Patents Represented by Attorney N. E. Willis
  • Patent number: 4013714
    Abstract: Compounds represented by the formula ##EQU1## wherein Rx is ##EQU2## AND A is hydrogen, methyl, ethyl, CH.sub.2 OH or RxOH; M being alkali metal, ammonium, alkyl ammonium, or alkanol ammonium and Rz being hydrogen, alkyl, phenyl, phenyl alkyl, alkoxy alkyl, alkoxy phenyl or alkoxy phenyl alkyl are useful as complexing agents and/or detergency builders. The ester and acid forms of these compounds are useful as intermediates for their preparation.
    Type: Grant
    Filed: December 19, 1973
    Date of Patent: March 22, 1977
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 4007260
    Abstract: Dental creams, particularly translucent dental creams, containing finely divided synthetic amorphous silica polishing agents, such polishing agents have an average refractive index of from about 1.410 to 1.440.
    Type: Grant
    Filed: July 18, 1975
    Date of Patent: February 8, 1977
    Assignee: Monsanto Company
    Inventor: Keun Y. Kim
  • Patent number: 4000209
    Abstract: A process for the production of a catalyst for the synthesis of isoprene from isobutylene and formaldehyde which comprises providing a catalyst precursor comprising silica and alumina and modifying the catalyst precursor by treatment with an alkali metal hydroxide and subsequently neutralizing by treatment with a mineral acid, depositing a transition metal on the treated catalyst precursor and calcining to form the catalyst.
    Type: Grant
    Filed: November 5, 1975
    Date of Patent: December 28, 1976
    Assignee: Monsanto Company
    Inventors: Ronald O. Downs, James C. Burleson
  • Patent number: 4000178
    Abstract: Method of ammoxidizing paraffin hydrocarbons to unsaturated nitriles in a transported bed reactor at a temperature of from 350.degree. to 550.degree. C. using a catalyst comprising antimony and uranium.
    Type: Grant
    Filed: September 19, 1975
    Date of Patent: December 28, 1976
    Assignee: Monsanto Company
    Inventors: Ronald H. Kahney, Talmage D. McMinn, Jr.
  • Patent number: 3994984
    Abstract: Chloromethyl ether impurities are removed from alkylbenzyl chlorides containing the same by treatment with an aqueous base.
    Type: Grant
    Filed: May 9, 1975
    Date of Patent: November 30, 1976
    Assignee: Monsanto Company
    Inventor: Roger L. Kidwell
  • Patent number: 3993574
    Abstract: Compositions comprising a mixture of from 60% to 95% by weight ##EQU1## (M is alkali metal or ammonium) and, correspondingly, 5% to 40% by weight sodium carbonate function as a synergistic detergency builder.
    Type: Grant
    Filed: August 22, 1975
    Date of Patent: November 23, 1976
    Assignee: Monsanto Company
    Inventors: Thomas Christ, Robert P. Langguth
  • Patent number: 3983161
    Abstract: An oxidation process for the conversion of an unsaturated amine to an unsaturated nitrile in which the oxidation reaction takes place in the presence of a nitrogen base, a cuprous halide and an alcoholic compound.
    Type: Grant
    Filed: December 9, 1974
    Date of Patent: September 28, 1976
    Assignee: Monsanto Company
    Inventor: John S. McConaghy, Jr.
  • Patent number: 3979467
    Abstract: A process for the nitration of halogenated aromatic compounds is improved by carrying out the nitration in the presence of a phosphorus compound in an amount sufficient to produce an ortho-directing effect. Phosphoric acid is particularly effective over a wide range of temperatures.
    Type: Grant
    Filed: May 9, 1973
    Date of Patent: September 7, 1976
    Assignee: Monsanto Company
    Inventor: Ignatius Schumacher
  • Patent number: 3975408
    Abstract: Refined dicarboxylic acid anhydrides such as maleic anhydride are provided with improved color stability by a treating agent selected from the group consisting of chlorine and halides or elements in group IVb of the periodic table, the transition elements, vanadium, chromium, manganese, mercury, silicon, phosphorus, bismuth, antimony, lead, cerium and sulfur.
    Type: Grant
    Filed: October 31, 1972
    Date of Patent: August 17, 1976
    Assignee: Monsanto Company
    Inventors: Ronald J. Boyer, Raymond E. Stenseth, Richard J. Sheehan
  • Patent number: 3972982
    Abstract: Fluorine compounds are removed from aqueous phosphoric acid by extraction with a mixture of a silane and a long-chain hydrocarbyl amine.BACKGROUND OF THE INVENTIONThis invention relates to a process for removing fluorine from aqueous phosphoric acid.It is known that wet-process phosphoric acid obtained by acidulation of phosphate rock contains substantial amounts of fluorine, predominantly in the form of fluorine compounds such as fluorophosphates and various metal fluorides. Even following purification by known extraction processes, for example, extraction with various organic amines, ethers, etc., such phosphoric acid generally remains contaminated with undesirably high quantities of fluorine compounds with fluorine contents of 1,000 parts per million (ppm) by weight or more not being uncommon.Fluorine contents of this magnitude introduce complications relative to the use of the acid in various applications.
