Patents Represented by Attorney, Agent or Law Firm Michele A. Kovaleski
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Patent number: 5500314Abstract: A process for the optical recording and storage of information in the form of bits by irradiating a recording material comprising a substrate coated with at least one layer of a pigment selected from the group of the dithiopyrrolopyrroles, dithioquinacridones, phthalocyanines or mixtures of several of these pigments as recording layer dotwise or linearly with laser light in the near infrared range (NIR range), which pigment (a) has a crystal modification having an absorption band in the NIR range, and (b) is in contact with a solid organic compound that changes the crystal modification of the pigment upon irradiation with laser light, so that (c) after irradiation the absorption in the NIR range is reduced, while the organic compound exhibits no absorption in the NIR range before and after irradiation.Type: GrantFiled: October 6, 1994Date of Patent: March 19, 1996Assignee: Ciba-Geigy CorporationInventors: Jin Mizuguchi, Gerald Giller
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Patent number: 5496920Abstract: An increase in the molecular weight of newly produced polyamides and recycled polyamide materials can be achieved by heating to above the melting point or glass transition point and adding of a bismaleimide and a sterically hindered hydroxyphenyl-alkyl-phosphonic acid ester or half-ester.Type: GrantFiled: May 27, 1994Date of Patent: March 5, 1996Assignee: Ciba-Geigy CorporationInventors: Rudolf Pfaendner, Kurt Hoffmann, Heinz Herbst
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Patent number: 5496875Abstract: The present invention relates to novel piperidine compounds of the formula (I) V5 V pV ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are as defined in the text. The compounds of the invention can be used as fight stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.Type: GrantFiled: July 11, 1994Date of Patent: March 5, 1996Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Roberto Scrima, Primo Carrozza
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Patent number: 5492949Abstract: Use of an inorganic or organic zinc compound and a terminal epoxide compound, optionally with chalk, gives a high level of stabilization of PVC.Type: GrantFiled: April 12, 1994Date of Patent: February 20, 1996Assignee: Ciba-Geigy CorporationInventors: Rolf Drewes, Markus Kolb, Karl Kuhn, Wolfgang Wehner
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Patent number: 5492564Abstract: The pigment form of the diketopyrrolopyrrole pigment of formula ##STR1## having high saturation, characterised by a chroma C*.sub.ab of at least 45 in the CIELAB system when incorporated in a plasticised PVC pressed sheet. This pigment has superior opacity and an unexpectedly high chroma.Type: GrantFiled: March 23, 1994Date of Patent: February 20, 1996Assignee: Ciba-Geigy CorporationInventors: Gary Wooden, Ingo Schloder, Olof Wallquist
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Patent number: 5489503Abstract: Novel UV absorbers of the bis- or tris-2'-hydroxyphenyltriazine type and their use in photographic materials, inks or recording materials for ink-jet printing, and surface coatings are described which conform to the formula ##STR1## in which the radicals R.sub.1 and R.sub.9 are as defined in claim 1.Type: GrantFiled: December 6, 1994Date of Patent: February 6, 1996Assignee: Ciba-Geigy Corp.Inventor: Vien V. Toan
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Patent number: 5489447Abstract: A description is given of carrier-bound compounds of the formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently of one another are hydrogen, halogen, nitro, cyano, CF.sub.3, C.sub.1 -C.sub.15 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.15 alkenyl, C.sub.1 -C.sub.12 haloalkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aryloxy, C.sub.7 -C.sub.12 arylalkyl, --CO.sub.2 R.sub.6, --COR.sub.6 or ##STR2## in which at least one of the radicals R.sub.1 to R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.15 alkyl, and, in addition, the radicals R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 together with the carbon atoms to which they are attached form a benzo or cyclohexenyl ring,R.sub.6 is C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkyl which is interrupted by oxygen, sulfur or >N--R.sub.9 ; or is C.sub.7 -C.sub.12 arylalkyl,R.sub.7 and R.sub.Type: GrantFiled: June 20, 1994Date of Patent: February 6, 1996Assignee: Ciba-Geigy CorporationInventors: Andreas Kramer, Adalbert Braig
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Patent number: 5489683Abstract: Novel piperidine-triazine compounds of the formula (Ia) and (Ib) suitable for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials. The meanings of R.sub.1, R.sub.2, R.sub.3, G.sub.1, G.sub.2, L.sub.1, L.sub.2, m and n are defined in the text.Type: GrantFiled: March 28, 1994Date of Patent: February 6, 1996Assignee: Ciba-Geigy CorporationInventors: Valerio Borzatta, Graziano Vignali, Fabrizio Guizzardi
