Patents Represented by Attorney Richard Francis
  • Patent number: 5030496
    Abstract: A flexible and resilient, nonwoven, surface treating article formed of entangled synthetic fibers bonded together at points where they contact one another by a binder resin comprising plasticized vinyl resin and polymerized amine-formaldehyde derivative.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: July 9, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Jon P. McGurran
  • Patent number: 5011508
    Abstract: Sintered ceramic abrasive grains having increased surface area and a method of making the same are provided. The abrasive grains are incorporated into improved "shelling-resistant" abrasive articles such as coated abrasives, grinding wheels and non-woven abrasives. The ceramic abrasive grains are made by providing first particles comprising alpha-alumina precursor, introducing fine particles which can be sintered directly to the surface of the first particles upon sintering of the same, and heating the mixture of particles under sintering conditions to cause autogenous bonding of the fine particles to the surface of each of the first particles.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: April 30, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Vernon M. Wald, Robert S. Kirk
  • Patent number: 5011512
    Abstract: A coated abrasive article comprised of a blend of premium abrasive grains and nonabrasive diluent grains adhered to a backing material by a resinous binder. The article has an unexpected abrading efficiency, performing equal to, or superior to, a coated abrasive article containing only premium abrasive grains.
    Type: Grant
    Filed: January 25, 1990
    Date of Patent: April 30, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Vernon M. Wald, Richard A. Masson, Fredrick D. Brown, David E. Broberg
  • Patent number: 4996266
    Abstract: The present invention relates to a method of making elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The method comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
    Type: Grant
    Filed: March 24, 1989
    Date of Patent: February 26, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: William R. Bronn, Spencer F. Silver, Eugene G. Joseph
  • Patent number: 4988370
    Abstract: This invention concerns the discovery that sol-gel process alumina abrasive grain provides superior performance in bonded abrasives for grinding cast iron. In a preferred form it is disclosed that bonded abrasives of sol-gel process alumina abrasives in combination with other abrasive grains such as those of silicon carbide and fused alumina also provide superior grinding of cast iron.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: January 29, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Douglas G. Haynes, Jr.
  • Patent number: 4980096
    Abstract: Surfactants which are blocked against surfactant action (identified herein as "photolabile blocked surfactants") by a photolabile protective or masking group but which, on exposure to actinic radiation, become unblocked are provided. Coating compositions in which surfactant is formed on irradiation are provided by blending the photolabile blocked surfactant with polymeric film-forming materials.Compositions containing the photolabile blocked surfactants are useful when employed as protective coatings on various substrates or as the adhesive in a pressure sensitive adhesive tape. Although initially well adhering to a substrate, such compositions may be readily removed from the substrate following exposure of the same to suitable radiation which unblocks the surfactant to permit it to regain its surfactant activity.
    Type: Grant
    Filed: January 15, 1988
    Date of Patent: December 25, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gilbert L. Eian, John E. Trend
  • Patent number: 4964883
    Abstract: A process of producing alpha alumina ceramic abrasive grain by sintering alpha alumina monohydrate is improved by seeding with a crystalline oxide of iron having a particle size of less than 150 nm.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: October 23, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Mary Lou Morris, Thomas E. Wood
  • Patent number: 4957810
    Abstract: Articles comprise a body made of hydrophobic synthetic partially open-cell material at least partially covered with a layer of hydrophilic material. The body of each article is characterized by the fact that it has a specific surface at least equal to about 40 cm.sup.2 /cm.sup.3, and at least about 25% of its internal and external surface has a surface energy at least equal to about 73.times.10.sup.-7 newton/meter. The articles find use as sponges, so-called suede type materials, and wiping clothes. The sponges may be used for wiping, cleaning and other household or industrial uses.
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: September 18, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Bernard Eleouet, Michel Ramage, Gilles Rongier
  • Patent number: 4933373
    Abstract: A molded abrasive article comprising abrasive particles dispersed throughout and adhered within a crosslinked polyurethane binder matrix having a glass transition temperature greater than about 10.degree. C. and a glass transition temperature range of greater than about 70.degree. C.
    Type: Grant
    Filed: April 6, 1989
    Date of Patent: June 12, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Louis S. Moren
  • Patent number: 4930266
    Abstract: Abrasive sheeting can produce fine finishes at surprisingly high cutting rates when its abrasive granules are individually positioned in a predetermined pattern, with an uncoated portion of virtually every granule protruding from the surface of the binder layer. Each of the abrasive granules preferably is a spherical composite of a large number of abrasive grains in a binder. For example, abrasive grains having a mean dimension of about 4 .mu.m can be bonded together to form spherical abrasive granules of virtually identical diameters, preferably within a range of from 25 to 100 .mu.m.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: June 5, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Clyde D. Calhoun, George D. Foss, Maurice J. Fleming, Wesley J. Bruxvoort
  • Patent number: 4906691
    Abstract: The present invention relates to pressure-sensitive adhesive compositions comprising tackified elastomeric copolymers or block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The invention also provides sheet materials coated with the adhesive compositions. The polymers of the present invention are made by a method which comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic-substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: March 6, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Eugene G. Joseph, Spencer F. Silver, William R. Bronn
  • Patent number: 4883501
    Abstract: This invention concerns the discovery that sol-gel process alumina abrasive grain provides superior performance in bonded abrasives for grinding cast iron. In a preferred form it is disclosed that bonded abrasives of sol-gel process alumina abrasives in combination with other abrasive grains such as those of silicon carbide and fused alumina also provide superior grinding of cast iron.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: November 28, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Douglas G. Haynes, Jr.
