Patents Represented by Law Firm Plumley & Tyner
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Patent number: 4171442Abstract: Process for the preparation of 2,4,5-trichloropyrimidine, characterized in that compounds of the formula ##STR1## wherein R a radical which can be split off under the reaction conditions andR' an optionally substituted lower alkyl radical,Are reacted at temperatures from 0.degree. to 50.degree. C. with less than 7.5 mols of chlorine, in particular 3.5 to 7.0 mols of chlorine, and the reaction products are then after-heated to temperatures of 100.degree.-150.degree. C., in particular 110.degree.-140.degree. C., in the absence of chlorine.Type: GrantFiled: June 6, 1978Date of Patent: October 16, 1979Assignee: Bayer AktiengesellschaftInventors: Gunther Beck, Helmut Heitzer
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Patent number: 4166002Abstract: Water-soluble polyamines which (a) have an average molecular weight of above 1,000, (b) contain at least one grouping of the formula-- R -- Zin whichZ denotes a --COOH or --SO.sub.Type: GrantFiled: November 29, 1974Date of Patent: August 28, 1979Assignee: Bayer AktiengesellschaftInventors: Wolfgang Lehmann, Gerhard Troemel, Kurt Ley, Friedhelm Muller
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Patent number: 4166176Abstract: The compounds of the formula ##STR1## WHEREIN X and Y denote halogen, hydroxyl, amino, alkoxy, aralkyloxy, cycloalkoxy, aryloxy, alkylmercapto, arylmercapto, alkylamino, dialkylamino, morpholino, piperidino, piperazino, pyrrolidino, acylamino, arylamino or alkyl,N denotes 0, 1 or 2 andQ denotes hydrogen, pyrazol-1-yl, oxazol-2-yl, benzoxazol-2-yl, naphthoxazol-2-yl, 1,2,4-oxadiazol-5-yl, 1,3,4-oxadiazol-2-yl, isoxazol-3-yl, isoxazol-5-yl, thiazol-2-yl, benzthiazol-2-yl, 1,3,4-thiadiazol-2-yl, imidazol-2-yl, benzimidazol-2-yl, 1,2,3-triazol-2-yl, 1,2,3-triazol-4-yl, 1,2,4-triazol-3-yl, 1,2,4-triazol-5-yl, 2 H-benzotriazol-2-yl, 2 H-naphthotriazol-2-yl, benzo[b]-furan-2-yl, naphtho[2,1-b]-furan-2-yl, benzo[b]-thiophen-2-yl, naphtho[2,1-b]-thiophen-2-yl, pyrimidin-2-yl, pyrridin-2-yl, quinazolin-4-yl or quinazolin-2-yl, if n is 1 or 2, or denotes naphthyl-, stilben-4-yl-, benzo[b]-furan-6-yl, dibenzofuran-3-yl-, dibenzofuran-2-yl, quinoxalin-6-yl-, quinazolin-6-yl- or 2 H-benzotriazol-5-yl, if n is 0,It being poType: GrantFiled: March 20, 1978Date of Patent: August 28, 1979Assignee: Bayer AktiengesellschaftInventors: Udo Eckstein, Horst Harnisch
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Patent number: 4164838Abstract: The invention is related to a process for the stretch-texturing of high-molecular weight linear synthetic endless filaments travelling at speeds of 300 to 1200 meters per minute by continuously guiding the filaments through a delivery zone, a heat-fixing zone, a false-twister and a stretching godet. The endless filaments are passed through a stretching zone S 55 to 180 cm long, defined by the distance between the delivery stage and the stretching godet, the distance between the delivery stage and the false-twister inlet amounting to S-X cm and the distance X between the false-twister outlet and the stretching godet being 5 to 30 cm.Type: GrantFiled: December 6, 1974Date of Patent: August 21, 1979Assignee: Bayer AktiengesellschaftInventors: Hans Bach, Karl-August Heinroth, Hans-Dieter Jurischka, Hans Kaloff, Rudolf J. Klee, Herbert Schmidt
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Patent number: 4163012Abstract: The invention relates to the preparation of concentrated solutions of azo dyestuffs containing ionic groups, by precipitating during the diazotization and/or coupling reaction and/or after the coupling reaction the foreign ions which lower the solubility of the dyestuffs and separating off these ions as sparingly soluble salts.In this way dyestuff solutions which are stable to storage at room temperature and have a dyestuff content of 10 to 50 percent by weight are obtained.Type: GrantFiled: October 28, 1975Date of Patent: July 31, 1979Assignee: Bayer AktiengesellschaftInventors: Erich Kramer, Horst Nickel, Fritz Puchner
