Patents Represented by Law Firm Plumley & Tyner
  • Patent number: 4171442
    Abstract: Process for the preparation of 2,4,5-trichloropyrimidine, characterized in that compounds of the formula ##STR1## wherein R a radical which can be split off under the reaction conditions andR' an optionally substituted lower alkyl radical,Are reacted at temperatures from 0.degree. to 50.degree. C. with less than 7.5 mols of chlorine, in particular 3.5 to 7.0 mols of chlorine, and the reaction products are then after-heated to temperatures of 100.degree.-150.degree. C., in particular 110.degree.-140.degree. C., in the absence of chlorine.
    Type: Grant
    Filed: June 6, 1978
    Date of Patent: October 16, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunther Beck, Helmut Heitzer
  • Patent number: 4166002
    Abstract: Water-soluble polyamines which (a) have an average molecular weight of above 1,000, (b) contain at least one grouping of the formula-- R -- Zin whichZ denotes a --COOH or --SO.sub.
    Type: Grant
    Filed: November 29, 1974
    Date of Patent: August 28, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wolfgang Lehmann, Gerhard Troemel, Kurt Ley, Friedhelm Muller
  • Patent number: 4166176
    Abstract: The compounds of the formula ##STR1## WHEREIN X and Y denote halogen, hydroxyl, amino, alkoxy, aralkyloxy, cycloalkoxy, aryloxy, alkylmercapto, arylmercapto, alkylamino, dialkylamino, morpholino, piperidino, piperazino, pyrrolidino, acylamino, arylamino or alkyl,N denotes 0, 1 or 2 andQ denotes hydrogen, pyrazol-1-yl, oxazol-2-yl, benzoxazol-2-yl, naphthoxazol-2-yl, 1,2,4-oxadiazol-5-yl, 1,3,4-oxadiazol-2-yl, isoxazol-3-yl, isoxazol-5-yl, thiazol-2-yl, benzthiazol-2-yl, 1,3,4-thiadiazol-2-yl, imidazol-2-yl, benzimidazol-2-yl, 1,2,3-triazol-2-yl, 1,2,3-triazol-4-yl, 1,2,4-triazol-3-yl, 1,2,4-triazol-5-yl, 2 H-benzotriazol-2-yl, 2 H-naphthotriazol-2-yl, benzo[b]-furan-2-yl, naphtho[2,1-b]-furan-2-yl, benzo[b]-thiophen-2-yl, naphtho[2,1-b]-thiophen-2-yl, pyrimidin-2-yl, pyrridin-2-yl, quinazolin-4-yl or quinazolin-2-yl, if n is 1 or 2, or denotes naphthyl-, stilben-4-yl-, benzo[b]-furan-6-yl, dibenzofuran-3-yl-, dibenzofuran-2-yl, quinoxalin-6-yl-, quinazolin-6-yl- or 2 H-benzotriazol-5-yl, if n is 0,It being po
    Type: Grant
    Filed: March 20, 1978
    Date of Patent: August 28, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Udo Eckstein, Horst Harnisch
  • Patent number: 4164838
    Abstract: The invention is related to a process for the stretch-texturing of high-molecular weight linear synthetic endless filaments travelling at speeds of 300 to 1200 meters per minute by continuously guiding the filaments through a delivery zone, a heat-fixing zone, a false-twister and a stretching godet. The endless filaments are passed through a stretching zone S 55 to 180 cm long, defined by the distance between the delivery stage and the stretching godet, the distance between the delivery stage and the false-twister inlet amounting to S-X cm and the distance X between the false-twister outlet and the stretching godet being 5 to 30 cm.
