Patents Represented by Attorney Richard A. Haggard
  • Patent number: 5686528
    Abstract: High-impact poly(styrene) resins modified with small-particle-size, multi-stage impact modifiers having a crosslinked poly(butadiene) core and a poly(styrene) or other vinylaromatic polymer shell show an improved balance of impact strength, stiffness and surface gloss, and an improved resistance to environmental stress crazing, when compared to conventional high-impact poly(styrene).
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: November 11, 1997
    Assignee: Rohm and Haas Company
    Inventors: William L. Wills, Albin P. Berzinis
  • Patent number: 5643645
    Abstract: A melt calendered sheet and a process for making melt calendered sheet having excellent transparency and solvent craze resistance. Clear melt calendered sheet having a critical stress rating above 12,000 KPa, heat distortion temperature above 85.degree. C., and flexural modulus above 3,275 MPa is produced from acrylic copolymer having a melt flow rate of from about 0.3 to about 1.3 grams/10 minutes.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 1, 1997
    Assignee: Ato Haas B.V.
    Inventors: Harold Reid Banyay, Michael S. Cholod, Laurence Mitchell Kolanko, Bonnie Vineis Smith
  • Patent number: 5571386
    Abstract: The invention provides a continuous process for producing a pure grade of acrylic acid having residual aldehyde levels under 10 parts per million. The process applies two groups of amines sequentially and continuously in selectively reducing acrolein and furfural and may be advantageously conducted in the presence of maleic acid and maleic anhydride impurities.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: November 5, 1996
    Assignee: Rohm and Haas Company
    Inventors: William Bauer, Jr., Timothy A. Hale, Robert M. Mason, Rita K. Upmacis
  • Patent number: 5561205
    Abstract: A tetravalent organotin containing compound where the tin atom is attached via an alkyl group to a phenyl moiety with a polymerizable group thereon, is useful as a monomer. A polymer prepared from the monomer. A transesterification catalyst prepared from the polymer and a process for conducting a transesterification reaction using the transesterification catalyst.
    Type: Grant
    Filed: March 31, 1995
    Date of Patent: October 1, 1996
    Assignee: Rohm and Haas Co.
    Inventors: Oian Jiang, Christine McDade, Andrew W. Gross
  • Patent number: 5549941
    Abstract: A melt calendered sheet and a process for making melt calendered sheet having excellent transparency and solvent craze resistance. Clear melt calendered sheet having a critical stress rating above 12,000 KPa, heat distortion temperature above 85.degree. C., and flexural modulus above 3,275 MPa is produced from acrylic copolymer having a melt flow rate of from about 0.3 to about 1.3 grams/10 minutes.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: August 27, 1996
    Assignee: Atohaas Bolding C.V.
    Inventors: Harold R. Banyay, Michael S. Cholod, Laurence M. Kolanko, Bonnie V. Smith
  • Patent number: 5539054
    Abstract: The invention relates to thermoplastic polyurethane blends containing at least one thermoplastic polyurethane and at least one copolymer, the copolymer derived from at least 5 weight percent of an N-vinyl lactam monomer unit. Blends of the invention generally are compatible or miscible, and many exhibit clarity and other physical properties, such as tensile modulus, distortion resistance and impact resistance, which are improved over the properties of the thermoplastic polyurethane component of the blend or of thermoplastic polyurethanes blends in the art.
    Type: Grant
    Filed: February 23, 1995
    Date of Patent: July 23, 1996
    Assignee: Rohm and Haas Company
    Inventor: Edward E. LaFleur
  • Patent number: 5523480
    Abstract: A process for the preparation of an .alpha.,.beta.-unsaturated C.sub.3 -C.sub.6 carboxylic acid of greater than 98% purity, which combines fractional distillation and melt crystallization procedures.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: June 4, 1996
    Assignee: Rohm and Haas Company
    Inventors: William Bauer, Jr., Robert M. Mason, Rita K. Upmacis
  • Patent number: 5488141
    Abstract: This invention is a method for removing certain carbonyl containing impurities from .alpha.,.beta.-unsaturated carboxylic acid ester with an aqueous solution of a bisulfite or dithionite salt.
