Abstract: A moisture curable composition that includes a polyurethane prepolymer comprising the reaction product of a) a polyol having an unsaturation of less than 0.02 meq/g; and b) a polyfunctional isocyanate, where the composition forms a pressure sensitive adhesive when cured, is disclosed.

Abstract: Adhesive formulations are blends of aqueous polymer dispersions and a hydrophobic plasticizer. The blended dispersed polymers include at least one hard sulfonated polyester urethane, at least one soft non-sulfonated polyester urethane, and at least one polar non-polyurethane water-based polymer or copolymer. A high molecular weight elastomeric non-sulfonated polyurethane polymer and a crosslinker are optional further components in the blend. The formulations are useful as non-heat activating, one-component adhesives which generate excellent green strength, water and heat resistant bonds.

Abstract: A method of bonding two substrates at least one of which is a rubbery polymeric material having carbon-carbon double bonds on the polymer backbone, the method comprising: a) applying an aqueous polyurethane dispersion adhesive composition to at least one of the substrates, the adhesive compostion further comprising an epoxy resin; b) allowing the composition to dry; and then c) joining the substrates with heating to activate the adhesive. The substrates are suitably footwear materials such as a molded rubber outer sole which has been first primed with a chlorinating primer, and a foam midsole of a material such as a lightly crosslinked ethylene vinyl acetate. The process results in bonded assemblies having improved humidity resistance.

Abstract: This invention relates to a foamable composition comprising at least two parts. More specifically, the first part comprises at least one polyol, at least one gelling agent, and at least one blowing agent wherein the first part comprises an effective amount of hydrophobic ingredients and a second part comprising at least one isocyanate. A foam mass can be prepared by a method of combining a polyol component with an isocyanate component substantially free of urethane prepolymer and applying the mixture to a void or substrate. The invention also relates to methods of using certain polyurethane compositions in the repair of surface defects or for the reinforcement of structural members such as spike holes left after spike removal from railroad ties during road bed maintenance or repair. This invention further relates to a method of foaming certain polyurethane compositions in the presence of water.

Abstract: Adhesive compositions are disclosed that include a block copolymer that includes monomers selected from the group consisting of styrene, isoprene, butadiene, and combinations thereof, from about 0.5% to about 10% by weight surfactant, and a tackifying agent. The adhesive composition has a surface tension of at least about 34 dynes/cm2.

Abstract: The present invention relates to water-based pressure sensitive adhesives comprising at least one water-based polymer and at least one aminoplast resins such as melamine-formaldehyde resins, urea-formaldehyde resins, alkylated melamine-formaldehyde resins and combinations thereof. More particularly, the invention relates to water-based pressure sensitive adhesives comprising the reaction product of aqueous polymer dispersions and water dispersible melamine-formaldehyde resins. The pressure sensitive adhesives are characterized as having enhanced bonding characteristics including loop tack, peel strength, and shear strength making them particularly useful for the manufacture of dry-bonded laminates, tapes, labels, medical patches and devices, flexible packages, furnace ducts, exterior insulating finish system and the like.

Abstract: This invention relates to a hot melt adhesive composition in pellet form. The hot melt adhesive composition is pressure sensitive, having a storage modulus, G′, at 25° C., of less than about 5×106 dynes/cm2. The pellets are coated with a pelletizing aid on the surface at a concentration preferably ranging from about 1 wt-% to about 30 wt-%. The pelletizing aid is a hot melt adhesive component or a material which does not substantially adversely affect the adhesive properties.

Abstract: A hot melt adhesive composition can be made using a polyester derived from 2-propanoic acid (lactic acid). A thermoplastic resin grade polyester can be formulated into a functional adhesive using adhesive components. A lower molecular weight material can be used as a tackifying resin with a biodegradable/compostable resin in a formulated hot melt adhesive. The adhesive material can be made pressure sensitive and can be made entirely by a degradable by combining the polyester polymer with other biodegradable/compostable ingredients. The resulting adhesive composition that can be used in a variety of applications. The biodegradable/compostable adhesive material can be used as a substitute for non-biodegradable materials made from commercial polymers that resist attack by bacteria, fungi and other microbial populations. The hot melt adhesives can be used in (e.g.) packaging and the manufacture of disposable articles which are made from degradable materials.