Patents Represented by Attorney Paul S. Phillips, Jr.
  • Patent number: 4520379
    Abstract: A thermally-sensitive color-forming composition is disclosed which comprises chromogenic material and certain acidic developer material. Record material comprising this color-forming composition exhibits substantially improved performance in certain Group 3 facsimile equipment.
    Type: Grant
    Filed: June 15, 1984
    Date of Patent: May 28, 1985
    Assignee: Appleton Papers Inc.
    Inventors: Kenneth D. Glanz, Troy E. Hoover
  • Patent number: 4490313
    Abstract: A process is disclosed for performing encapsulation, en masse, by an in situ polymerization reaction to yield capsule wall material. The reaction comprises the polymerization of urea and formaldehyde, monomeric or low molecular weight polymers of dimethylol urea or methylated dimethylol urea, melamine and formaldehyde, monomeric or low molecular weight polymers of methylol melamine or methylated methylol melamine, in an aqueous vehicle and the reaction is conducted in the presence of mixtures of poly-electrolyte material, esp. poly(acrylic acid), and polystyrene sulfonic acid and/or salts thereof in certain critical proportions. The disclosed encapsulation process provides improved resistance of the emulsion of intended capsule core material to destabilization and permits the manufacture of micro-capsules with improved drop size distribution.
    Type: Grant
    Filed: January 24, 1983
    Date of Patent: December 25, 1984
    Assignee: Appleton Papers Inc.
    Inventors: Robert W. Brown, Richard P. Bowman
  • Patent number: 4470057
    Abstract: A thermally-sensitive color-forming composition is disclosed which comprises chromogenic material, acidic developer material and a phenylhydroxynaphthoate compound. Record material comprising this color-forming composition exhibits improved color-forming efficiency and/or image density.
    Type: Grant
    Filed: March 24, 1983
    Date of Patent: September 4, 1984
    Assignee: Appleton Papers Inc.
    Inventor: Kenneth D. Glanz
  • Patent number: 4470058
    Abstract: A two-coat record sheet material is disclosed. This record sheet material comprises a base coat comprising an oil-soluble phenol-formaldehyde novolak resin and a topcoat comprising substantially nonreactant pigment material, but no color developer material. The nonreactive topcoat eliminates the accumulation of contaminants on the fuser roll of copier/duplicators produced by prior art record sheet material.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: September 4, 1984
    Assignee: Appleton Papers Inc.
    Inventors: Jerome R. Bodmer, John H. Peters
  • Patent number: 4454083
    Abstract: A process is disclosed for continuously manufacturing minute capsules in a closed conduit under conditions of non-turbulent flow. The continuous microencapsulation process comprises in-line emulsification of intended capsule core material in a liquid manufacturing vehicle comprising negatively-charged polyelectrolyte material and methylol melamine or etherified methylol melamine followed by conduction of the emulsion, under non-turbulent flow conditions, through a tubular reactor maintained at a single, elevated temperature.
    Type: Grant
    Filed: December 21, 1981
    Date of Patent: June 12, 1984
    Assignee: Appleton Papers Inc.
    Inventors: Robert W. Brown, Lester A. Balster
  • Patent number: 4450043
    Abstract: A process for recovering pulp from pressure-sensitive carbonless copying paper waste is disclosed. This process includes defibrating the waste without substantial rupture of the microcapsules, treating the defibrated waste with an enzyme for starch saccharification and separating the fibers from the released microcapsules by means of a sidehill screen equipped with a washing shower.
    Type: Grant
    Filed: March 12, 1982
    Date of Patent: May 22, 1984
    Assignee: Appleton Papers Inc.
    Inventor: William J. Schulz
  • Patent number: 4444699
    Abstract: A process is disclosed for performing encapsulation, en masse, by an in situ polymerization reaction to yield capsule wall material. The polymerization comprises a reaction between melamine and formaldehyde and/or polycondensation of monomeric methylol melamine or etherified methylol melamine, or a low molecular weight polymer thereof, in an aqueous vehicle and the reaction is conducted in the presence of negatively-charged, carboxyl-substituted polyelectrolyte material and certain salts, both dissolved in the vehicle. The disclosed encapsulation process permits the manufacture of microcapsules with more impermeable walls and/or lower capsule batch viscosities.
    Type: Grant
    Filed: April 20, 1982
    Date of Patent: April 24, 1984
    Assignee: Appleton Papers Inc.
    Inventor: Donald E. Hayford
  • Patent number: 4423116
    Abstract: A thermally-responsive transparent film is disclosed which comprises certain chromogenic material and certain color developer material. With this film marks are developed in response to the application of heat to form an image. These images can be erased by the action of certain liquids or vapors. The imaged and erased states are fixed under a range of environmental conditions. This film finds particular utility as a reusable projection transparency.
    Type: Grant
    Filed: March 15, 1982
    Date of Patent: December 27, 1983
    Assignee: Appleton Papers Inc.
    Inventor: Richard E. Fox
  • Patent number: 4420616
    Abstract: A process for the preparation of copper quinolinate in which quinoline is oxidized by hydrogen peroxide in sulfuric acid in the presence of copper sulfate wherein the reaction is carried out at a pressure of less than 400 mm Hg. The reduced pressure enables the reaction to be performed at higher temperatures and with greater control; also the reaction time is shortened and the yield improved.Copper quinolinate is used to prepare quinolinic acid which is the starting material for some chromogenic materials used in the pressure-sensitive record material field.
    Type: Grant
    Filed: February 20, 1981
    Date of Patent: December 13, 1983
    Assignee: Yamamoto Kagaku Gosei Co., Ltd.