    Type: Grant
    Filed: December 6, 1974
    Date of Patent: August 21, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans Bach, Karl-August Heinroth, Hans-Dieter Jurischka, Hans Kaloff, Rudolf J. Klee, Herbert Schmidt
  • Patent number: 4163012
    Abstract: The invention relates to the preparation of concentrated solutions of azo dyestuffs containing ionic groups, by precipitating during the diazotization and/or coupling reaction and/or after the coupling reaction the foreign ions which lower the solubility of the dyestuffs and separating off these ions as sparingly soluble salts.In this way dyestuff solutions which are stable to storage at room temperature and have a dyestuff content of 10 to 50 percent by weight are obtained.
    Type: Grant
    Filed: October 28, 1975
    Date of Patent: July 31, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Erich Kramer, Horst Nickel, Fritz Puchner
  • Patent number: 4163088
    Abstract: The invention relates to antistatic polyamide compositions comprising a polyamide and as an antistatic agent from 0.1 to 20%, preferably from 1.5 to 15%, by weight based on the total weight of the composition of urethanes with ether groups. The urethanes with ether groups are stable in melts of aliphatic polyamides for prolonged periods at temperatures of up to about 300.degree. C. and filaments and fibers of such polyamides or woven fabrics, knitted fabrics, non-woven or pile fabrics produced from these filaments or fibers show outstanding antistatic properties.
    Type: Grant
    Filed: June 20, 1977
    Date of Patent: July 31, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans E. Kunzel, Claus-Rudiger Bernert, Gunter Arend, Francis Bentz, Helmut Sinner, Dieter Brokmeier
  • Patent number: 4160819
    Abstract: A method of inhibiting or reducing the irritation of skin resulting from allergic contact dermatitis, caused by contact with natural or synthetic allergenic agents, e.g. poison ivy, and dinitrochlorobenzene, respectively, is described. The method comprises applying to the skin an irritating reducing effective amount of a protective agent which is an organic compound having at least two polar groups, e.g. carboxyl groups, separated by a chain of at least 15 atoms the majority of which are carbon atoms and optionally containing a cyclic moiety of at least 5 atoms, prior to contact of the skin with the allergenic agent. The protective agent may be combined in a pharmacologically acceptable base for application to the skin.
    Type: Grant
    Filed: January 20, 1978
    Date of Patent: July 10, 1979
    Assignee: Cincinnati Milacron, Inc.
    Inventors: Sharon G. Willer, Paul R. Yust, Ralph Kelly
  • Patent number: 4159265
    Abstract: Monoazo dyestuffs of the formula ##STR1## wherein K represents the radical of a couping component K-H of the formula ##STR2## said dyestuff being suitable for the dyeing of synthetic fibre materials especially those from polyamides.
    Type: Grant
    Filed: April 25, 1978
    Date of Patent: June 26, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Richard Sommer, Gerhard Wolfrum, Gerhard Buttner
  • Patent number: 4156086
    Abstract: Trisaminopyridines of the formula ##STR1## are prepared by reacting a pyridinium salt of the formula ##STR2## with an organic amine having the formula R.sub.3 NH.sub.2 at a temperature of 110.degree. C. to 130.degree. C.;in whichX is --CN, --CONQ.sub.1 Q.sub.2 or --COOQ.sub.3 ;R is substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or aryl;R.sub.1 is substituted or unsubstituted alkyl, aralkyl or aryl;Q.sub.1 and Q.sub.2 independently of one another are hydrogen, alkyl, cycloalkyl, aralkyl or aryl; or conjointly with the nitrogen atom form a 5-membered or 6-membered heterocyclic structure; andQ.sub.3 is alkyl or aralkyl.Where X is --CONQ.sub.1 Q.sub.2 or --COOQ.sub.3, the --CN group in the starting pyridinium salt is subsequently converted in the known manner to --CONQ.sub.1 Q.sub.2 or --COOQ.sub.3. The trisaminopyridines are useful as intermediates for preparation of azo dyestuffs by coupling with diazo components in the known manner.
