Abstract: An intermediate clear barrier coat is composed of at least one polymer or oligomer or combination in an aqueous or organic solvent carrier. This layer is placed between a basecoat layer containing pigment and a low VOC clearcoat layer and inhibits the components of the low VOC clear topcoat from inducing a shift of color in the basecoat.
Abstract: A coating composition based on amines, aldimines and isocyanates which forms a polyurea coating or film. These coating compositions are especially useful in the automotive refinish industry due to the cure rate at ambient conditions. The coatings of these compositions can be useful for obtaining low VOC (Volatile Organic Content) levels.
Type:
Grant
Filed:
July 31, 1995
Date of Patent:
August 26, 1997
Assignee:
BASF Corporation
Inventors:
Thomas J. Laginess, Sudhakar Dantiki, Brian P. Koevenig, Rajnikant P. Shah
Abstract: Improved basecoat--clearcoat paint coating compositions which may be ambient cured are disclosed. The coating compositions comprise:1) a hydroxyl functional coreactant,2) at least one anhydride functional coreactant and,3) a carbodiimide compound.The improved compositions cure at a rate especially useful as refinish paint compositions.
Type:
Grant
Filed:
December 27, 1994
Date of Patent:
November 26, 1996
Assignee:
BASF Corporation
Inventors:
Patrick J. Mormile, Rajnikant P. Shah, Anthony J. Tye
Abstract: A process for removing volatile constituents from a polymer dispersion or solution by stripping with a carrier gas is disclosed. The carrier gas being, in the case of a polymer solution, the vapor of the solvent used for the polymer solution as an inert gas saturated with said vapor. In the case of a polymer dispersion, the vapor of the dispersing medium used for the polymer dispersion or an inert gas saturated with said vapor. In both processes certain amount of the carrier gas is passed through the polymer dispersion or solution, the volatile constituents taken up the carrier gas on passage through the polymer dispersion or solution are then removed from the carrier gas in such a manner that the energy content of the carrier gas remains essentially unchanged. The carrier gas thus obtained is then reused for further removal of volatile constituents from the same polymer dispersion or solution by stripping.
Abstract: A composite fiber of at least two different polymers, one of which is water-insoluble and selected from the group consisting of polyester, polyamide and copolymers therefrom and the other is water-dissipatable, having a plurality of at least 19 segments of the water-insoluble polymer, uniformly distributed across the cross-section of the fiber and being surrounded by the water-dissipatable polymer, a process for the manufacture of such a fiber and a process for the manufacture of microfibers therefrom.
Abstract: Novel reactive carbodiimide compounds and their method of preparation are disclosed. These reactive carbodiimide compounds are especially useful in automotive paint compositions and more particularly in low volatile organic content (VOC) automotive paint compositions.
Type:
Grant
Filed:
July 21, 1993
Date of Patent:
October 18, 1994
Assignee:
BASF Corporation
Inventors:
Anthony J. Tye, George G. Beck, Patrick J. Mormile
Abstract: A low-foaming resin-fortified latex comprising a dispersed acrylic polymer, polyelectrolyte resin and a non-ionic emulsifier with an HLB value of 13 or less.
Type:
Grant
Filed:
June 21, 1993
Date of Patent:
February 8, 1994
Assignee:
BASF Corporation
Inventors:
Basil Wasyliw, Edward Stone, John G. Pucknat
Abstract: Coating Compositions are disclosed which may be ambient cured and are especially useful in refinish paint compositions. The Coating Compositions comprise at least one hydroxy functional resin, at least one isocyanate functional resin and a aldimine or ketimine.
Type:
Grant
Filed:
September 4, 1991
Date of Patent:
May 25, 1993
Assignee:
BASF Corporation
Inventors:
Patrick J. Mormile, Sudhakar Dantiki, Daniel Guyomard, Stewart Shepler, Bradley M. Richards
Abstract: There is disclosed a metallic and nonmetallic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before appling the base coat coating. A water reducible acrylic resin with nonionic and acid functionality derived from vinyl monomers having nonionic and urethane functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a wetter application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
Type:
Grant
Filed:
July 13, 1990
Date of Patent:
April 20, 1993
Assignee:
BASF Corporation
Inventors:
James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones
Abstract: A non-isocyanate flexibilizer additive is provided which finds utility in coating systems such as alkyds, polyesters, acrylic/polyester, alkyd/acrylic, carboxy/epoxy, polyether/urethane, epoxy/polyester, other epoxy, and urea and melamine formaldehyde systems. The non-isocyanate functional flexibilizer has the formula; B--C(O)--NW--A--NX--C(O)--K wherein A is selected from the group consisting fundamentally of polyesters, polyamides, polyureas, polyurethanes, acrylics; biuret, allophonate and urethane extended polyesters; wherein B and K are selected from the group consisting of --OR and --Z--R'--SiOR".sub.(3-n) R"".sub.n wherein R' is a divalent lower alkyl radical of from 1 to 18 carbon atoms, R is a lower alkyl radical of from 1 to 18 carbon atoms, Z is a member selected from the group consisting of S and NR", W and X are selected from H and lower alkyl radicals of from 1 to 10 carbon atoms, wherein R", R" and R"" are H or a lower alkyl radical of from 1-18 carbon atoms, and wherein n is 0, 1 or 2.
