Patents Represented by Attorney N. E. Willis
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Patent number: 4013714Abstract: Compounds represented by the formula ##EQU1## wherein Rx is ##EQU2## AND A is hydrogen, methyl, ethyl, CH.sub.2 OH or RxOH; M being alkali metal, ammonium, alkyl ammonium, or alkanol ammonium and Rz being hydrogen, alkyl, phenyl, phenyl alkyl, alkoxy alkyl, alkoxy phenyl or alkoxy phenyl alkyl are useful as complexing agents and/or detergency builders. The ester and acid forms of these compounds are useful as intermediates for their preparation.Type: GrantFiled: December 19, 1973Date of Patent: March 22, 1977Assignee: Monsanto CompanyInventor: Kent P. Lannert
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Patent number: 4007260Abstract: Dental creams, particularly translucent dental creams, containing finely divided synthetic amorphous silica polishing agents, such polishing agents have an average refractive index of from about 1.410 to 1.440.Type: GrantFiled: July 18, 1975Date of Patent: February 8, 1977Assignee: Monsanto CompanyInventor: Keun Y. Kim
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Patent number: 4000209Abstract: A process for the production of a catalyst for the synthesis of isoprene from isobutylene and formaldehyde which comprises providing a catalyst precursor comprising silica and alumina and modifying the catalyst precursor by treatment with an alkali metal hydroxide and subsequently neutralizing by treatment with a mineral acid, depositing a transition metal on the treated catalyst precursor and calcining to form the catalyst.Type: GrantFiled: November 5, 1975Date of Patent: December 28, 1976Assignee: Monsanto CompanyInventors: Ronald O. Downs, James C. Burleson
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Patent number: 4000178Abstract: Method of ammoxidizing paraffin hydrocarbons to unsaturated nitriles in a transported bed reactor at a temperature of from 350.degree. to 550.degree. C. using a catalyst comprising antimony and uranium.Type: GrantFiled: September 19, 1975Date of Patent: December 28, 1976Assignee: Monsanto CompanyInventors: Ronald H. Kahney, Talmage D. McMinn, Jr.
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Patent number: 3994984Abstract: Chloromethyl ether impurities are removed from alkylbenzyl chlorides containing the same by treatment with an aqueous base.Type: GrantFiled: May 9, 1975Date of Patent: November 30, 1976Assignee: Monsanto CompanyInventor: Roger L. Kidwell
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Patent number: 3993574Abstract: Compositions comprising a mixture of from 60% to 95% by weight ##EQU1## (M is alkali metal or ammonium) and, correspondingly, 5% to 40% by weight sodium carbonate function as a synergistic detergency builder.Type: GrantFiled: August 22, 1975Date of Patent: November 23, 1976Assignee: Monsanto CompanyInventors: Thomas Christ, Robert P. Langguth
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Patent number: 3983161Abstract: An oxidation process for the conversion of an unsaturated amine to an unsaturated nitrile in which the oxidation reaction takes place in the presence of a nitrogen base, a cuprous halide and an alcoholic compound.Type: GrantFiled: December 9, 1974Date of Patent: September 28, 1976Assignee: Monsanto CompanyInventor: John S. McConaghy, Jr.
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Patent number: 3979467Abstract: A process for the nitration of halogenated aromatic compounds is improved by carrying out the nitration in the presence of a phosphorus compound in an amount sufficient to produce an ortho-directing effect. Phosphoric acid is particularly effective over a wide range of temperatures.Type: GrantFiled: May 9, 1973Date of Patent: September 7, 1976Assignee: Monsanto CompanyInventor: Ignatius Schumacher
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Patent number: 3975408Abstract: Refined dicarboxylic acid anhydrides such as maleic anhydride are provided with improved color stability by a treating agent selected from the group consisting of chlorine and halides or elements in group IVb of the periodic table, the transition elements, vanadium, chromium, manganese, mercury, silicon, phosphorus, bismuth, antimony, lead, cerium and sulfur.Type: GrantFiled: October 31, 1972Date of Patent: August 17, 1976Assignee: Monsanto CompanyInventors: Ronald J. Boyer, Raymond E. Stenseth, Richard J. Sheehan