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Patent number: 4163088Abstract: The invention relates to antistatic polyamide compositions comprising a polyamide and as an antistatic agent from 0.1 to 20%, preferably from 1.5 to 15%, by weight based on the total weight of the composition of urethanes with ether groups. The urethanes with ether groups are stable in melts of aliphatic polyamides for prolonged periods at temperatures of up to about 300.degree. C. and filaments and fibers of such polyamides or woven fabrics, knitted fabrics, non-woven or pile fabrics produced from these filaments or fibers show outstanding antistatic properties.Type: GrantFiled: June 20, 1977Date of Patent: July 31, 1979Assignee: Bayer AktiengesellschaftInventors: Hans E. Kunzel, Claus-Rudiger Bernert, Gunter Arend, Francis Bentz, Helmut Sinner, Dieter Brokmeier
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Patent number: 4160819Abstract: A method of inhibiting or reducing the irritation of skin resulting from allergic contact dermatitis, caused by contact with natural or synthetic allergenic agents, e.g. poison ivy, and dinitrochlorobenzene, respectively, is described. The method comprises applying to the skin an irritating reducing effective amount of a protective agent which is an organic compound having at least two polar groups, e.g. carboxyl groups, separated by a chain of at least 15 atoms the majority of which are carbon atoms and optionally containing a cyclic moiety of at least 5 atoms, prior to contact of the skin with the allergenic agent. The protective agent may be combined in a pharmacologically acceptable base for application to the skin.Type: GrantFiled: January 20, 1978Date of Patent: July 10, 1979Assignee: Cincinnati Milacron, Inc.Inventors: Sharon G. Willer, Paul R. Yust, Ralph Kelly
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Patent number: 4159265Abstract: Monoazo dyestuffs of the formula ##STR1## wherein K represents the radical of a couping component K-H of the formula ##STR2## said dyestuff being suitable for the dyeing of synthetic fibre materials especially those from polyamides.Type: GrantFiled: April 25, 1978Date of Patent: June 26, 1979Assignee: Bayer AktiengesellschaftInventors: Richard Sommer, Gerhard Wolfrum, Gerhard Buttner
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Patent number: 4156086Abstract: Trisaminopyridines of the formula ##STR1## are prepared by reacting a pyridinium salt of the formula ##STR2## with an organic amine having the formula R.sub.3 NH.sub.2 at a temperature of 110.degree. C. to 130.degree. C.;in whichX is --CN, --CONQ.sub.1 Q.sub.2 or --COOQ.sub.3 ;R is substituted or unsubstituted alkyl, cycloalkyl, aralkyl, or aryl;R.sub.1 is substituted or unsubstituted alkyl, aralkyl or aryl;Q.sub.1 and Q.sub.2 independently of one another are hydrogen, alkyl, cycloalkyl, aralkyl or aryl; or conjointly with the nitrogen atom form a 5-membered or 6-membered heterocyclic structure; andQ.sub.3 is alkyl or aralkyl.Where X is --CONQ.sub.1 Q.sub.2 or --COOQ.sub.3, the --CN group in the starting pyridinium salt is subsequently converted in the known manner to --CONQ.sub.1 Q.sub.2 or --COOQ.sub.3. The trisaminopyridines are useful as intermediates for preparation of azo dyestuffs by coupling with diazo components in the known manner.Type: GrantFiled: January 16, 1978Date of Patent: May 22, 1979Assignee: Bayer AktiengesellschaftInventors: Karl L. Moritz, Karl H. Schundehutte