    Type: Grant
    Filed: January 16, 1978
    Date of Patent: May 22, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl L. Moritz, Karl H. Schundehutte
  • Patent number: 4131724
    Abstract: The invention relates to a process for the production of crosslinked fibres or filaments by spinning an acrylonitrile copolymer containing at least 20 mVal of carboxyl groups per kg of polymer together with a polyoxazoline in a polar organic solvent and thereafter crosslinking at temperatures of from 120 to 190.degree. C.The invention also relates to crosslinked acrylonitrile fibres and filaments obtainable by this process.
    Type: Grant
    Filed: May 18, 1977
    Date of Patent: December 26, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Eduard Radlmann, Ulrich Reinehr, Peter Hoffmann, Dieter Arlt, Gunther Nischk
  • Patent number: 4119623
    Abstract: Dyestuffs, which in the form of the free acid of the formula ##STR1## wherein R.sub.1 denotes hydrogen, nitro, cyano, SO.sub.2 --R.sub.7, CONR.sub.8 R.sub.9, SO.sub.2 NR.sub.8 R.sub.9, SO.sub.2 OR.sub.10, COOR.sub.10, SO.sub.2 --NHSO.sub.2 --R.sub.11, sulpho or alkyl,R.sub.2 denotes hydrogen, nitro, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.3 denotes hydrogen, halogen, SO.sub.2 --R.sub.7, SO.sub.2 --NR.sub.8 R.sub.9 or optionally subsituted alkyl, alkoxy or aryl,R.sub.4 denotes hydrogen, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.5 denotes hydrogen or optionally substituted alkyl,R.sub.6 denotes alkylene,R.sub.7 denotes optionally substituted alkyl, aryl or aralkyl,R.sub.8 and R.sub.9 denote hydrogen, optionally substituted alkyl, cycloalkyl, aryl or aralkyl or the radical of a heterocyclic compound or, together with the N-atom, denote a heterocyclic structure,R.sub.10 denotes hydrogen or optionally substituted alkyl, aryl or aralkyl,R.sub.
    Type: Grant
    Filed: August 12, 1976
    Date of Patent: October 10, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Herbert Hugl, Hans-Gunter Otten, Richard Sommer, Gerhard Wolfrum
  • Patent number: 4119634
    Abstract: Bis-benzoxazolyl compounds of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another denote hydrogen, halogen, optionally substituted C.sub.1 -C.sub.8 -alkyl, optionally substituted C.sub.1 -C.sub.4 -alkoxy, aralkyl, aryl, carboxyl, cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, carboxamide which is optionally substituted by C.sub.1 -C.sub.4 -alkyl, aryl or aralkyl, or C.sub.1 -C.sub.4 -alkylsulphonyl, or 2 adjacent radicals R.sub.1 -R.sub.4 represent a fused, optionally substituted aromatic or hydroaromatic ring, are suitable for the brightening of plastics and of polyester fibres.
    Type: Grant
    Filed: August 9, 1977
    Date of Patent: October 10, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventor: Josef Schroeder
  • Patent number: 4101637
    Abstract: Process for producing triple superphosphate by reacting dilute phosphoric acid and lime, limestone or dolomite and granulating the resultant product.
    Type: Grant
    Filed: October 29, 1975
    Date of Patent: July 18, 1978
    Assignee: J. R. Simplot Company
    Inventors: Laurence William Bierman, Gary Lynn Long
  • Patent number: 4100143
    Abstract: The invention relates to cross-linkable or cross-linked filaments or fibers of a copolymer comprising at least 65% by weight of acrylonitrile and from 0.5 to 10% by weight of at least one copolymerised N-methylol compound of an unsaturated mono- or bis-urethane or an alkyl ether thereof and, optionally, at least one other copolymerisable monomer.