    Inventors: Seishi Ikegami, Yoshihiro Hatano
  • Patent number: 4404460
    Abstract: Heated clothing includes:(a) multiple clothing sections adapted to cover different portions of the human body,(b) electrical wires carried by such sections and including bus wires and heater wires, and(c) circuitry for controlling battery powered electrical current flow to such wires, and including switch structure connected in series with one or more of the heater wires for interrupting current flow thereto without requiring disconnection of bus wires.
    Type: Grant
    Filed: March 12, 1982
    Date of Patent: September 13, 1983
    Assignee: Appleton Papers Inc.
    Inventor: John F. Kerr
  • Patent number: 4375492
    Abstract: A reactive dielectric record material is disclosed which comprises certain chromogenic material and certain phenolic material. This record material produces images by means of a dielectric process wherein two color-forming agents contained within a reactive image-bearing surface are brought into reactive, color-producing contact by means of colorless toner material.
    Type: Grant
    Filed: May 22, 1981
    Date of Patent: March 1, 1983
    Assignee: Appleton Papers Inc.
    Inventor: Richard E. Fox
  • Patent number: 4334072
    Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring or a naphthalene ring and both the E ring and the condensed ring may be substituted, A represents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of indolizine radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat-sensitive record materials and manifold marking systems.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: June 8, 1982
    Assignee: Appleton Papers Inc.
    Inventors: William J. Becker, Sheldon Farber, Troy E. Hoover
  • Patent number: 4316026
    Abstract: A process for the preparation of copper quinolinate in which quinoline is oxidized by hydrogen peroxide in 10 to 30% sulfuric acid in the presence of copper sulfate at a temperature of 55.degree. to 75.degree. C., the molar ratio of sulfuric acid to quinoline being greater than 1:1. The concentration and amount of sulfuric acid enable greater control of the reaction temperature and result in copper quinolate in improved yield and purity.Copper quinolinate is used to prepare quinolinic acid which is the starting material for some chromogenic materials used in the pressure-sensitive record material field.
    Type: Grant
    Filed: August 12, 1980
    Date of Patent: February 16, 1982
    Assignee: Yamamoto Kagaku Gosei Co., Ltd.
    Inventors: Yoshihiro Hatano, Seishi Ikegami, Kenji Itoh, Mansuke Matsumoto
  • Patent number: 4275206
    Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic ring or a naphthalene ring and both the E ring and the condensed ring may be substituted, A respresents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of indolizine radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat-sensitive record materials and manifold marking systems.
    Type: Grant
    Filed: January 16, 1980
    Date of Patent: June 23, 1981
    Assignee: Appleton Papers Inc.
    Inventors: William J. Becker, Sheldon Farber, Troy E. Hoover
  • Patent number: 4246318
    Abstract: A thermally sensitive record material is disclosed which comprises chromogenic material which is a mixture of the isomers 7-(1-ethyl-2-methylindol-3-yl)-7-(4-dimethylamino-2-ethoxyphenyl)-5,7-dihy drofuro[3,4-b]pyridin-5-one and 5-(1-ethyl-2-methylindol-3-yl)-5-(4-diethylamino-2-ethoxyphenyl)-5,7-dihyd rofuro[3,4-b]pyridin-7-one. This record material has superior color forming efficiency and greater image stability, especially resistance to fading in incident light.
    Type: Grant
    Filed: April 9, 1979
    Date of Patent: January 20, 1981
    Assignee: Appleton Papers Inc.
    Inventor: Henry H. Baum
  • Patent number: 4242513
    Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring and both the E ring and the condensed ring may be substituted, A represents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of heterocyclic radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat sensitive record materials and manifold marking systems.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: December 30, 1980
    Assignee: Appleton Papers Inc.
    Inventors: Troy E. Hoover, Sheldon Farber, William J. Becker
  • Patent number: 4232887
    Abstract: Chromogenic compounds of normally colorless form are disclosed having the following structural formula: ##STR1## wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring and both the E ring and the condensed ring may be substituted, A represents an optionally substituted aminophenyl, indolyl, benzoindolyl, julolidinyl or kairolyl radical or the radical represented by B, and B represents a family of indolizine radicals. The compounds of this invention are eligible for use in pressure-sensitive and heat sensitive record materials and manifold marking systems.
    Type: Grant
    Filed: March 5, 1979
    Date of Patent: November 11, 1980
    Assignee: Appleton Papers Inc.
    Inventors: William J. Becker, Sheldon Farber, Troy E. Hoover
  • Patent number: 4200751
    Abstract: Lactone electron donative color-forming agents of quinoline-carboxylic acid are disclosed having the general formulae (I) and (II) ##STR1## wherein A and B represent a variety of chemical moieties, X represents halo- or nitro- and n.sup.1 is an integer of 0-4. The color-forming agents are useful in recording materials of the pressure-sensitive and heat-sensitive varieties, and the like.
    Type: Grant
    Filed: November 21, 1977
    Date of Patent: April 29, 1980
    Assignee: Yamamoto Kagaku Gosei Co., Ltd.
    Inventors: Seiji Ikegami, Yoshihiro Hatano
  • Patent number: 4151748
    Abstract: A thermally sensitive record medium is disclosed. Data is generated on the record medium in response to an application of heat. The record medium is capable of generating data images in more than one color by exposing the medium to more than one temperature level in areas to be imaged. Overlap or interference between two colors is avoided by utilizing at least one color-forming system which requires a thermal decomposition of one system component before it can be reacted to yield color.The record material is made by coating individual layers, each containing a color-forming system or preferably by coating a single layer including all of the color-forming systems.
    Type: Grant
    Filed: December 15, 1977
    Date of Patent: May 1, 1979
    Assignee: NCR Corporation
    Inventor: Henry H. Baum