Type:
Grant
Filed:
July 7, 1992
Date of Patent:
March 16, 1993
Assignee:
BASF Corporation
Inventors:
Gerald L. Bajc, Thomas E. Noseworthy, James M. Cameron
Abstract: Alkali-soluble resins, their preparation and use are disclosed herein. The resins are carboxylated polyamide/acrylic resins and are synthesized in a two-step fusion process in which a polyamide is first condensed with a carboxylated rosin and this intermediate product is then further condensed with an acrylic or styrene/acrylic copolymer.
Type:
Grant
Filed:
September 21, 1988
Date of Patent:
February 2, 1993
Assignee:
BASF Corporation
Inventors:
Sobhy El-Hefnawi, Shailesh C. Shah, Basil Wasyliw
Abstract: Novel water-soluble compositions are described. In particular, water soluble polyamide-acrylic, polyamide-styrene acrylic and polyamide-styrene maleic resins are disclosed as well as novel methods for their production.
Abstract: There is disclosed a metallic and nonmetallic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before appling the base coat coating. A water reducible acrylic resin with nonionic and acid functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a wetter application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
December 1, 1992
Assignee:
BASF Corporation
Inventors:
James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones
Abstract: Blends of styrene-butadiene rubber and PVC latices in a dry weight ratio of 45:10 to 55:70 are useful to form heat sealable films. The mixture does not contain plasticizers and thus reduces environmental concerns during processing. The resulting film have good clarity and flexibility and may be used to seal textiles, non-wovens and boards.
Abstract: There is disclosed a metallic and nonmettalic water borne base coat compositions exhibiting excellent appearance. A method for long term stability and the introduction of aluminum flake pigments into a water borne coating is also disclosed. The method is based on storing the aluminum flake in a solvent environment with introduction of the aluminum flake in to the aqueous environment just before applying the base coat coating. A water reducible acrylic resin with nonionic and acid functionality has been disclosed that allows for direct introduction of aluminum flake in to an aqueous environment. The coating vehicle is based on acrylic latex vehicle which exhibits excellent drying and film properties. The rheology control agent employed allows for a drier application of the coating to the substrate. The coating compositions disclosed are also in compliance with current and proposed volatile organic compound regulations.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
November 24, 1992
Assignee:
BASF Corporation
Inventors:
James L. Anderson, Jr., Horst J. Finkenauer, David L. Newton, Jeff P. Jones, Craig J. McClanahan
Abstract: A gas barrier film-surfaced foamed sealant composition, especially useful for application to mine stoppings and other geological formations, is derived from a foamed sealant-forming medium comprising an aqueous elastomeric latex binder such as a styrene-butadiene rubber (SBR) latex, a particulate filler such as clay, a gelling agent such as ammonium sulfamate and a gaseous foaming agent such as air dispersed therein. The foamed sealant possesses a gas-impervious barrier film or coating on its exposed surface, e.g., one obtained from the aforesaid sealant-forming composition but which has not been foamed or frothed.
Abstract: A lithographic desensitizing ink comprises an alkyl amine, a hydroxylated polymerized oil and an acidic resin dissolved in a hydrophobic, hydroxylic solvent, and a pigment, wherein the amine is a secondary or tertiary amine or tertiary amine oxide with substituents of 4 to 12 carbon atoms and wherein the oil has a hydroxyl value of 50 to 250 and a viscosity (ASTM D 803) of 10 to 2000 stokes.
Abstract: An aqueous ink composition of an oil-soluble dye in a latex is disclosed. The oil-soluble dye is dispersed in a fortified latex comprising a blend of a distinct dispersed phase in a distinct soluble polymer phase. The soluble polymer generally has a weight-average molecular weight of about 5,000 to about 20,000 and an acid number of about 50 to 400. These novel ink compositions have been found to be especially useful in gravure and flexographic ink applications.
Type:
Grant
Filed:
June 29, 1990
Date of Patent:
May 19, 1992
Assignee:
BASF Corporation
Inventors:
William P. Keaveney, Reinhard J. Sappok
Abstract: Foam rubber articles may be prepared by shaping foamed latex into the desired configuration and gelling it. The gelled latex may then be cut to the required thickness to provide articles such as cosmetic puffs. The shaping process may use a disposable mold such as a circular polymeric casting or the mold may be permanent, such as glass, passing through a gelling chamber. The process reduces waste for products which has previously been cut from slab foam.
Abstract: A process for preparing an etherified polyoxyalkylene derivative of the formula ##STR1## wherein R.sup.1 and R.sup.4 are identical or different and are each independently C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.5 alkenyl, C.sub.6 -C.sub.20 aryl, C.sub.6 -C.sub.20 alkyl aryl, C.sub.6 -C.sub.20 cycloalkyl, and mixtures thereof, R.sup.2 and R.sup.3 are identical or different and independent of each other are H, CH.sub.3, CH.sub.3 CH.sub.2, and mixtures thereof, m, m' and n are identical or different and are each greater than or equal to zero, with the proviso that m+m'+n is from 3 to 300; by reacting a polyoxyalkylene compound of the formula.
Type:
Grant
Filed:
November 8, 1989
Date of Patent:
February 19, 1991
Assignee:
BASF Corporation
Inventors:
Ronald E. Greenough, Jay G. Otten, Stefan Birnbach, Jochen Houben