    Type: Grant
    Filed: June 10, 1994
    Date of Patent: January 30, 1996
    Assignee: Rohm and Haas Company
    Inventors: William Bauer, Jr., Nelson I. Quiros, Rita K. Upmacis
  • Patent number: 5436357
    Abstract: A tetravalent organotin containing compound where the tin atom is attached via an alkyl group to a phenyl moiety with a polymerizable group thereon, is useful as a monomer. A polymer prepared from the monomer. A transesterification catalyst prepared from the polymer and a process for conducting a transesterification reaction using the transesterification catalyst.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: July 25, 1995
    Assignee: Rohm and Haas Company
    Inventors: Qian Jiang, Christine McDade, Andrew W. Gross
  • Patent number: 5406641
    Abstract: Process for cured composites and flexible light pipe, in which a molten cladding polymer and a crosslinkable core mixture are coaxially extruded through a coextrusion die, the cladding is filled with the crosslinkable core mixture, and the crosslinkable core mixture is cured within the cladding.
    Type: Grant
    Filed: June 15, 1993
    Date of Patent: April 11, 1995
    Assignee: Rohm and Haas Company
    Inventors: Andrew B. W. Bigley, Jr., Jeffrey L. Daecher, Norman L. Holy, Robert E. Jerman, Phelps B. Johnson, William J. Work
  • Patent number: 5324456
    Abstract: Polymers of (N-lower alkyl)dimethylglytarimide or (N-hydrogen)-dimethylglutarimide are resistant to molecular weight degradation and yellowing on exposure to heat and ultraviolet or visible light by inclusion of a hindered piperazinone stabilizer.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: June 28, 1994
    Assignee: Rohm and Haas Company
    Inventor: Darnel Degraff
  • Patent number: 5318737
    Abstract: A method for preparing a plastic composite by feedblock coextrusion of a molten acrylic based capstock overlying and integrally bonded to an underlying structural plastic ply. The composition of the capstock contains from about 40 to about 88 wt. % of an acrylic polymer having a molecular weight of at least about 125,000 daltons, and from about 12 to about 60 wt. % of an acrylate-based impact modifier resin in the form of discrete multi-layered polymeric particles. The capstock composition has a melt flow index of about 0.4 to about 0.75 grams/10 minutes (ASTM Method D-1238, Condition I) and the underlying structural ply has substantially the same melt flow index as that of the capstock composition.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: June 7, 1994
    Assignee: Rohm and Haas Company
    Inventors: Loren D. Trabert, Robert L. Post, Edward G. Ludwig
  • Patent number: 5186993
    Abstract: The invention is directed to clear polymer blends of acrylic/vinyl aromatic copolymers with certain core-shell polymer impact modifiers. The core-shell modifiers have lightly crosslinked, predominantly diolefinic rubbery cores and one or more hard shells.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: February 16, 1993
    Assignee: Rohm and Haas Company
    Inventors: Michael P. Hallden-Abberton, William L. Wills
  • Patent number: 5166239
    Abstract: The invention is directed to stabilizer compositions, to polymers containing these stabilizer compositions for use as additives in polymeric matrices, and to polymeric products which contain these additives. The stabilizer compositions comprise a ternary composition of a sterically hindered phenol, a less sterically hindered phenol, and an organic phosphite. These compositions are admixed with polymers to provide polymeric additives to improve the physical and mechanical properties of polymeric matrices.
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: November 24, 1992
    Assignee: Rohm and Haas Company
    Inventors: Nazir A. Memon, Joseph C. Koziar
  • Patent number: 5164434
    Abstract: The invention is directed to stabilizer compositions, to polymers containing three stabilizer compositions for use as additives in polymers, and to polymeric products which contain these additives. The stabilizer compositions comprise a compositon of: a) at least two hindered phenols and b) a sulfide. These compositions are admixed with polymers to provide polymeric additives to improve the physical and mechanical properties of polymers matrices.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: November 17, 1992
    Assignee: Rohm and Haas Company
    Inventors: Susan M. Liwak, Nazir A. Memon