  • Patent number: 4881951
    Abstract: Ceramic abrasive grits comprising alpha alumina and at least about 0.5 percent by weight rare earth metal oxide are prepared by combining alumina hydrate and rare earth metal oxide or its precursors to produce a blend, drying the blend to produce a dried solid, crushing the dried solid to produce grits, calcining the dried grits to substantially remove bound volatile materials, and firing the grits to produce a ceramic material. The rare earth metal is selected from the group consisting of praseodymium, samarium, ytterbium, neodymium, lanthanum, gadolinium, cerium, dysprosium, erbium, and mixtures of one or more rare earth metal.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: November 21, 1989
    Assignee: Minnesota Mining and Manufacturing Co.
    Inventors: Larry D. Monroe, William P. Wood
  • Patent number: 4871376
    Abstract: Improved resin/filler compositions for use in forming coated abrasives having a substrate/bonding system/abrasive composite structure, are provided. Also, methods for making such improvements are described. In general, the improvements result from inclusion in the resin/filler composition, a coupling agent providing for bonding between the resin and the filler. Preferred classes of coupling agents comprise: silanes, titanates, and zircoaluminates. Improvements effected by methods according to the present invention concern: viscosity of resulting resin/filler mixtures, retention of filler in suspension with a resin, and improved performance characteristics of products made according to the method, in particular improved resistance to deterioration upon contact with water, or upon use and/or storage in humid environments.
    Type: Grant
    Filed: December 14, 1987
    Date of Patent: October 3, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Carolyn G. DeWald
  • Patent number: 4857618
    Abstract: The present invention relates to elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The polymers are made by a method which comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to proudce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: August 15, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Spencer F. Silver, William R. Bronn, Eugene G. Joseph
  • Patent number: 4857615
    Abstract: The present invention relates to a method of making elastomeric copolymers and block copolymers, e.g., based upon styrene/isoprene, having a novel condensed phase structure wherein polymer branches occur along the polymer backbone, either at a predetermined location or at random locations. The method comprises the step of reacting, under polymerization conditions, hydrocarbyl lithium initiator, at least one anionically polymerizable compound, and an organometallic- substituted styrene condensing agent. The reactants may be added simultaneously to produce a copolymer with polymer branch segments randomly located along the polymer backbone or sequentially to produce a copolymer with branches located at the same predetermined location along the polymer backbone. The resultant polymers may be further reacted with a linking agent to form multi-arm copolymers.
    Type: Grant
    Filed: October 9, 1987
    Date of Patent: August 15, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: William R. Bronn, Spencer F. Silver, Eugene G. Joseph
  • Patent number: 4851278
    Abstract: An improved hot melt pressure sensitive adhesive composition comprises copolymerized monomeric acrylate or methacrylate ester of a non teritary alcohol, polar monomer such as acrylic acid, 2-polystyrylethyl methacrylate macromolecular monomer and sufficient zinc carboxylate to endow the composition with improved melt flow properties and cohesive strength. The invention also provides adhesive coated sheet materials comprising the adhesive composition coated onto a flexible sheet.
    Type: Grant
    Filed: February 25, 1988
    Date of Patent: July 25, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Rudyard M. Enanoza
  • Patent number: 4842619
    Abstract: An abrasive article for polishing glass and ceramic surfaces comprised of a combination of abrasive particles and inorganic glass polishing aid dispersed throughout a three-dimensional nonwoven fibrous web of organic material, and adhered therein by a resinous binder. The article is capable of refining a ground glass or ceramic surface to a highly polished surface faster than abrasive articles known in the art.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: June 27, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Peter J. Fritz, Joseph C. Nnebedum
  • Patent number: 4839455
    Abstract: The present invention relates to one-part, moisture-curable, urethane compositions suited as a coating for wood. The composition comprises trisocyanate prepolymer, an epoxy silane, and compatible solvent.
    Type: Grant
    Filed: August 28, 1987
    Date of Patent: June 13, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: James J. Fong
  • Patent number: 4820566
    Abstract: A tufted carpet having a backing which has thereon a plurality of tufts of fine denier fibers and a plurality of tufts of stiff, crimped, coarse denier fibers. A preferred pattern of tufts is alternate stripes or a checkerboard of areas consisting essentially of tufts of one type of fiber in an area.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: April 11, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard F. Heine, Gene E. Tharp