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Patent number: 3972982Abstract: Fluorine compounds are removed from aqueous phosphoric acid by extraction with a mixture of a silane and a long-chain hydrocarbyl amine.BACKGROUND OF THE INVENTIONThis invention relates to a process for removing fluorine from aqueous phosphoric acid.It is known that wet-process phosphoric acid obtained by acidulation of phosphate rock contains substantial amounts of fluorine, predominantly in the form of fluorine compounds such as fluorophosphates and various metal fluorides. Even following purification by known extraction processes, for example, extraction with various organic amines, ethers, etc., such phosphoric acid generally remains contaminated with undesirably high quantities of fluorine compounds with fluorine contents of 1,000 parts per million (ppm) by weight or more not being uncommon.Fluorine contents of this magnitude introduce complications relative to the use of the acid in various applications.Type: GrantFiled: March 3, 1975Date of Patent: August 3, 1976Assignee: Monsanto CompanyInventor: Louis F. Centofanti
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Patent number: 3972922Abstract: Sequestrant compounds represented by the ##EQU1## wherein X is alkali metal or hydrogen, are prepared by oxidation of a compound represented by the formula ##EQU2##Type: GrantFiled: March 18, 1974Date of Patent: August 3, 1976Assignee: Monsanto CompanyInventors: Russel D. Harken, F. Wyman Morgan
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Patent number: 3970698Abstract: Hydroxy ether carboxylates represented by the formula ##EQU1## wherein M is alkali metal, ammonium, alkyl ammonium or alkanol ammonium and A is hydrogen, methyl, ethyl, or CH.sub.2 OH, are useful as complexing agents and detergency builders. The ester and acid forms of such compounds are useful as intermediates for preparation of the salts.Type: GrantFiled: December 19, 1973Date of Patent: July 20, 1976Assignee: Monsanto CompanyInventor: Kent P. Lannert
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Patent number: 3965169Abstract: Trisodium carboxymethyloxysuccinate monohydrate is useful as a metal complexing agent, detergency builder and desiccant.Type: GrantFiled: February 25, 1974Date of Patent: June 22, 1976Assignee: Monsanto CompanyInventor: N. Earl Stahlheber
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Patent number: 3957890Abstract: It was found that the process for the nitration of halogenated aromatic compounds is improved by carrying out the nitration in the presence of a phosphorus compound in an amount sufficient to produce an ortho-directive effect. The addition of polyvalent metal elements such as vanadium, molybdenum, tungsten, and other elements that have the capability of existing in a variety of oxidation states, to a mixture of phosphoric and nitric acid improves the yield of the nitrohaloaromatics without affecting the isomer ratio.Type: GrantFiled: August 20, 1973Date of Patent: May 18, 1976Assignee: Monsanto CompanyInventor: Ignatius Schumacher
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Patent number: 3954884Abstract: This invention relates to methods for rapidly producing beta hydroxy ethylene glycol ethers by reacting internal epoxyalkanes with mono or poly ethylene glycols in the presence of critical amounts of acidic catalysts under controlled temperature conditions.Type: GrantFiled: July 24, 1972Date of Patent: May 4, 1976Assignee: Monsanto CompanyInventor: Roger L. Kidwell
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Patent number: 3952054Abstract: Diglycolic acid is prepared by oxidation of p-dioxanone.Type: GrantFiled: December 5, 1974Date of Patent: April 20, 1976Assignee: Monsanto CompanyInventor: Chung Y. Shen
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Patent number: 3950388Abstract: Organic compounds having a substituent represented by the formula ##EQU1## wherein M is alkali metal or ammonium which are useful complexing agents for metal and/or alkaline earth metal ions are prepared by reaction of a conjugate base of a hemiketal of a ketomalonic acid diester and an alcohol with a bromo or iodo acetate ester and saponifying the resulting product.Type: GrantFiled: May 24, 1974Date of Patent: April 13, 1976Assignee: Monsanto CompanyInventor: Kent P. Lannert
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Patent number: 3940424Abstract: Compounds represented by the formula ##EQU1## and salts thereof represented by the formula ##EQU2## wherein Q is bromine, chlorine, --O-alkali metal or OH; R is hydrogen or an alkyl group containing from 1 to 20 carbon atoms; M is alkali metal; and Rx is ##EQU3## n being an integer from 4 to 10, or ##EQU4## Rz being hydrogen, alkyl phenyl alkyl, alkoxy alkyl, alkoxy phenyl, alkoxy phenyl alkyl or --COOX, X being R or M, are useful as intermediates for the preparation of sequestrants.Type: GrantFiled: December 19, 1973Date of Patent: February 24, 1976Assignee: Monsanto CompanyInventor: Kent P. Lannert
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Patent number: 3939262Abstract: Dental creams, particularly translucent dental creams, containing finely divided synthetic amorphous silica polishing agents, such polishing agents have an average refractive index of from about 1.410 to 1.440.Type: GrantFiled: January 21, 1974Date of Patent: February 17, 1976Assignee: Monsanto CompanyInventor: Keun Y. Kim