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Patent number: 4131724Abstract: The invention relates to a process for the production of crosslinked fibres or filaments by spinning an acrylonitrile copolymer containing at least 20 mVal of carboxyl groups per kg of polymer together with a polyoxazoline in a polar organic solvent and thereafter crosslinking at temperatures of from 120 to 190.degree. C.The invention also relates to crosslinked acrylonitrile fibres and filaments obtainable by this process.Type: GrantFiled: May 18, 1977Date of Patent: December 26, 1978Assignee: Bayer AktiengesellschaftInventors: Eduard Radlmann, Ulrich Reinehr, Peter Hoffmann, Dieter Arlt, Gunther Nischk
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Patent number: 4119623Abstract: Dyestuffs, which in the form of the free acid of the formula ##STR1## wherein R.sub.1 denotes hydrogen, nitro, cyano, SO.sub.2 --R.sub.7, CONR.sub.8 R.sub.9, SO.sub.2 NR.sub.8 R.sub.9, SO.sub.2 OR.sub.10, COOR.sub.10, SO.sub.2 --NHSO.sub.2 --R.sub.11, sulpho or alkyl,R.sub.2 denotes hydrogen, nitro, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.3 denotes hydrogen, halogen, SO.sub.2 --R.sub.7, SO.sub.2 --NR.sub.8 R.sub.9 or optionally subsituted alkyl, alkoxy or aryl,R.sub.4 denotes hydrogen, halogen or optionally substituted alkyl, alkoxy or aryl,R.sub.5 denotes hydrogen or optionally substituted alkyl,R.sub.6 denotes alkylene,R.sub.7 denotes optionally substituted alkyl, aryl or aralkyl,R.sub.8 and R.sub.9 denote hydrogen, optionally substituted alkyl, cycloalkyl, aryl or aralkyl or the radical of a heterocyclic compound or, together with the N-atom, denote a heterocyclic structure,R.sub.10 denotes hydrogen or optionally substituted alkyl, aryl or aralkyl,R.sub.Type: GrantFiled: August 12, 1976Date of Patent: October 10, 1978Assignee: Bayer AktiengesellschaftInventors: Herbert Hugl, Hans-Gunter Otten, Richard Sommer, Gerhard Wolfrum
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Patent number: 4119634Abstract: Bis-benzoxazolyl compounds of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another denote hydrogen, halogen, optionally substituted C.sub.1 -C.sub.8 -alkyl, optionally substituted C.sub.1 -C.sub.4 -alkoxy, aralkyl, aryl, carboxyl, cyano, C.sub.1 -C.sub.4 -alkoxycarbonyl, carboxamide which is optionally substituted by C.sub.1 -C.sub.4 -alkyl, aryl or aralkyl, or C.sub.1 -C.sub.4 -alkylsulphonyl, or 2 adjacent radicals R.sub.1 -R.sub.4 represent a fused, optionally substituted aromatic or hydroaromatic ring, are suitable for the brightening of plastics and of polyester fibres.Type: GrantFiled: August 9, 1977Date of Patent: October 10, 1978Assignee: Bayer AktiengesellschaftInventor: Josef Schroeder
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Patent number: 4101637Abstract: Process for producing triple superphosphate by reacting dilute phosphoric acid and lime, limestone or dolomite and granulating the resultant product.Type: GrantFiled: October 29, 1975Date of Patent: July 18, 1978Assignee: J. R. Simplot CompanyInventors: Laurence William Bierman, Gary Lynn Long
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Patent number: 4100143Abstract: The invention relates to cross-linkable or cross-linked filaments or fibers of a copolymer comprising at least 65% by weight of acrylonitrile and from 0.5 to 10% by weight of at least one copolymerised N-methylol compound of an unsaturated mono- or bis-urethane or an alkyl ether thereof and, optionally, at least one other copolymerisable monomer.Type: GrantFiled: January 19, 1977Date of Patent: July 11, 1978Assignee: Bayer AktiengesellschaftInventors: Gerhard Dieter Wolf, Werner Schnoor, Jean-Claude Voegele, Ulrich Reinehr, Gunther Nischk
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Patent number: 4096111Abstract: Process for the bulk dyeing of synthetic linear polyesters, characterized in that one or more dyestuffs of the formula ##STR1## WHEREIN R.sub.1 and R.sub.2 denote hydrogen or a non-ionic substituent, m denotes an integer from 0 to 2 and n denotes an integer from 1 to 4 and m and n together are not greater than 4, are employed.Type: GrantFiled: March 30, 1976Date of Patent: June 20, 1978Assignee: Bayer AktiengesellschaftInventors: Rutger Neeff, Heinz Dietrich Jordan
