a previously overbased alkaline earth sulfonate, e.g., calcium sulfonate, to produce alkaline earth salicylate salts comprising varying percentages of dispersed alkaline earth carbonate salts.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: March 7, 2006
    Assignee: Crompton Corporation
    Inventor: Ronald J. Muir
  • Patent number: 6984684
    Abstract: An aluminum hydroxide composition is disclosed, having diminished tendency to cause discoloration on heating at 177° C. of a plastic composition whose major polymeric component is polyvinyl chloride, comprising aluminum hydroxide and an amount, effective in diminishing discoloration, of at least one inorganic perchlorate salt selected from the group consisting of alkali metal perchlorates and alkaline earth metal perchlorates.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: January 10, 2006
    Assignee: Crompton Corporation
    Inventors: Kook Jin Bae, Stuart D. Brilliant
  • Patent number: 6943202
    Abstract: A radiation-curable polyurethane is obtained from the reaction of a low free diisocyanate polyurethane prepolymer and an acrylic monomer.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: September 13, 2005
    Assignee: Crompton Corporation
    Inventors: Zhenya Zhu, Igor V. Khudyakov, Ronald O. Rosenberg
  • Patent number: 6939903
    Abstract: A process for preparing a composite material is disclosed wherein the process comprises: A) sizing a natural fiber with a reactive organosilane; B) mixing the sized natural fiber with a polyolefin resin; and C) adding a functionalized polyolefin coupling agent to the mixture of the sized natural fiber and the polyolefin resin to provide said composite material.
    Type: Grant
    Filed: April 16, 2003
    Date of Patent: September 6, 2005
    Assignee: Crompton Corporation
    Inventors: William D. Sigworth, Roger A. Cheney, Louis M. Panzer, Henry L. Mei
  • Patent number: 6930183
    Abstract: Disclosed herein is an antioxidant that is an alkylated iminodibenzyl of the general formula: wherein: R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, alkyl moieties, and alkenyl moieties; and R5, R6, R7, and R8 are independently selected from the group consisting of hydrocarbyl moieties and hydrogen.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: August 16, 2005
    Assignee: Crompton Corporation
    Inventors: Karl J. Duyck, Theodore E. Nalesnik
  • Patent number: 6926767
    Abstract: A storage stable aqueous dispersion useful in preparing sizing compositions for glass fibers contains a normally solid nucleating agent, a nonionic surfactant, and a base. The nucleating agent is a mixture of an aliphatic monocarboxylic acid and an aliphatic dicarboxylic acid. Also disclosed are the process of making the dispersion, and the use of the sized glass fibers in glass fiber reinforced polyolefin composites having improved mechanical properties such as tensile strength, flexural strength, and notched and unnotched IZOD.
    Type: Grant
    Filed: November 21, 2001
    Date of Patent: August 9, 2005
    Assignee: Uniroyal Chemical Company, Inc.
    Inventor: Bing-Lin Chen
  • Patent number: 6919389
    Abstract: The invention discloses a stabilized resin composition comprising a thermoplastic resin and a stabilizing benzimidazole based additive compound. In a second embodiment, the invention discloses a method to make a stabilized composition comprising a benzimidazole based stabilizing compound and a resin, said method comprising mixing said benzimidazole based stabilizing compound with said resin.
    Type: Grant
    Filed: March 13, 2003
    Date of Patent: July 19, 2005
    Assignee: Crompton Corporation
    Inventors: William Palmer Enlow, Marshall D. Moore, Vaikunth Sitaram Prabhu, Tilak T. Raj, Arakali Srinivasarao Radhakrishna, Raju Kharatkar