Patents Represented by Attorney R. A. Negin
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Patent number: 6080377Abstract: A method for reducing gaseous nitrogen oxides present in a gas stream by reaction with a reductant species is practiced by flowing the gas stream under lean NO.sub.X -reducing conditions in contact with a catalytic material containing a catalytically effective amount of a catalytic species, e.g., a platinum group metal, and a reductant storage material, e.g., a zeolite, effective for storing reductant species for reaction with NO.sub.X, and providing an intermittent supply of the reductant to the gas stream. The catalytic material may be prepared in any manner, but one method is to incorporate a catalytically effective amount of the platinum into a template-bearing molecular sieve material, preferably ZSM-5 zeolite, to hinder the platinum from being incorporated into the pores of the molecular sieve material, and then calcining the molecular sieve material, whereby the template is removed from the molecular sieve material after the platinum is incorporated therein.Type: GrantFiled: April 27, 1995Date of Patent: June 27, 2000Assignee: Engelhard CorporationInventors: Michel Deeba, Jennifer S. Feeley, Robert J. Farrauto
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Patent number: 5681538Abstract: A monolith suitable for use as a heat exchanger or as a carrier for a catalyst member is assembled from a plurality of plates (10, 10', 410) that are mounted one atop the next. The plates are generally rectangular and define a central baffle portion (12, 412) having a pair of substantially straight, parallel sides (14, 414) and having attached to the baffle portion at the ends thereof a support flange (18, 418) which is bendable upward into a configuration that enables it to support a second plate in spaced, parallel relation to the first plate, and anchor flanges (20, 420) that are bendable downward, to seal the corners of the monolith and, optionally, to engage the support flanges of one or more underlying plates.Type: GrantFiled: February 1, 1995Date of Patent: October 28, 1997Assignee: Engelhard CorporationInventors: Shiang Sung, John K. Hochmuth
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Patent number: 5597771Abstract: The present invention relates to a layered catalyst composite of the type generally referred to as a three-way conversion catalyst having the capability of substantially simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides. The structure of the layered catalyst composite of the present invention is designed wherein there is a first layer and a second layer. The first layer comprises a first support; at least one first palladium component and an oxygen storage component in intimate contact with the palladium component; optionally another first platinum group metal component; a zirconium component; at least one first alkaline earth metal components and at least one first rare earth metal component selected from the group consisting of lanthanum metal components and neodymium metal components.Type: GrantFiled: June 24, 1994Date of Patent: January 28, 1997Assignee: Engelhard CorporationInventors: Zhicheng Hu, Chung-Zong Wan, Yiu-Kwan Lui, Joseph C. Dettling
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Patent number: 5232615Abstract: The novel polymers of the present invention are prepared by reacting a heterocyclic nitrogen compound containing at least one --N(H)-- group in the ring, an aldehyde N-containing polymer adduct (e.g., an ashless nitrogen-containing dispersant or polyolefin-substituted amine) to form an oil soluble Mannich base derivative useful as dispersant, antiwear and antioxidant additive in oleaginous compositions such as lubricating oils and fuels. Preferred heterocyclic nitrogen compounds are azoles such as benzotriazoles and alkyl-substituted benzotriazoles. The polyolefin-substituted amine can comprises the reaction product of a polyamine and halogenated long chain hydrocarbons.Type: GrantFiled: March 8, 1990Date of Patent: August 3, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Abhimanyu O. Patil, Robert D. Lundberg
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Patent number: 5225091Abstract: The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 10,000 number average molecular weight substituted with thiocarboxylic acid producing moieties (preferably acid or anhydride moieties), wherein the terminal unsaturation comprises ethenylidene unsaturation. The thiocarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.Type: GrantFiled: April 15, 1991Date of Patent: July 6, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Won R. Song, Robert D. Lundberg, Robert A. Kleist
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Patent number: 5225092Abstract: The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight terminally substituted with amine compounds, which are also useful additives to oleaginous compositions, e.g., as fuel and lubricating oil dispersants.Type: GrantFiled: February 1, 1990Date of Patent: July 6, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Jacob Emert, Alan M. Schilowitz, Antonio Gutierrez, Won R. Song
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Patent number: 5217634Abstract: A material useful as a dispersant additive in oleaginous compositions selected from fuels and lubricating oils comprising the reaction products of:(i) at least one intermediate adduct comprised of the reaction products of(a) at least one polyepoxide, and(b) at least one member selected from the group consisting of polyamines, polyols, and amino alcohols; and(ii) at least one of (a) hydrocarbyl substituted C.sub.3 -C.sub.10 monocarboxylic or C.sub.4 -C.sub.10 dicarboxylic acid producing material; (b) an aldehyde and a hydrocarbyl substituted hydroxy aromatic compound; or (c) an aldehyde and the reaction product of a hydrocarbyl substituted C.sub.3 -C.sub.10 monocarboxylic or C.sub.4 -C.sub.10 dicarboxylic acid or anhydride and an amine substituted hydroxy aromatic compound.Also included is a process for preparing said material and an oleaginous composition containing said material.Type: GrantFiled: September 9, 1991Date of Patent: June 8, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Jacob Emert, Antonio Gutierrez, Robert D. Lundberg
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Patent number: 5213698Abstract: According to the present invention, improved dispersants are provided which comprise adducts of (A) polymer-substituted mono- and dicarboxylic acid or anhydrides and (B) an amido-amine characterized by being a reaction product of an alpha, beta-unsaturated compound of the formula: ##STR1## wherein X is sulfur or oxygen, Y is --OR.sup.4, --SR.sup.4, or --NR.sup.4 (R.sup.5) , and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl, and bis(para-amino cyclohexyl) methane or oligomers thereof.Type: GrantFiled: June 4, 1992Date of Patent: May 25, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Robert D. Lundberg, Robert A. Kleist
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Patent number: 5200103Abstract: The present invention is directed to oil-soluble lubricating oil additives comprising Mannich Base condensates of an alkyl substituted hydroxy aromatic compound with formaldehyde and an amine, wherein the alkyl-moiety of the aromatic compounds is derived from at least one ethylene alpha-olefin copolymer of 300 to 20,000 number average molecular weight, wherein at least about 30% of the polymer's chains contain terminal ethenylidene unsaturation. The Mannich Base condensates of this invention are useful as dispersants.Type: GrantFiled: February 1, 1990Date of Patent: April 6, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Won R. Song, Robert D. Lunberg, Antonio Gutierrez, Robert A. Kleist
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Patent number: 5186851Abstract: The present invention is directed to oil-soluble lubricating oil additives comprising Mannich Base condensates of an alkyl substituted hydroxy aromatic compound with formaldehyde and an amine, wherein the alkyl-moiety of the aromatic compounds is derived from at least one ethylene alpha-olefin copolymer of 300 to 10,000 number average molecular weight, wherein at least about 30% of the polymer's chains contain terminal ethenylidene unsaturation. The Mannich Base condensates of this invention are useful as dispersants.Type: GrantFiled: April 7, 1992Date of Patent: February 16, 1993Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Won R. Song, Robert D. Lundberg, Robert A. Kleist
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Patent number: 5167848Abstract: Oil soluble grafted ethylene-alpha-olefin copolymer useful as a viscosity modifier for oleaginous compositions comprising:(i) backbone copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crysallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.w /M.sub.w of less than 1.Type: GrantFiled: May 30, 1989Date of Patent: December 1, 1992Assignee: Exxon Chemical Patents Inc.Inventors: David Y. Chung, Mark J. Struglinski, John E. Johnston