Abstract: Polyamide-imides derived from trimellitic acid compounds and an aromatic diamine are improved in moisture resistance when from 10 to about 90 mole % of the trimellitic acid compound is replaced by a biphenyl tetracarboxylic acid compound.
Abstract: Fiber-reinforced compositions comprising a structural fiber and a cyanate ester resin formulation having an N-substituted urea compound as a latent cure accelerator provide rapid-curing prepreg with good out-time characteristics. The prepreg may be used to form composite articles with good toughness and excellent retention of properties on extended exposure to moisture at elevated temperatures.
Type:
Grant
Filed:
March 24, 1989
Date of Patent:
June 5, 1990
Assignee:
Amoco Corporation
Inventors:
Shahid P. Qureshi, Hugh C. Gardner, Richard H. Newman-Evans
Abstract: Urea compounds having a plurality of substituents selected from hydrogen, substituted hydrocarbyl radicals and unsubstituted hydrocarbyl radicals are good latent cure accelerators for thermosetting cyanate resin formulations. The resulting cyanate resin formulations are useful as coatings, adhesives and as impregnating resins, particularly in applications where extended storage at or near room temperature is desired.
Type:
Grant
Filed:
September 28, 1988
Date of Patent:
April 17, 1990
Assignee:
Amoco Corporation
Inventors:
Hugh C. Gardner, Richard H. Newman-Evans
Abstract: Novel tetraglycidates have the formula ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen, alkyl of 1 to 8 carbon atoms, perfluoroalkyl, or cycloalkylidene of 5 to 7 carbon atoms. Epoxy resin systems exhibiting good tensile properties and moisture sensitivity can be made by copolymerizing the tetraglycidates with a polyamine curing agent. Prepregs can be made by combining the epoxy resin systems with a fiber reinforcement. The epoxy resin system may include a co-epoxide.
Abstract: Described herein are miscible blends of polycarbonomides, defined as amide and/or imide containing polymers, and a polyarylate or arylate-carbonate copolymer which are useful in the manufacture of extruded sheets, high temperature connectors, aircraft and mass transportation vehicle interiors, injection molded articles, and extruded profiles and thermoformable articles.
Type:
Grant
Filed:
August 29, 1988
Date of Patent:
November 7, 1989
Assignee:
Amoco Corporation
Inventors:
James E. Harris, Markus Matzner, Lloyd M. Robeson
Abstract: Novel curable resin compositions are disclosed containing an aromatic cyanate ester and an allyl ether of a bisphenol as a modifier. These compositions provide improved prepregs and composites. Additional modifiers including epoxy resins and bismaleimides may be included.
Abstract: Carbon fibers may be made by a process comprising:overwrapping a multifilament polyacrylonitrile tow with a thread of material to maintain the tow as an integral bundle, followed bystabilizing said tow by heating in an oxidizing atmosphere at a temperature between about 180.degree. and about 400.degree. C., thereby oxidizing the filaments comprising said tow, followed bycarbonizing the tow thus stabilized by heating at a temperature sufficient to effect carbonization, thereby forming a carbon fiber.The carbon fibers may be used to make reinforced composites in thermoplastic or thermosetting matrix resins, particularly prepreg.
Abstract: Novel bismaleimide resin formulations are described which contain olefinic ether reactive diluents. These formulations provide a combination of prepreg processing characteristics and thermal and mechanical properties unavailable from other reactive diluents. Preferred diluents contain one or more alkyl ether groups.
Abstract: Moulded articles of uniform wall thickness are prepared by vacuum-forming or thermoforming a composition comprising a uniform blend of, as base resin, a moulding grade resin having a continuous phase of a first copolymer of a styrenic monomer and an ethylenically unsaturated nitrile and a minor proportion of, as additive resin, a second copolymer of a styrenic monomer and an ethylenically unsaturated nitrile having an ultra high molecular weight, the forming operation being carried out at least 50.degree. C. above the glass transition temperature of the base resin and at a stress level of at most 1 MPa.
Abstract: Novel 3-ring tetraglycidates having the formula ##STR1## wherein ##STR2## Y=halogen, C.sub.1 -C.sub.4 alkyl; and n=0 to 4, are disclosed.Epoxy resin systems exhibiting good tensile properties and moisture sensitivity can be made by copolymerizing the tetraglycidates with a polyamine curing agent. Prepregs can be made by combining the epoxy resin systems with a fiber reinforcement. The epoxy resin system may include a co-epoxide.