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Patent number: 5488112Abstract: The invention relates to dimeric 2-(2'-hydroxyphenyl)benzotriazoles of the formula I ##STR1## in which p is 0 or 1; is C.sub.1 -C.sub.12 alkylene;R.sub.1 and R'.sub.1, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.18 aklyl, C.sub.1 -C.sub.18 alkoxy or --CN;R.sub.2 and R'.sub.2, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl or together are C.sub.2 -C.sub.12 alkylene or C.sub.2 -C.sub.12 hydroxyalkylene; andR.sub.3 and R'.sub.3, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.18 alkyl or C.sub.1 -C.sub.18 alkoxy.The compounds of formula I are highly suitable for the stabilization of organic material against the harmful effects of heat, oxygen and light, in particular UV radiation.Type: GrantFiled: February 22, 1995Date of Patent: January 30, 1996Assignee: Ciba-Geigy CorporationInventors: Dieter Reinehr, Jean-Pierre Bacher, Andre Schmitter
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Patent number: 5488108Abstract: A photographic material is described which comprises, on a base, blue-sensitive, green-sensitive and/or red-sensitive silver-halide emulsion layers and if desired a protection layer, a layer containing a UV absorber being arranged between the uppermost silver-halide emulsion layer and the protection layer or on top of the uppermost silver-halide emulsion layer, wherein the UV absorber conforms to the formula ##STR1## in which the radicals R.sub.1 and R.sub.12 are as defined in claim 1.Type: GrantFiled: August 11, 1994Date of Patent: January 30, 1996Assignee: Ciba-Geigy CorporationInventors: David G. Leppard, Kurt Burdeska, Mario Slongo
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Patent number: 5484943Abstract: Pyrrolo[3,4-c]pyrroles of formula ##STR1## wherein D and E are each independently of the other a group of formula ##STR2## The symbols Q, R.sub.8, R.sub.9, R.sub.10, R.sub.11, X, Y, Z, m and n are as defined in claim 1.These pyrrolo[3,4-c]pyrroles are distinguished by outstanding solid state fluorescence in the UV range as well as by the ease with which they can be converted to pyrrolopyrrole pigments even in the substrate in which they are incorporated.Type: GrantFiled: October 6, 1994Date of Patent: January 16, 1996Assignee: Ciba-Geigy CorporationInventors: John S. Zambounis, Zhimin Hao, Abul Iqbal
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Patent number: 5482548Abstract: The present invention provides a pigment composition comprising a diarylide pigment, a monoprimary amine, a diprimary amine and an inorganic compound having active oxide or hydroxide surfaces.Type: GrantFiled: October 25, 1994Date of Patent: January 9, 1996Assignee: Ciba-Geigy CorporationInventors: John A. Stirling, Edward J. Anderson, Carol J. Farnocchi
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Patent number: 5482547Abstract: Compositions comprisinga) an organic material of high molecular weight in the form of a paint or varnish or of a printing ink,b) a pigment composition comprising an organic pigment whose particle surface is provided with a tenacious coating of alkyl silicate, said coating being fixed by adsorption of an alkyl silicate on a layer that coats the surface of the pigment particles and consists essentially of partially hydrolyzed organic compounds of elements of group 4A or 4B of the Periodic System selected from the group consisting of chelates of formula ##STR1## wherein R.sub.1 is methyl, ethyl, methoxy or ethoxy, R.sub.2 is methyl or ethyl and R.sub.3 is halogen or C.sub.1 -C.sub.4 alkoxy, and M is Ti or Sn, and of esters of formulaM.sub.1 (OR.sub.4).sub.4 (III),wherein M.sub.1 is an element of group 4A or 4B of the Periodic System and R.sub.4 is C.sub.1 -C.sub.4 alkyl, which alkyl silicate is hydrolyzed before, during or after adsorption.Type: GrantFiled: February 3, 1994Date of Patent: January 9, 1996Assignee: Ciba-Geigy CorporationInventors: Philippe Bugnon, Jean Allaz
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Patent number: 5481023Abstract: There is disclosed a process for the preparation of compounds of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other C.sub.1 --C.sub.8 alkyl, m is 0, 1, 2 or 3, n is 1 or 2, and A, if n 32 1, is OR.sub.3, and R.sub.3 is C.sub.4 -C.sub.20 alkyl or C.sub.5 -C.sub.12 cycloalkyl, or A, if n=2, has the formula --O--C.sub.x H.sub.2x --O-- or --O--(CH.sub.2 CH.sub.2 O).sub.a CH.sub.2 CH.sub.2 O--, x is a number from 2 to 8 and a is a number from 1 to 12, by reacting a compound of formula II ##STR2## with a compound of formula III ##STR3## the reaction being carded out in the presence of an aluminium trialcoholate or triphenolate as catalyst.Type: GrantFiled: September 30, 1993Date of Patent: January 2, 1996Assignee: Ciba-Geigy CorporationInventors: Christoph Kleiner, Samuel Evans, Ralf Schmitt