    Type: Grant
    Filed: January 19, 1977
    Date of Patent: July 11, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Dieter Wolf, Werner Schnoor, Jean-Claude Voegele, Ulrich Reinehr, Gunther Nischk
  • Patent number: 4096111
    Abstract: Process for the bulk dyeing of synthetic linear polyesters, characterized in that one or more dyestuffs of the formula ##STR1## WHEREIN R.sub.1 and R.sub.2 denote hydrogen or a non-ionic substituent, m denotes an integer from 0 to 2 and n denotes an integer from 1 to 4 and m and n together are not greater than 4, are employed.
    Type: Grant
    Filed: March 30, 1976
    Date of Patent: June 20, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rutger Neeff, Heinz Dietrich Jordan
  • Patent number: 4089895
    Abstract: New azo reactive dyestuffs corresponding to the general formula ##STR1## wherein R denotes optionally substituted lower alkyl, A the radical of an optionally substituted lower alkyl, R.sub.1 hydrogen or optionally substituted lower alkyl and Z a reactive group.They are useful for dyeing and printing materials containing hydroxyl groups or amide groups.
    Type: Grant
    Filed: January 7, 1976
    Date of Patent: May 16, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventor: Horst Jager
  • Patent number: 4090018
    Abstract: 2-Styrylbenztriazoles of the formula ##STR1## in which R denotes C.sub.1 -C.sub.4 -alkyl, benzyl or C.sub.1 -C.sub.4 -alkoxyethyl are suitable for whitening organic materials.
    Type: Grant
    Filed: January 13, 1977
    Date of Patent: May 16, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventor: Josef Schroeder
  • Patent number: 4089851
    Abstract: Disazo dyestuffs of the formula ##STR1## IN WHICH K represents the radical of a coupling component of the benzene, acetoacetic acid arylide, pyrazolone or aminopyrazole series,R.sub.1 and R.sub.2 denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen andN denotes 1 or 2,Are suitable for the dyeing of natural and synthetic fibre materials and paper in greenish to reddish yellow shades. The dyeings particularly on polyamide have good to very good light fastness and good fastness to water and washing.
    Type: Grant
    Filed: June 15, 1976
    Date of Patent: May 16, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hans Kramb
  • Patent number: 4088651
    Abstract: Acylamino quinophthalone compounds which are free from sulfonic acid groups and correspond to the formula ##STR1## in which R.sub.1 and R.sub.2 are hydrogen, halogen, acylamino or lower alkoxy with the proviso that one of the residues R.sub.1 and R.sub.2 denotes acylamino while the other residue stands for hydrogen, halogen or a lower alkoxy; R.sub.3 is hydrogen, halogen or a lower alkoxy; X is a substituent; and n is a number from 0 to 3; are disclosed. The compounds useful as dyestuffs for hydrophobic fiber materials, e.g. polyester, are prepared by reacting an acylamino phthalic acid, the anhydride thereof, or mixtures of acylamino phthalic acids or the anhydrides thereof with a 3-hydroxy-quinalide.
    Type: Grant
    Filed: April 17, 1975
    Date of Patent: May 9, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dietmar Kalz, Gerhard Wolfrum
  • Patent number: 4088673
    Abstract: Process for the preparation of styryl dyestuffs, characterized in that, in a one-pot reaction, amines of the general formula form ##STR1## wherein R.sub.1 denotes alkyl or aryl,R.sub.2 denotes hydrogen, alkyl or aryl,R.sub.3 -r.sub.6 denote hydrogen or non-ionic substituents, preferably alkyl, alkoxy, nitro or halogen or R.sub.1 with R.sub.3 or R.sub.5 conjointly from the remaining members of a 5-membered or 6-membered ring system which optionally contains further hetero-atomsAre treated with at least 1 equivalent of a Vilsmeier reagent, unconverted Vilsmeier reagent is decomposed, the pH value is adjusted to above 4 by addition of bases and subsequently--without any intermediate isolation--the product is treated with a methylene-active compound of the formula ##STR2## wherein X represents a nitrile or acyl group.
    Type: Grant
    Filed: November 18, 1975
    Date of Patent: May 9, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Walter Gomm, Hermann Beecken