Abstract: Ethylenically-unsaturated ethers of alkenyl phenols are useful as reactive diluents for bismaleimides. Formulations comprising bismaleimides and the reactive diluents of this invention are particularly useful for producing heat and moisture resistant fiber-reinforced composites.
Abstract: Process for producing resin-impregnated fiber tow or strand in the form of prepreg tape which includes unique coating wheels for surface-coating the strand with molten, flowable resin and a kneading section to work the strand and disperse the molten resin uniformly among and between the individual fibers of the strand. The strand, after chilling, has good dimensional stability and is useful as prepreg in forming composite structures.
Type:
Grant
Filed:
December 17, 1986
Date of Patent:
February 14, 1989
Assignee:
Amoco Corporation
Inventors:
Richard G. Angell, Jr., Michael J. Michno, Jr., John M. Konrad, Kenneth E. Hobbs
Abstract: Urea compounds having a plurality of substituents selected from hydrogen, substituted hydrocarbyl radicals and unsubstituted hydrocarbyl radicals are good latent cure accelerators for thermosetting cyanate resin formulations. The resulting cyanate resin formulations are useful as coatings, adhesives and as impregnating resins, particularly in applications where extended storage at or near room temperature is desired.
Type:
Grant
Filed:
July 8, 1987
Date of Patent:
February 14, 1989
Assignee:
Amoco Corporation
Inventors:
Hugh C. Gardner, Richard H. Newman-Evans
Abstract: Alpha-(4-maleimidophenyl)-alpha'-(4-isomaleimidophenyl) diisopropyl benzene, as a novel composition of matter. The compound, which may be used as a component of curable thermoset resins or as a unique, difunctional synthesis intermediate having non-symmetrical reactivity, may be prepared from the corresponding bis-maleamic acid by dehydrating at or below ordinary, ambient temperatures, using acetic anhydride or a similar dehydrating agent.
Abstract: Aryl ether sulfone polymers comprising a 4,4'-bis-phenylsulfonyl biphenyl and at least two additional arylene structural units exhibit improved toughness and stress crack resistance and a reduced tendency toward crystallization. The polymers and soluble and film-forming from solution, and may be used as coating and impregnating resins for producing laminates, fiber-reinforced composites and the like.
Type:
Grant
Filed:
August 4, 1987
Date of Patent:
November 15, 1988
Assignee:
Amoco Corporation
Inventors:
James E. Harris, Louis M. Maresca, Markus Matzner
Abstract: Novel curable resin compositions are disclosed containing an aromatic cyanate ester and an allyl ether of a bisphenol as a modifier. These compositions provide improved prepregs and composites. Additional modifiers including epoxy resins and bismaleimides may be included.
Abstract: Described herein is a composition which contains a specific group of hardeners, an epoxy resin and a thermoplastic polymer. When combined with a structural fiber the composition produces composites which have improved impact resistance, improved tensile properties and high compressive properties.
Type:
Grant
Filed:
January 8, 1987
Date of Patent:
July 26, 1988
Assignee:
Amoco Corporation
Inventors:
Hugh C. Gardner, Michael J. Michno, Jr., George L. Brode, Robert J. Cotter
Abstract: Thermal stabilization of olefin polymers, particularly polypropylene. Stabilization is accomplished by means of an ester of a pentaerythritol monoacetal. The ester contains a phenolic group.
Type:
Grant
Filed:
March 6, 1985
Date of Patent:
July 5, 1988
Assignee:
Borg-Warner Chemicals, Inc.
Inventors:
Ingenuin Hechenbleikner, William P. Enlow
Abstract: Composites comprising structural fibers such as carbon fibers and, as the matrix resin, an aryl ether sulfone polymer comprising a 4,4'-bis-phenylsulfonyl biphenyl and at least two additional arylene structural units. The matrix resins exhibit improved toughness and stress crack resistance and a reduced tendency toward crystallization. The polymers are soluble and film-forming from solution, and may be used as coating and impregnating resins for producing the laminates and fiber-reinforced composites of this invention.
Type:
Grant
Filed:
August 10, 1987
Date of Patent:
July 5, 1988
Assignee:
Amoco Corporation
Inventors:
James E. Harris, Michael J. Michno, Jr.
Abstract: Diamines of the structure ##STR1## Wherein X is --SO.sub.2 -- or --CO--, Y is O or S, and Ar is a linear aryl ether moiety comprising from 1 to 80 aryl rings, are epoxy resin curing agents providing cured resins with improved moisture resistance and toughness. The resins are particularly useful in preparing prepregs and composites.