Abstract: Polyamide-imides derived from trimellitic acid compounds and an aromatic diamine are improved in moisture resistance when from 10 to about 90 mole % of the trimellitic acid compound is replaced by a biphenyl tetracarboxylic acid compound.
Abstract: Resinous condensation polymers of polycarboxylic acid compounds and aromatic diprimary amines comprising diamino-t-butylbenzens are described. In particular, film-forming polyamides, polyimides and polyamide-imides and their copolymers made using diamino-t-butylbenzenes which have amino groups meta or para to each other on a benzene ring are described. These polymers have some solubility in organic solvents such as N-methylpyrrolidone, a high glass transition temperature, excellent thermal stability, and are useful in films, fibers and composites, and in the electronics industry as electrical component substrates, protective coatings, interlevel dielectrics and the like.
Type:
Grant
Filed:
April 25, 1990
Date of Patent:
November 6, 1990
Assignee:
Amoco Corporation
Inventors:
David J. Fenoglio, Douglas E. Fjare, John L. Melquist, Edwin F. Morello, Neal R. Nowicki
Abstract: Catalysts containing a reducible compound on a silica-containing support are provided for the conversion of a lower molecular weight alkane to more valuable, higher molecular weight hydrocarbons.
Type:
Grant
Filed:
February 23, 1987
Date of Patent:
November 6, 1990
Assignee:
Amoco Corporation
Inventors:
James L. Jezl, Glenn O. Michaels, Michael J. Spangler, Mark L Winzenburg
Abstract: Novel poly(aryl ether sulfone)-poly(aryl ether ketone) block copolymers are described. They are prepared by the nucleophilic polycondensation of a hydroxy- or halo-terminated poly(aryl ether ketone) oligomer with the poly(aryl ether sulfone) forming reagents; alternatively, a preformed poly(aryl ether sulfone) block may be used.The novel copolymers are tough materials with excellent heat, solvent, and stress-crack resistanced. They display high HDT's (heat distortion temperatures) and are useful in molding, extrusion and composites applications.
Type:
Grant
Filed:
August 22, 1988
Date of Patent:
November 6, 1990
Assignee:
Amoco Corporation
Inventors:
Markus Matzner, James H. Botkin, Paul A. Winslow
Abstract: Novel maleic anhydride catalysts comprising phosphorus-vanadium oxides and phosphorus-vanadium-co-metal oxides which under reaction conditions for the manufacture of maleic anhydride from butane feedstock do not expand to the point of crushing and producing fines. The catalyst being prepared by the process comprising rapidly heating the catalyst syrup during the drying of the syrup so that it reaches a temperature of at least about 150.degree. C. in less than about 10 hours.
Abstract: Blends comprising(A.) at least one poly(aryl) ether ketone), and(B.) at least one polyimide having repeating units of the formula ##STR1## wherein R.sup.1 is a substituted or unsubstituted tetravalent radical having benzenoid unsaturation, andR.sup.2 is a substituted or unsubstituted divalent group having aromatic unsaturation which is essentially free of (i) backbone ether oxygen bonded directly to the aromatic ring forming an imide linkage and (ii) amide linkages bonded through carboxyl groups bonded to the aromatic ring forming an imide linkage. The blends exhibit good melt processability and wear resistance greater than the individual blend components.
Abstract: Described herein are novel crystalline polyarylnitrile polymers which have excellent mechanical and thermal properties. Also, described is a process for producing such polyarylnitrile polymers.
Type:
Grant
Filed:
May 1, 1989
Date of Patent:
October 16, 1990
Assignee:
Amoco Corporation
Inventors:
Louis M. Maresca, Alford G. Farnham, Thomas H. Schwab, Ulrich A. Steiner
Abstract: In a kerogen agglomeration process, the oil shale is pretreated by comminuting the oil shale in the presence of an added organic liquid prior to contacting the oil shale with an added organic liquid and water to form kerogen-rich agglomerates and mineral-rich particles. The benefit is a reduction in comminution cost while maintaining about the same separation efficiency as methods having higher comminution costs.
Abstract: A method is described for improving the viscosity storage stability of a Mannich base condensation product of an oxidized polyolefin, formaldehyde, and an amine. This method involves contacting such Mannich base condensation product with a lower alkyl peroxide, a lower alkyl hydroperoxide or an aryl(lower)alkyl hydroperoxide at a temperature of about 250.degree. F. to about 400.degree. F. for a time period sufficient to provide an oxidized product.
