Abstract: A high yield process is provided for treating lignocellulose food fiber to sanitize and bleach the fiber. The process is not only a high yield process but produces better or equivalent bleaching than alternative processes and further does not produce a waste disposal problem. The process also has the advantage of requiring very little energy compared to alternative processes.
Abstract: The invention is a sustained release dosage or delivery form, such as a tablet, pill, granule or the like capable of providing sustained release of a functionally active ingredient and the method for its manufacture. The invention comprises a matrix of a polymer containing functionally active ingredient and an excipient shaped at or above the glass transition temperature of said polymer into a form such as a granule, tablet or the like. Preferably the excipient is a microcrystalline cellulose.
Abstract: A process is provided to react anhydrous carbonate with a particle size between 300 and 74 micrometers and hydrogen peroxide containing a hydroxyalkylidene diphosphonic acid to produce sodium carbonate perhydrate containing 13% to 141/2% active oxygen. The process differs from the prior art in that reaction mixture is substantially dry at all times. The product is stable even without added stabilizers.
Abstract: Fats and proteins in wastewater are commonly concentrated in a dissolved air flotation cell as a sludge ("skimmings") which has a very high water content, even after centrifuging or the like. A process is provided to reduce the water content of the sludge thereby reducing the cost of disposal of the sludge.
Type:
Grant
Filed:
November 8, 1990
Date of Patent:
July 9, 1991
Assignee:
FMC Corporation
Inventors:
Harry M. Castrantas, Frank E. Caropreso
Abstract: A process is provided for a two-stage oxygen delignification of chemical pulp in which 0.01% to 1% hydrogen peroxide is incorporated into the first and, optionally the second stage. The invention is particularly suitable when the pulp is subsequently bleached with at least one chlorine dioxide stage and at least one hydrogen peroxide stage.
Type:
Grant
Filed:
May 19, 1989
Date of Patent:
April 30, 1991
Assignees:
FMC Corporation, North Carolina State University
Inventors:
V. R. Parthasarathy, Meenaksi Sundaram, Hasan Jameel, Josef S. Gratzl, Ronald J. Klein
Abstract: A process is provided for purifying phosphoric acid, such as wet process phosphoric acid by extracting the impure phosphoric acid with a nonaqueous solvent and contacting the nonaqueous solution of phosphoric acid with a strongly basic anion exchange resin and recovering the purified phosphoric acid by stripping the nonaqueous solution with an aqueous solution.
Abstract: It was unexpectedly found that a brominated phosphate ester, tris(2,4-dibromophenyl)phosphate when employed in flame retardant quantities in a modified polyphenylene oxide resin resulted in discoloration of the resin on aging. Neither phosphate esters, flame retardants nor brominated flame retardants when employed separately as flame retardants caused similar discoloration. The use of epoxy compounds counteracted this color stability problem.
Abstract: A stable hydrogen peroxide composition is provided of from 1% to 52% by weight hydrogen peroxide and 1,10-phenanthroline. The composition may contain other conventional additives suitable for stabilizing hydrogen peroxide.
Abstract: A novel process is provided for producing a pure triaryl phosphate ester free from phenolics without creating an undesirable waste product. After recovery of the triaryl phosphate ester the reactio mixture residue is converted into an emulsion suitable for use as a flame retardant useful for application to carpets.
Abstract: A manufacturing process and composition is claimed for a composition of matter comprising sodium carbonate, sodium carbonate perhydrate, a fluorescent whitening agent and a diphosphonic acid. The process comprises incorporating the fluorescent whitening agent and diphosphonic acid into aqueous hydrogen peroxide, uniformly applying the hydrogen peroxide solution to particulate sodium carbonate to form a reaction mixture, urging water vapor from the surface of the reaction mixture and maintaining the temperature of the reaction mixture between about 35.degree. C. and 80.degree. C.
Abstract: A novel composition of matter is claimed comprising particles which appear to comprise sodium carbonate, sodium percarbonate (also called sodium carbonate peroxide or sodium carbonate perhydrate), and a stabilizer for the compound, preferably a diphosphonic acid, the sodium carbonate being present in sufficient quantity to form sodium carbonate monohydrate by reacting with the available water in the composition.