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Patent number: 4089895Abstract: New azo reactive dyestuffs corresponding to the general formula ##STR1## wherein R denotes optionally substituted lower alkyl, A the radical of an optionally substituted lower alkyl, R.sub.1 hydrogen or optionally substituted lower alkyl and Z a reactive group.They are useful for dyeing and printing materials containing hydroxyl groups or amide groups.Type: GrantFiled: January 7, 1976Date of Patent: May 16, 1978Assignee: Bayer AktiengesellschaftInventor: Horst Jager
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Patent number: 4090018Abstract: 2-Styrylbenztriazoles of the formula ##STR1## in which R denotes C.sub.1 -C.sub.4 -alkyl, benzyl or C.sub.1 -C.sub.4 -alkoxyethyl are suitable for whitening organic materials.Type: GrantFiled: January 13, 1977Date of Patent: May 16, 1978Assignee: Bayer AktiengesellschaftInventor: Josef Schroeder
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Patent number: 4089851Abstract: Disazo dyestuffs of the formula ##STR1## IN WHICH K represents the radical of a coupling component of the benzene, acetoacetic acid arylide, pyrazolone or aminopyrazole series,R.sub.1 and R.sub.2 denote hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen andN denotes 1 or 2,Are suitable for the dyeing of natural and synthetic fibre materials and paper in greenish to reddish yellow shades. The dyeings particularly on polyamide have good to very good light fastness and good fastness to water and washing.Type: GrantFiled: June 15, 1976Date of Patent: May 16, 1978Assignee: Bayer AktiengesellschaftInventor: Hans Kramb
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Patent number: 4088651Abstract: Acylamino quinophthalone compounds which are free from sulfonic acid groups and correspond to the formula ##STR1## in which R.sub.1 and R.sub.2 are hydrogen, halogen, acylamino or lower alkoxy with the proviso that one of the residues R.sub.1 and R.sub.2 denotes acylamino while the other residue stands for hydrogen, halogen or a lower alkoxy; R.sub.3 is hydrogen, halogen or a lower alkoxy; X is a substituent; and n is a number from 0 to 3; are disclosed. The compounds useful as dyestuffs for hydrophobic fiber materials, e.g. polyester, are prepared by reacting an acylamino phthalic acid, the anhydride thereof, or mixtures of acylamino phthalic acids or the anhydrides thereof with a 3-hydroxy-quinalide.Type: GrantFiled: April 17, 1975Date of Patent: May 9, 1978Assignee: Bayer AktiengesellschaftInventors: Dietmar Kalz, Gerhard Wolfrum
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Patent number: 4088673Abstract: Process for the preparation of styryl dyestuffs, characterized in that, in a one-pot reaction, amines of the general formula form ##STR1## wherein R.sub.1 denotes alkyl or aryl,R.sub.2 denotes hydrogen, alkyl or aryl,R.sub.3 -r.sub.6 denote hydrogen or non-ionic substituents, preferably alkyl, alkoxy, nitro or halogen or R.sub.1 with R.sub.3 or R.sub.5 conjointly from the remaining members of a 5-membered or 6-membered ring system which optionally contains further hetero-atomsAre treated with at least 1 equivalent of a Vilsmeier reagent, unconverted Vilsmeier reagent is decomposed, the pH value is adjusted to above 4 by addition of bases and subsequently--without any intermediate isolation--the product is treated with a methylene-active compound of the formula ##STR2## wherein X represents a nitrile or acyl group.Type: GrantFiled: November 18, 1975Date of Patent: May 9, 1978Assignee: Bayer AktiengesellschaftInventors: Walter Gomm, Hermann Beecken