Abstract: Thermoplastic vulcanizates are prepared by curing, at least partially by dynamic vulcanization, blends of chlorinated polyethylene and crystalline thermoplastic polymers such as polypropylene. Inclusion of a plasticizing material or extender oil, e.g. trioctyl trimellitate, enhances softness and oil resistance of the blends. Vulcanizing materials include a basic material, normally added with the chlorinated polyethylene, and (1) a derivative of 2,5-dimercapto-1,3, 4-thiadiazole or (2) a combination of 2,5-dimercapto-1,3,4-thiadiazole and an activator material such as an amine having a boiling point of 110.degree. C. or higher and a pk value less than 4.5.
Type:
Grant
Filed:
April 7, 1988
Date of Patent:
March 20, 1990
Assignee:
The Dow Chemical Company
Inventors:
James H. Flynn, Oliver C. Ainsworth, Robert R. Blanchard
Abstract: Prepare highly pure zinc oxide spherodial particles of narrow size distribution and having a mean particle diameter of from about 0.1 to about 0.3 .mu.m by hydrolyzing hydrocarbyl zinc hydrocarboxides, such as ethyl zinc t-butoxide.
Abstract: A flow-through electrochemical cell for sequentially oxidizing and reducing an aryl compound. The cell includes a cell body forming a compartment to hold an aqueous electrolyte solution, a porous anodic electrode, and a porous cathodic electrode. The anodic electrode includes a first porous layer of a hydrophobic material, a second porous layer with an oxidation catalyst dispersed therein, and a current collector in electrical contact with the second layer. The cathodic electrode comprises a block of a porous, electrically-conductive material impregnated with lead particles. The cell is particularly useful for the preparation of aryl hydroquinones at very high current efficiencies, high current densities, and low voltages.
Abstract: A catalyst composition comprising a catalytic metal and a support, the support being prepared by depositing a metal alkoxide on a core support, then calcining the support.
Abstract: An improved alkaline catalyst which is especially useful in the preparation of alpha-alkenyl aromatic compounds, such as p-isopropenylphenol, via the cleavage of cleavable organic compounds, e.g., dihydroxydiaryl alkanes such as bisphenol A.
Abstract: A process for preparing a phosphate ester which contains at least one terminal epoxide moiety, the process comprising contacting under reaction conditions, optionally in the presence of water, at least one phosphoric acid ester with an amount of an epoxide having an epoxy equivalent greater than one. The product compositions can be cured by standard epoxide curing agents to provide protective coatings having intumescent properties.
Type:
Grant
Filed:
May 28, 1985
Date of Patent:
September 23, 1986
Assignee:
The Dow Chemical Company
Inventors:
Horst G. Langer, Thomas P. Brady, Marsha A. Paul, George A. Doorakian