Abstract: A novel process is claimed for manufacturing a composition of matter comprising particles which appear to comprise sodium carbonate, sodium carbonate peroxide and a stabilizer such as, a disphosphonic acid, the anhydrous sodium carbonate being present in sufficient quantity to form sodium carbonate monohydrate by reacting with all of the water formed on decomposition of the sodium percarbonate.
Abstract: A composition is provided of inorganic polyphosphates which will form a clear, stable solution suitable for injection into meat products. The composition comprises sodium tripolyphosphate and a long-chain glassy phosphate in sufficient quantities to provide 92 to 85 parts by weight sodium tripolyphosphate and 8 to 15 parts by weight of long-chain glassy phosphate, said long-chain glassy phosphate having a degree of polymerization of about 20 to 30, an average mole ratio of (Na.sub.2 O+H.sub.2 O)/P.sub.2 O.sub.5 below about 1.067, and preferably possessing terminal groups on the polyphosphate chain having no less than about 75% OH with the remainder being ONa.
Abstract: A process is provided for purifying finely divided minerals contacting organic material sufficiently to make the minerals useful for coating a filling paper or for use as catalysts, catalyst supports or the like. The process comprises concomitantly contacting an aqueous slurry of the mineral with a peroxygen and a gas containing ozone at a pH from 5 to 12. Preferably, the peroxygen is incorporated into the slurry prior to contacting the slurry with a gas containing ozone. Optionally, the slurry may be pretreated with a chelating agent or subsequently bleached with a reducing agent.
Type:
Grant
Filed:
March 31, 1989
Date of Patent:
June 19, 1990
Assignee:
FMC Corporation
Inventors:
Frank E. Caropreso, Harry M. Castrantas, J. Miller Byne
Abstract: A process is provided for making halogen-substituted triaryl phosphate esters which are normally solid under ambient conditions. The process comprises reacting a halogenated phenol with phosphorus oxychloride in the presence of a magnesium chloride catalyst above the melting point of the desired product. After the reaction is complete the product is recovered by adding an alcohol, such as, pentanol, 2-ethyl hexanol or hexanol and cooling the resulting mixture below the melting point of the product.
Abstract: A process is provided for reducing the concentration of microbial cells in a flowable fluid by dividing the fluid into a sterile permeate and a retentate reducing the pH of the retentate in an electrolytic cell, heating the retentate to reduce the concentration of microbial cells therein and increasing the pH of the permeate in an electrolytic cell and combining the retentate and permeate.
Type:
Grant
Filed:
March 10, 1989
Date of Patent:
November 14, 1989
Assignee:
FMC Corporation
Inventors:
Stratos E. Hatzidimitriu, W. Reginald Hall
Abstract: A process is provided for manufacturing tetrasodium pyrophosphate from sodium tripolyphosphate and a sodium salt capable of forming sodium carbonate on calcination. A compound capable of forming sodium carbonate is added to adjust the mol ratio to about 2, the mixture is milled and heated to from 300.degree. C. to 700.degree. C.
Abstract: A process is provided to remove inert contaminants from a working compound employed for the manufacture of hydrogen peroxide by the reduction and oxidation of a solution of alkylated anthraquinones and derivatives. The contaminants are removed by the process of contacting the working compound, a solvent, and carbon dioxide to form a first portion and a residue portion, separating the two portions and recovering the purified working solution from the first portion.
Abstract: The invention is a process to purify a solution of phosphoric acid by removing transition metal impurities such as iron, chromium and vanadium. In the process a solution of phosphoric acid in an organic solvent which is substantially immiscible with water is contacted with an aqueous solution of a salt of an alkali metal of phosphoric acid. The phosphoric acid recovered following the contacting contains a substantially lesser content of transition metal impurities.
Type:
Grant
Filed:
July 6, 1987
Date of Patent:
October 25, 1988
Assignee:
FMC Corporation
Inventors:
Jeffrey C. Dore, David P. Brochu, Richard E. Hall