    Type: Grant
    Filed: March 3, 1975
    Date of Patent: August 3, 1976
    Assignee: Monsanto Company
    Inventor: Louis F. Centofanti
  • Patent number: 3972922
    Abstract: Sequestrant compounds represented by the ##EQU1## wherein X is alkali metal or hydrogen, are prepared by oxidation of a compound represented by the formula ##EQU2##
    Type: Grant
    Filed: March 18, 1974
    Date of Patent: August 3, 1976
    Assignee: Monsanto Company
    Inventors: Russel D. Harken, F. Wyman Morgan
  • Patent number: 3970698
    Abstract: Hydroxy ether carboxylates represented by the formula ##EQU1## wherein M is alkali metal, ammonium, alkyl ammonium or alkanol ammonium and A is hydrogen, methyl, ethyl, or CH.sub.2 OH, are useful as complexing agents and detergency builders. The ester and acid forms of such compounds are useful as intermediates for preparation of the salts.
    Type: Grant
    Filed: December 19, 1973
    Date of Patent: July 20, 1976
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 3965169
    Abstract: Trisodium carboxymethyloxysuccinate monohydrate is useful as a metal complexing agent, detergency builder and desiccant.
    Type: Grant
    Filed: February 25, 1974
    Date of Patent: June 22, 1976
    Assignee: Monsanto Company
    Inventor: N. Earl Stahlheber
  • Patent number: 3957890
    Abstract: It was found that the process for the nitration of halogenated aromatic compounds is improved by carrying out the nitration in the presence of a phosphorus compound in an amount sufficient to produce an ortho-directive effect. The addition of polyvalent metal elements such as vanadium, molybdenum, tungsten, and other elements that have the capability of existing in a variety of oxidation states, to a mixture of phosphoric and nitric acid improves the yield of the nitrohaloaromatics without affecting the isomer ratio.
    Type: Grant
    Filed: August 20, 1973
    Date of Patent: May 18, 1976
    Assignee: Monsanto Company
    Inventor: Ignatius Schumacher
  • Patent number: 3954884
    Abstract: This invention relates to methods for rapidly producing beta hydroxy ethylene glycol ethers by reacting internal epoxyalkanes with mono or poly ethylene glycols in the presence of critical amounts of acidic catalysts under controlled temperature conditions.
    Type: Grant
    Filed: July 24, 1972
    Date of Patent: May 4, 1976
    Assignee: Monsanto Company
    Inventor: Roger L. Kidwell
  • Patent number: 3952054
    Abstract: Diglycolic acid is prepared by oxidation of p-dioxanone.
    Type: Grant
    Filed: December 5, 1974
    Date of Patent: April 20, 1976
    Assignee: Monsanto Company
    Inventor: Chung Y. Shen
  • Patent number: 3950388
    Abstract: Organic compounds having a substituent represented by the formula ##EQU1## wherein M is alkali metal or ammonium which are useful complexing agents for metal and/or alkaline earth metal ions are prepared by reaction of a conjugate base of a hemiketal of a ketomalonic acid diester and an alcohol with a bromo or iodo acetate ester and saponifying the resulting product.
    Type: Grant
    Filed: May 24, 1974
    Date of Patent: April 13, 1976
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 3940424
    Abstract: Compounds represented by the formula ##EQU1## and salts thereof represented by the formula ##EQU2## wherein Q is bromine, chlorine, --O-alkali metal or OH; R is hydrogen or an alkyl group containing from 1 to 20 carbon atoms; M is alkali metal; and Rx is ##EQU3## n being an integer from 4 to 10, or ##EQU4## Rz being hydrogen, alkyl phenyl alkyl, alkoxy alkyl, alkoxy phenyl, alkoxy phenyl alkyl or --COOX, X being R or M, are useful as intermediates for the preparation of sequestrants.
    Type: Grant
    Filed: December 19, 1973
    Date of Patent: February 24, 1976
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 3939262
    Abstract: Dental creams, particularly translucent dental creams, containing finely divided synthetic amorphous silica polishing agents, such polishing agents have an average refractive index of from about 1.410 to 1.440.
    Type: Grant
    Filed: January 21, 1974
    Date of Patent: February 17, 1976
    Assignee: Monsanto Company
    Inventor: Keun Y. Kim