Abstract: An injection system includes an injector, first valve, second valve, and pressure sensing device. In an embodiment, first valve is in communication with an injector outlet and includes a closed position for at least partially stopping fluid flow from injector outlet. The second valve is in communication with an injector inlet and includes a closed position for at least partially stopping fluid flow to injector inlet. The pressure sensing device is configured for sensing an injector inlet pressure drop of the injector. The injection system may be configured to stop or impede fluid flow to injector inlet when the rate of pressure drop measured by the pressure sensing device is at least equal to a predetermined pressure value that represents a rate of pressure drop measured between injector inlet and second valve when the first valve and second valve are in the closed position.

Abstract: The present invention provides systems and methods to improve the performance and emission control of internal combustion engines equipped with nitrogen oxides storage-reduction (“NSR”) emission control systems. The system generally includes a NSR catalyst, a fuel processor located upstream of the NSR catalyst, and at least one fuel injection port. The fuel processor converts a fuel into a reducing gas mixture comprising CO and H2. The reducing gas mixture is then fed into the NSR catalyst, where it regenerates the NSR adsorbent, reduces the NOx to nitrogen, and optionally periodically desulfates the NSR catalyst. The fuel processor generally includes one or more catalysts, which facilitate reactions such as combustion, partial oxidation, and/or reforming and help consume excess oxygen present in an engine exhaust stream. The methods of the present invention provide for NSR catalyst adsorbent regeneration using pulsed fuel flow. Control strategies are also provided.

Abstract: A diesel exhaust aftertreatment system comprises an LNT within an exhaust line. A low thermal mass DPF and a low thermal mass fuel reformer are configured within the exhaust line upstream from the LNT. A thermal mass is configured downstream from the fuel reformer and the DPF, but upstream from the LNT. For LNT denitration, the fuel reformer is rapidly heated and then used to catalyze steam reforming. The DPF is also rapidly heat each time the fuel reformer is heated and the LNT denitrated. The system operates to regenerate the DPF each time the LNT is denitrated. Preferably, a second DPF is provided to augment the performance of the first DPF. Preferably, the first DPF is small and of the flow through type whereas the second DPF is much larger and of the wall flow filter type. The second DPF can be used as the thermal mass.

Abstract: An exhaust line fuel injection system and associated methods of operation and control are disclosed. The fuel passes through a regulating valve connected to a pressurized fuel source and an outlet connected to an exhaust system fuel supply line. The exhaust system fuel supply line is connected to a nozzle, which generally comprises a check-valve and is configured to inject the fuel into the exhaust line. Using a pressure measuring device, an indication of the exhaust system fuel supply line pressure is obtained. A controller provides control over the flow regulating valve using feedback from the pressure indication and a predetermined relationship between the flow rate through the nozzle and one of the exhaust system fuel supply line pressure and the pressure drop across the nozzle. The method can be implemented with a single pressure measuring device. The same pressure measurements, especially their frequency spectrum, can be used to detect system faults.

Abstract: An exhaust aftertreatment system is provided with a large channel combustor, a fuel reformer, and a lean NOX trap. The lean NOX trap is denitrated by steps comprising: heating the fuel reformer to steam reforming temperatures by introducing vaporized fuel to the large channel combustor and combusting a portion of the vaporized fuel under lean conditions, then making the exhaust-injected fuel mixture overall rich, whereby the fuel reformer produces syn gas that denitrates the lean NOX trap. The fuel reformer has a low thermal mass, whereby it is designed to heat to at least about 500° C. and catalyze steam reforming reaction with each denitration. The large channel combustor is a monolith having an average channel size larger than the fuel reformer and a thermal mass no more than about 20% that of the fuel reformer, whereby the large channel combustor facilitates low temperature startup of the fuel reformer.

Abstract: Rhodium utilization in LNT/SCR-based exhaust after treatment systems for medium and heavy duty trucks is reduced by operating inline fuel reformers in a certain manner. The fuel processors are operated at steam reforming temperatures to produce a reformate-containing exhaust having a hydrogen to CO ratio of at least about 3:2 or at least about 3% hydrogen, This generally involves operating the fuel reformers at temperatures from about 500 to about 625° C. and with an overall fuel to air ratio from about 1.10 to about 1.40. In this manner, regeneration can be efficiently carried out while limiting the catalyst loading of the fuel processors to no more than about 1.0 grams rhodium per liter maximum displacement of the diesel engine and the catalyst loading of the LNTs to no more than about 0.50 grams rhodium per liter maximum displacement of the diesel engine.

