Abstract: The present invention relates to an additive, and its use for inhibiting nucleation, growth and agglomeration of gas hydrates by adding an effective amount of an inhibitor to a multiphasic mixture which tends to hydrate formation and consists of water, gas and optionally condensate, or to a drilling fluid which tends to form gas hydrates. Said inhibitor comprising dialkoxylated quaternary ammonium compounds of the formula 1 where R1, R2 are each independently radicals of the formulae—(B)—(O—A)n—O—CO—R5 or —(A—O)n—(C)—CO—O—R5, R3 is C1- to C30-alkyl or C2- to C30-alkenyl, R4 is an organic radical which optionally contains heteroatoms and has from 1 to 100 carbon atoms, R5 is an alkyl or an alkenyl, n is a number from 1 to 20, A is an alkylene group, B is an alkylene group, C is a C1- to C6-alkylene group and X is an anion, are used as gas hydrate inhibitors.
Abstract: The invention relates to an additive and to a method of corrosion inhibition on devices for the recovery and transportation of hydrocarbons in crude oil recovery and processing by adding an effective amount of an inhibitor. The inhibitor comprises an alkoxylated quaternary compounds of the formula 1 where R1, R2 are independently groups of the formula —(B)—(O—A)n—O—CO—R5 or —(A—O)n—(C)—CO—O—R5, R3 is C1— to C30-alkyl or C2— to C30-alkenyl, R4 is an organic radical with 1 to 100 carbon atoms optionally containing heteroatoms, R5 is an alkyl or an alkenyl, n is a number from 1 to 20, A is an alkylene group, B is an alkylene group, C is a C1— to C6-alkylene group and X is an anion, used as corrosion inhibitors.
Abstract: The invention provides water-soluble or water-swellable copolymers obtained by free-radical copolymerization of A) acryloyldimethyltaurine and/or acryloyldimethyltaurates, B) if desired, one or more other olefinically unsaturated, optionally crosslinking comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and possessing a molecular weight of less than 500 g/mol, the copolymerization C) taking place in the presence of at least one polymeric additive having a number-average molecular weight of from 200 g/mol to 109 g/mol. The water-soluble or water-swellable copolymers of the present invention are useful in paper processing, laundry detergents, textile processing, petroleum extraction and formulating cosmetics.
Abstract: A method for reducing or completely eliminating water influx in an oil or natural gas borehole includes introducing in the borehole an aqueous solution of a copolymer comprising: A) 40–98 wt. % of structural units of formula (I), wherein: R1 is hydrogen or methyl; R2 represents C2–C10 alkylene; and Me+ represents an ammonium metal ion and an alkali metal ion; B) 0.1 to 58 wt. % of structural units of formula (II); C) 0.1 to 10 wt. % of structural units of formula (III), wherein: R3 and R4 independently of each other represent hydrogen, methyl or ethyl, or R3 and R4 represent together a propylene group, which, with inclusion of a radical (A), form a pyrrolidon radical or, with inclusion of a pentamethylene group, forms a caprolactam radical; D) 0.10 to 10 wt % of structural units of formula (IV). The method also includes introducing in the ground or deposit, simultaneously with the copolymer or subsequently, an agent for crosslinking the copolymer.
Type:
Grant
Filed:
September 24, 2002
Date of Patent:
December 19, 2006
Assignee:
Clariant UK Ltd.
Inventors:
Karl Heinz Heier, Christoph Kayser, Aranka Tardi, Michael Schaefer, Roman Morschhaeuser, James C Morgan, Alistair M. Gunn
Abstract: Process for the preparation of bleach activator granules, which comprises extruding a mixture comprising bleach activator, anionic or nonionic surfactant and polyalkylene glycol at temperatures of from 40 to 120° C. and a pressure of from 5 to 30 bar, and granulating the resultant extrudates at a temperature of from 40 to 120° C. on a spheronizer.
Abstract: Liquid bleaching composition components are claimed which comprise 1) amphiphilic copolymers which include structural units which are derived from a) acryloyldimethyltauric acid in free, partially neutralized or completely neutralized form with mono- or divalent inorganic or organic cations and b) at least one hydrophobic comonomer based on ethylenically unsaturated polyalkylene alkoxylates and optionally c) further at least monovinylically unsaturated comonomers different from a) and b), and 2) at least one bleach activator, bleach catalyst or oxygen transfer agent.
Type:
Grant
Filed:
December 4, 2003
Date of Patent:
September 19, 2006
Assignee:
Clariant GmbH
Inventors:
Gerd Reinhardt, Irina Geiger, Matthias Loeffler, Roman Morschhaeuser
Abstract: A method for the flotation of sulfide ores is disclosed. The method comprises contacting the sulfide ores with a composition comprising at least one compound of the formula where R1, R2 and R3 independently of one another are alkyl groups having 1 to 18 carbon atoms, alkenyl groups having 2 to 18 carbon atoms, aryl groups having 6 to 10 carbon atoms, or alkylaryl groups having 7 to 10 carbon atoms.