Type:
Grant
Filed:
October 20, 1988
Date of Patent:
October 16, 1990
Assignee:
Amoco Corporation
Inventors:
David J. Fenoglio, Yoon S. Song, Robert J. Basalay
Abstract: Resinous condensation polymers of polycarboxylic acid compounds and aromatic diprimary amines comprising diamino-t-butyltoluene are described. In particular, film-forming polyamides, polyimides and polyamide-imides and their copolymers made using diamino-t-butyltoluene which have amino groups meta or para to each other on a benzene ring are described. These polymers have some solubility in organic solvents such as N-methylpyrrolidone, a high glass transition temperature, excellent thermal stability, and are useful in films, fibers and composites, and in the electronics industry as electrical component substrates, protective coatings, interlevel dielectrics and the like.
Type:
Grant
Filed:
April 9, 1990
Date of Patent:
October 16, 1990
Assignee:
Amoco Corporation
Inventors:
David J. Fenoglio, Douglas E. Fjare, John L. Melquist
Abstract: This invention relates to blends of amide-imide polymer or amide-imide-phthalamide polymer and polyaryletherketones which include an inorganic hydrate to stabilize the melt viscosity of the polymer blend. The invention also relates to a composition and a molded article.
Abstract: An improved delayed coking process using an improved method for adding antifoam materials to the delayed coking process. The process is directed to injecting a polysiloxane antifoam material in mixture with an inert gas in the absence or substantial absence of steam and wherein this mixture is heated and thereafter injected into a delayed coking drum. The process allows improved use of antifoam materials and prevents downstream contamination of process units with silica materials which can be broken down when the polysiloxane antifoam material is contacted with large quantities of steam within the coking drum.
Abstract: Gallium-containing, crystalline silicate molecular sieves in which substantially all of the gallium occupies molecular sieve lattice positions or is intimately associated with the crystal lattice of the silicate sieve when composited into a silica matrix are shown to form catalyst compositions having superior properties for the catalytic, liquid-phase isomerization of a xylene-containing stream containing a minor amount of ethylbenzene to a product mixture rich in paraxylene.
Type:
Grant
Filed:
December 15, 1988
Date of Patent:
October 9, 1990
Assignee:
Amoco Corporation
Inventors:
Jeffrey A. Amelse, John A. Donohue, Nancy A. Kutz, Judith B. Melville, Brian L. Slusar
Abstract: The invention relates to a process for the conversion of linear alkanes such as n-butane to dehydrogenated and isomerized products in the presence of a catalyst comprising a platinum component and a zincosilicate component.
Abstract: A method is disclosed for preparing one of more specific dimethylnaphthalene isomers by the isomerization of one or more other specific dimethylnaphthalene isomers in the liquid phase and in the presence of a solid zeolitic isomerization catalyst.
Type:
Grant
Filed:
October 23, 1989
Date of Patent:
October 9, 1990
Assignee:
Amoco Corporation
Inventors:
David Sikkenga, Ian C. Zaenger, Gregory S. Williams
Abstract: This invention relates to preparation of polyamide-imide foam by extruding foamable composition comprising polyamide-imide and volatiles into a confined expansion zone, expanding the composition therein and cooling the result. The resulting foams are essentially open-celled and exhibit good strength, insulating properties and other desirable features.
Type:
Grant
Filed:
May 23, 1988
Date of Patent:
October 2, 1990
Assignee:
Amoco Corporation
Inventors:
Gary T. Brooks, Brian C. Connolly, Robert Riley
Abstract: A low modulus, solvent resistant, wet etchable polyimide useful electronic applications as passivation and insulating coatings, said polyimides containing a 4,4'-bis(p-aminophenoxy)biphenyl moiety, a siloxane diamine moiety, and a dianhydride moiety.
Type:
Grant
Filed:
March 9, 1990
Date of Patent:
October 2, 1990
Assignee:
Amoco Corporation
Inventors:
Marvin J. Burgess, David A. Wargowski, Agnes M. Palka
Abstract: Described herein are novel amino-terminated poly(aryl ether ketone) oligomers and methods for their production. These amino-terminated poly(aryl ether ketone) oligomers are used as building blocks for a variety of polymers and copolymers.
Abstract: Disclosed is a hydrocracking process wherein the feedstock is contacted in a first reaction zone with a first reaction zone catalyst comprising a nickel component and a tungsten component deposed on a support component consisting essentially of an alumina component and a crystalline molecular sieve component. The effluent from the first reaction zone effluent is then contacted in a second reaction zone with a second reaction zone catalyst comprising a cobalt component and a molybdenum component deposed on a support component comprising an alumina component and a crystalline molecular sieve component.
Type:
Grant
Filed:
March 27, 1989
Date of Patent:
September 25, 1990
Assignee:
Amoco Corporation
Inventors:
Simon G. Kukes, Louis C. Gutberlet, Albert L. Hensley