Abstract: Described here are systems and methods for reducing emissions of IC engines using a fuel processor bypass. In general, the systems described here include an exhaust pipe, a bypass pipe, a valve, a fuel processor, a fuel injector, and a NOx trap. When the valve is in the open position, the entire exhaust passes through the bypass pipe. When the valve is in a closed position, the entire exhaust passes through the exhaust pipe. In some variations, the systems described here also comprise a pre-combustor, a thermal mass, a mixer, and/or a DPF. Methods for regenerating or desulfating a NOx trap are also described. Typically these methods include introducing exhaust into an exhaust pipe, opening a valve located at the inlet of a bypass pipe, injecting fuel upstream of a fuel processor, and introducing a reducing mixture into a NOx trap. The injection of fuel may be pulsed or continuous.

Abstract: Discontinuous torque ratio shifts by a transmission can result in complex transient exhaust conditions that can adversely affect exhaust air-fuel ratio control, which can result in ineffective regeneration. In extreme cases, the result can be irreversible damage to exhaust system components. The inventors' concept is to alter either regeneration scheduling or shift scheduling to avoid shifting while regenerating.

Abstract: A lean NOX trap is a diesel exhaust aftertreatment system is selectively denitrated in a manner that addresses unreliability of NOX sensor data. According to one concept, data from a NOX is ignored or given decreased weight in a period immediately following a denitration. According to another concept, denitration is made contingent on both a first and a second criteria being met. The first criteria relates to the amount of NOX stored in the LNT or remaining NOX storage capacity of the LNT. The second criteria relates to the current performance of the exhaust treatment system, or a portion thereof, as determined from one or more measurements of NOX concentration in the exhaust. This reduces premature denitrations and associated unnecessary fuel expenditures resulting from inaccurate NOX concentration data and transient events.

Abstract: A lean NOx trap is a diesel exhaust aftertreatment system is selectively denitrated based on a measure relating to the state and/or the performance of the exhaust aftertreatment system, or a portion thereof comprising the lean NOx trap, reaching a critical value. The critical value is varied according to the demands currently being place on the exhaust aftertreatment system. In one embodiment, the critical value is set based on engine speed-load information. The method regenerates more frequently when exhaust aftertreatment demands are high and less frequently when demands are low. The method improves aftertreatment performance while reducing aftertreatment fuel penalty.

Abstract: In an exhaust aftertreatment system, two LNTs having differing compositions are configured in series downstream from an inline fuel reformer. The downstream LNT is adapted for desulfation at higher temperatures than the upstream LNT. During desulfation, the system develops temperature gradients with the temperatures increasing in the direction of exhaust flow. The ordering of the LNTs is designed utilize these gradients. In a preferred embodiment, the system also includes two SCR catalysts having different compositions. The SCR catalyst with a composition adapted to tolerate higher temperatures is located nearer the downstream end of the system.

Abstract: The inventors' concept relates to controlling a power generation system having an exhaust aftertreatment system comprising a fuel reformer and an LNT in series. Over the course of a desulfation, a fuel injection upstream of the fuel reformer is pulsed to create alternating lean and rich phases and control the LNT temperature. The LNT temperature is controlled by manipulating a minimum temperature for the fuel reformer at the end of the lean phase, a length of the lean phase, or a pulse frequency. Preferably, the rich phases end when the fuel reformer reaches a predetermined maximum temperature. The method is effective in regulating the fuel reformer temperature while accurately controlling the LNT temperature.

Abstract: One aspect of the invention relates to a power generation system that has an internal combustion engine that operates in a low temperature combustion mode to produce an engine exhaust that is low in NOx and particulate matter. The exhaust is treated by a fuel cell to remove organic compounds and CO while producing useful power. Another aspect of the invention relates to controlling the adiabatic flame temperature by EGR drawing from upstream of the fuel cell. A further aspect of the invention relates to treating engine exhaust with a reducing catalyst and then with a fuel cell. A still further aspect of the invention relates to treating exhaust with an intermediate temperature solid oxide fuel cell. A further aspect of the invention relates to a system equipped with a valve allowing exhaust to selectively bypass a fuel cell.