Type:
Grant
Filed:
July 22, 2003
Date of Patent:
September 12, 2006
Assignee:
Clariant GmbH
Inventors:
Tobias Rau, Heinrich Hesse, Wolfgang Buch, Jaime Gomez, Miguel Angel Arends, Norbert Ernstorfer
Abstract: Method of hydrodechlorinating nuclear-chlorinated o-xylenes and recovering o-xylene, forming hydrogen chloride, the nuclear-chlorinated o-xylenes being hydrogenated in the gas phase at a noble-metal-containing catalyst at a temperature in the range from 220 to 360° C. The catalyst preferably comprises palladium or platinum, in particular supported palladium or platinum. The nuclear-chlorinated o-xylenes can be used individually or as mixtures.
Abstract: The use of compounds of the formula (1) M(L)nXm??(1) in which M is a metal atom from the group consisting of Mn, Fe, Co, Ni, Mo and W, L is a ligand from the group consisting of the cyclic carboxamides (lactams), X is chloride, bromide, nitrate, perchlorate, citrate, hexafluorophosphate or anions of organic acids having C1–C22 carbon atoms and n is a number from 2 to 4 and m is a number from 0 to 4, as catalysts for peroxygen compounds, in particular in detergents, bleaches and cleaning agents, is claimed.
Type:
Grant
Filed:
September 30, 2004
Date of Patent:
August 22, 2006
Assignee:
Clariant GmbH
Inventors:
Ekaterina Jonas, Gerd Reinhardt, Daniel Kewitz, Aylin Karadag
Abstract: A process is disclosed for manufacturing N-methyl-N-phenylaminoacrolein of formula (I) which comprises reacting N-methylformanilide and an alkyl vinyl ether of formula (III) wherein R is a C3–C4 alkyl, said process being characterized in that the reaction between N-methylformanilide and said alkyl vinyl ether of formula (III) is carried out in the presence of phosgene, diphosgene or triphosgene in a solvent selected from dioxane, acetonitrile and/or chlorobenzene.
Type:
Grant
Filed:
May 7, 2004
Date of Patent:
August 15, 2006
Assignee:
Clariant Life Science Molecules (Italia) S.p.A.
Abstract: The following dye-transfer-inhibiting dye fixatives are used in laundry detergents which comprise nonionic surfactants: Reaction products of a) amines with epichlorohydrin or b) cyanamide with amines and aldehydes.
Type:
Grant
Filed:
February 28, 2002
Date of Patent:
August 15, 2006
Assignee:
Clariant GmbH
Inventors:
Frank-Peter Lang, Helmut Berenbold, Michael Wessling
Abstract: The invention provides water-soluble or water-swellable copolymers obtained by free-radical copolymerization of A) acryloyldimethyltaurine and/or acryloyldimethyltaurates, B) optionally, one or more other olefinically unsaturated, noncationic, optionally crosslinking comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and possessing a molecular weight of less than 500 g/mol, C) one or more mono- or polyolefinically unsaturated, optionally crosslinking macromonomers each possessing at least one oxygen, nitrogen, sulfur or phosphorus atom and having a number-average molecular weight of greater than or equal to 200 g/mol, and D) one or more olefinically unsaturated, cationic comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and possessing a molecular weight of less than 500 g/mol, the copolymerization E) taking place in the presence or absence of at least one polymeric additive having number-average molecular weights of from 200 g/mol to 109 g/mol.
Type:
Grant
Filed:
November 28, 2001
Date of Patent:
July 25, 2006
Assignee:
Clariant GmbH
Inventors:
Roman Morschhäuser, Jan Glauder, Sonja Klein, Matthias Löffler
Abstract: Cosmetic, dermatological and pharmaceutical compositions containing quaternary ammonium compounds, particularly for hair-treatment, require low setting points, good solubility and dispersibility in aqueous media and a low flash point. It has now been found that such compositions can be formulated with quaternary ammonium compounds and polyhydric alcohols. The invention provides compositions comprising a) at least one quaternary ammonium compound, b) at least one branched alcohol having 8 to 36 carbon atoms or a mixture of at least one branched alcohol and at least one unbranched alcohol having 8 to 36 carbon atoms, and c) at least one polyhydric alcohol having 2 to 6 carbon atoms. The resulting compositions have a low setting point or melting point, good solubility and dispersibility in aqueous media and a low flash point.
Type:
Grant
Filed:
May 28, 2002
Date of Patent:
July 11, 2006
Assignee:
Clariant GmbH
Inventors:
Robert Milbradt, Sonja Klein, Franz Xaver Scherl, Erich Gatter, Adelgunde Oberhauser
Abstract: A liquid softener composition suitable for treatment of clothes and/or fabrics, composed by a) anionic surfactants of the formula R—O-(AO)n—SO3? M+ in the range of 1 to 20% b) a cationic surfactant or association of cationic surfactants in the range of 1 to 40% c) optionally amphoteric and/or non-ionic surfactants in the range of 0.1 to 20%; wherein the cationic compounds and anionic surfactants are present in a weight ratio of 1.5:1 to 19:1 (cationics/anionics).