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Patent number: 5481002Abstract: There are disclosed compounds ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently of one another hydrogen, a C.sub.1 -C.sub.12 alkyl group, a C.sub.1 -C.sub.12 alkoxy group, a C.sub.5 -C.sub.8 cycloalkyl group, a C.sub.5 -C.sub.8 cycloalkoxy group, a C.sub.5 -C.sub.8 cycloalkylthio group, a C.sub.6 -C.sub.10 aryl group, a C.sub.6 -C.sub.10 aryloxy group, a C.sub.6 -C.sub.10 arylthio group, nitro, halogen, cyano, --COOH, --COOR.sub.7, --NR.sub.8 R.sub.9 or --CONR.sub.8 R.sub.9, where R.sub.7 is C.sub.1 -C.sub.20 alkyl, C.sub.5 -C.sub.8 acycloalkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl, and R.sub.8 and R.sub.9 are each independently of the other hydrogen, C.sub.1 -C.sub.8 alkyl, phenyl or phenyl-C.sub.1 -C.sub.4 alkyl, X is nitrogen or CR.sub.4, Y is nitrogen or CR.sub.5 and Z is nitrogen or CR.sub.6, and R.sub.4, R.sub.5 and R.sub.6 are each independently of one another hydrogen, a straight-chain or branched C.sub.1 -C.sub.12 alkyl group or a C.sub.6 -C.sub.Type: GrantFiled: December 14, 1993Date of Patent: January 2, 1996Assignee: Ciba-Geigy CorporationInventors: Walter Fischer, Beat Schmidhalter, Heinz Wolleb
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Patent number: 5476886Abstract: Mass-coloured synthetic polyamide containing, as pigment, at least one diketopyrrolopyrrole pigment of formula ##STR1## wherein A and B are each independently of the other a radical of formula ##STR2## wherein Q is a --CONH.sub.2 group,m is 1 or 2,R.sub.1 and R.sub.2 are each independently of the other hydrogen, Cl, Br, CH.sub.3 or C.sub.2 H.sub.5,R.sub.3 is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or phenyl,X is a direct bond, --O--, --S--, --SO.sub.2 --, --CH.dbd.CH--, --CH.sub.2 -- or --C(CH.sub.3).sub.2 --, andY is --O-- or --S--.Polyamides mass-coloured with the pigments useful in the practice of this invention have exceptional heat stability and excellent lightfastness.Type: GrantFiled: July 18, 1994Date of Patent: December 19, 1995Assignee: Ciba-Geigy CorporationInventors: Olof Wallquist, Bernd Lamatsch
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Patent number: 5476949Abstract: Finely divided 1,4-diketopyrrolo[3,4-c]pyrroles of the formula ##STR1## where A and B are each independently of the other a radical of the formula ##STR2## wherein at least 84% by weight of the particles have a Stokes equivalent diameter of .ltoreq.0.25 .mu.m, and mixtures thereof.The substituents R.sub.1 and R.sub.2 are defined in claim 1.These pigments are notable for a very pure hue and outstanding transparency.Type: GrantFiled: July 21, 1994Date of Patent: December 19, 1995Assignee: Ciba-Geigy CorporationInventors: Olof Wallquist, Gary Wooden, Thomas Eichenberger, Ingo Schloder
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Patent number: 5476882Abstract: Light-stabilized polymer microparticles, which contain at least one light stabilizer, and processes for the preparation of these microparticles by polymerization of suitable monomers, at least a part of the polymerization being carried out in the presence of at least one light stabilizer, are described. The polymer microparticles can be used in coating compositions which comprise a disperse phase containing these particles and a liquid continuous phase.Coatings and finishes based on the compositions according to the invention are distinguished by improved weathering resistance, in particular by a high light stability.Type: GrantFiled: October 18, 1993Date of Patent: December 19, 1995Assignee: Ciba-Geigy CorporationInventors: Godwin Berner, Manfred Rembold, Jean Rody, Mario Slongo
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Patent number: 5472992Abstract: Compounds of the formula I ##STR1## in which R.sub.1 is C.sub.1 -C.sub.18 alkyl, cyclopentyl or cyclohexyl, and R.sub.2 and R.sub.3, independently of one another, are phenyl which is unsubstituted or monosubstituted to tetrasubstituted by halogen, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, with the proviso that R.sub.1 is not decyl if R.sub.2 and R.sub.3 are chlorine-substituted phenyl, are suitable for the photopolymerisation of compounds containing ethylenically unsaturated double bonds.Type: GrantFiled: April 28, 1994Date of Patent: December 5, 1995Assignee: Ciba-Geigy CorporationInventors: David G. Leppard, Manfred Kohler, Ljubomir Misev
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Patent number: 5473003Abstract: Compositions comprising an organic material which is sensitive to thermal, oxidative and/or actinic degradation and at least one compound of the formula I ##STR1## in which Z.sub.1 and Z.sub.2 independently of one another are C.sub.1 -C.sub.18 alkyl, C.sub.5 -C.sub.8 cycloalkyl, phenyl, phenyl-C.sub.1 -C.sub.4 alkyl or (C.sub.1 -C.sub.4 alkyl)phenyl andp is a number from 4 to 18,with the proviso that Z.sub.1 and Z.sub.2 are not simultaneously tertiary alkyl radicals. Some of the compounds of the formula I are novel.The compounds of the formula I can also be employed as stabilizers as a mixture with compounds of the formula VI and/or of the formula VII ##STR2## in which n and the radicals R.sup.1, R .sup.1 ' and A are as defined in claims 14 and 15.Type: GrantFiled: December 21, 1994Date of Patent: December 5, 1995Assignee: Ciba-Geigy CorporationInventors: Rita Pitteloud, Paul Dubs, Bernard Gilg