Abstract: Systems and methods are disclosed for ameliorating NOx slip from a lean NOx trap by reducing the amount of hydrocarbons reaching the lean NOx trap during the early stages of, or in a period immediately preceding, a rich regeneration. In one embodiment, a hydrocarbon absorber is configured downstream from a fuel reformer, but upstream from the lean NOx trap, in order to reduce the quantity of hydrocarbons that reach the lean NOx trap during lean reformer warm-up and rich regeneration phases. In another embodiment, the fueling rate to a fuel reformer configured in an exhaust line upstream from the lean NOx trap is limited to reduce NOx slip.

Abstract: A power generation system and method of operating a power generation system which comprises a diesel engine which produces lean exhaust which passed to an exhaust after treatment system comprising an exhaust line which is in communication with a controller, reformer, lean NOx trap and SCR has been taught wherein the reformer comprises oxidation and reforming catalyst is a composition which comprises a catalyst wash coat comprising a ZrO2 refractory metal oxide support, a LnxOy distributed on the surface of the refractory metal oxide in an amount to form a monolayer over the refractory metal oxide support wherein Ln is selected from the group consisting of La, Nd and mixtures thereof and Rh distributed over the catalyst surface in an effective amount to catalyze steam reforming at 650° C.

Abstract: Described here are systems and methods for controlling IC engines. In one aspect, a method for controlling a fuel processor is provided, the method including i) determining a temperature of an exhaust flow to the fuel processor, the fuel processor including a fuel processor catalyst; ii) determining a concentration of O2 in the exhaust flow upstream of the fuel processor catalyst; iii) determining a rate of the exhaust flow; and iv) adjusting a fuel flow rate to the fuel processor based on i), ii), iii) and a heat capacity value associated with the fuel processor. In other aspects, a system comprising logic operable to control a fuel processor is provided.

Abstract: The invention provides methods and systems for catalytic reforming of a hydrocarbon fuel to produce hydrogen, which may be used as a power source for a fuel cell. In some embodiments, hydrogen is produced by partial oxidation or autothermal reforming of fuel in an oxygen containing gas stream that is rich the majority of the time, with periodic conversion to a lean gas stream for short periods of time to maintain catalytic activity. In one embodiment, hydrogen peroxide is used as the oxidant in an autothermal reforming process. In some embodiments, hydrogen is produced by steam reforming at a low steam to carbon ratio, with a periodic increase in the steam to carbon ratio for short periods of time to maintain catalytic activity.

Abstract: Partial denitrations are made practical by an SCR catalyst placed downstream of a NOx adsorber. The SCR catalyst permits partial denitrations to be extended to where a favorable fuel penalty rate presented by driving conditions can be utilized to a sufficient extent that the benefit of the favorable conditions is not offset by the increased start-up fuel penalty associated with conducting opportunistic partial denitrations. Regenerations, including both denitration and desulfations, can be initiated selectively based on a fuel penalty calculation. Examples of such calculations lead to methods in which opportunistic regenerations are based on low oxygen concentrations, condition existing while shifting gears, and throttling events for a diesel engine with a throttled air supply. The methods flexibly take advantage of driving conditions to reduce fuel penalties associated with regenerations. In one embodiment, driving conditions include future conditions predicted based on GPS and map data.

Abstract: Desulfation methods for an exhaust treatment system having a fuel reformer configured upstream of a LNT. Reductant is injected upstream of the fuel reformer. The reductant reacts within the reformer to generate heat, but the system is configured for some reductant to breakthrough and react in the LNT to generate further heat. This configuration allows the LNT to operate at temperatures higher the than first device and facilitates independent control of the LNT and first device temperatures. An outer loop controls the LNT temperature by issuing instructions to an inner loop that controls the reformer. Typically, the inner loop will pulse the reductant injection rate in order to limit the reformer temperature. The outer loop can pulses the loop on a longer time scale, resulting in two pulse periods. Through timing, a reformate peak from one period is made to overlap a temperature peak from a previous period.

Abstract: One aspect of the invention relates an exhaust treatment system having an SCR reactor following a NOx adsorber. Syn gas is used to regenerate the NOx adsorber. Another aspect relates to an LNT/SCR provided with an ammonia source separate from the LNT. A further aspect relates to a system comprising first and second LNTs and one or more SCRs downstream of the LNTs. A still further aspect relates to a device comprising first and second NOx adsorbers contained in a single housing. Another aspect relates to coating a surface of a moving part in an exhaust system with an oxidation catalyst to mitigate fouling. Additional aspects of the invention relate to strategies for controlling one or more of the time to initiate a regeneration cycle, the time to terminate a regeneration cycle, and the reductant injection rate during regeneration of LNT/SCR exhaust treatment systems.