Abstract: The invention relates to compositions comprising copolymers based on acryloyldimethyltaurine and also synergistic additives selected from anionic, cationic, nonionic, and betaine surfactants. The compositions exhibit a pronounced thermoassociative behavior and are outstandingly suitable as thickeners. The copolymers of the present invention are useful in formulating cosmetics, pharmaceuticals, and oil field chemicals.
Type:
Grant
Filed:
November 28, 2001
Date of Patent:
May 30, 2006
Assignee:
Clariant GmbH
Inventors:
Roman Morschhäuser, Christoph Kayser, Matthias Löffler, Karl Heinz Heier, Aranka Tardi, Manfred Schade, Gernold Botthof
Abstract: The present invention relates to a flotation reagent and a process for the flotation of sulfidic ores. The process comprises contacting the sulfidic ores with a combination of thionocarbamates and mercaptobenzothiazoles to improve the flotation of sulfidic ores, particularly the flotation of copper ore when the copper ore is associated with molybdenum and/or gold. The flotation reagent comprises a combination of compounds of formula (1) and formula (2) where R1 and R2 independently of one another are alkyl groups having 1 to 18 carbon atoms, and R3 and R4 independently of one another are hydrogen or C1–C6-alkyl, and M is hydrogen or an alkali metal, and (1) and (2) are in a weight ratio of (1):(2) of 95:5 to 75:25.
Type:
Grant
Filed:
October 31, 2001
Date of Patent:
May 30, 2006
Assignee:
Clariant International Ltd.
Inventors:
Heinrich Hesse, Jaime Gomez, Miguel Angel Arends, Norbert Ernstorfer
Abstract: The invention relates to the use of a composition for cleaning the outside of a means of transport. The composition contains component a) at least one tertiary amino oxide of formula R1 R2 R3 NO, whereby R1 represents an alkylamidoalkyl, alkenylamidoalkyl, alkoxypropylamidoalkyl or alkenylamidoalkyl group having between 8–18 carbon atoms, R2 and R3 represent, independently from each other, low molecular alkyl radicals or hydroxyethyl radicals or hydroxypropyl radicals, and component b) at least one alkali metal salt of polyasparaginic acid having a molecular weight of between 5,000 g/mol–50,000 g/mol, or a polyglutaminic acid having a molecular weight of between 5,000 g/mol–50,000 g/mol, or a mixture of both substances, whereby the weight ratio of the components a:b is between 10:1 and 3000:1. The cleaner of the present invention effectively removes dirt and comprises environmentally friendly corrosion inhibitors.
Type:
Grant
Filed:
December 18, 2002
Date of Patent:
May 30, 2006
Assignee:
Clariant GmbH
Inventors:
Ingo Jeschke, Achim Stankowiak, Wolfgang Huber
Abstract: The present invention provides an additive for improving the cold flow properties of vegetable or animal fuel oil. The additive comprises A) a copolymer of ethylene and 8–21 mol % of at least one acrylic or vinyl ester having a C1–C18-alkyl radical and B) a comb polymer of at least one C8–C16-alkyl ester of an ethylenically unsaturated dicarboxylic acid and at least one C10–C20-olefin, wherein the sum Q Q = ? i ? w 1 ? i · n 1 ? i + ? j ? w 2 ? j · n 2 ? j ?of the molar averages of the carbon chain distributions in the alkyl side chains of the olefins (monomer 1) and the fatty alcohols (monomer 2) is from 23 to 27. In Q, w1 and w2 are the molar proportions of the individual chain lengths in the comb polymer from the different monomers 1 and 2, and n1 and n2 are the side chain carbon atom lengths, excluding comb polymer bonded carbon atoms of monomer 1, and the running variables i and j are the individual side chain lengths in the particular monomer groups.
Type:
Grant
Filed:
June 11, 2003
Date of Patent:
May 9, 2006
Assignee:
Clariant GmbH
Inventors:
Matthias Krull, Bettina Siggelkow, Martina Hess, Ulrike Neuhaus
Abstract: The invention provides a deicing or antiicing composition, containing from 35 to 93% by weight of at least one glycol and from 0.01 to 15% by weight of at least one water-soluble sheet silicate, and water ad 100% by weight, based on the weight of the deicing composition.
Abstract: The present invention relates to the use of alkoxylated polyglycerols preparable by polycondensation of glycerol and subsequent alkoxylation for demulsifying water-oil emulsions, in particular in the production of crude oil from crude oil/water emulsions. The invention provides for the use of alkoxylated polyglycerols with a molecular weight of from 250 to 100,000 units which comprise 2 to 100 glycerol units whose free OH groups are alkoxylated with C2–C4-alkylene oxide groups or a mixture of such alkylene oxide groups so that the alkoxylated polyglycerol has a degree of alkoxylation of from 1 to 100 alkylene oxide units per free OH group. The alkoxylated polyglycerols of the present invention are employed for demulsifying oil/water emulsions in amounts of from 0.0001 to 5% by weight, based on the oil content of the emulsion to be demulsified.
Type:
Grant
Filed:
February 9, 2002
Date of Patent:
April 11, 2006
Assignee:
Clariant GmbH
Inventors:
Dirk Leinweber, Franz Xaver Scherl, Elisabeth Wasmund, Heidi Grundner