Abstract: Methods and compositions for reducing the precipitation of fluoride compounds following the contact of an aluminum containing subterranean formation with an acid solution containing hydrofluoric acid are provided. In accordance with the methods, a hydroxy carboxylic acid is combined with the hydrofluoric acid solution and the subterranean formation is contacted with the resulting acid solution.

Abstract: Well drilling and servicing fluids for use in producing formations and methods of removing filter cake therefrom are provided. The methods basically comprise using a drilling or servicing fluid basically comprised of water, a water soluble salt and a particulate solid bridging agent selected from magnesium oxychloride cement, magnesium oxysulfate cement, magnesium potassium phosphate hexahydrate, magnesium hydrogen phosphate trihydrate and magnesium ammonium phosphate hexahydrate. Thereafter, the filter cake deposited by the drilling or servicing fluid is contacted with an aqueous clean-up solution for a period of time such that the bridging agent is dissolved thereby.

Abstract: A downhole apparatus and method for depositing metal at a desired area in a well casing. In one embodiment the apparatus comprises an oxygen tank filled with oxygen, a fuel tank filled with fuel, and a metal depositing device. An inert gas, such as nitrogen, may be supplied to dampen the heat generated by the metal depositing device. In an alternate embodiment, the apparatus comprises a gas tank with nitrous oxide therein and a sparking device to initiate a decomposition reaction to separate the nitrous oxide into its oxygen and nitrogen components. The metal depositing device may be adapted for flame spraying, plasma spraying or welding. A steering head is provided to reciprocate and rotate the apparatus so that the metal depositing device may be directed to the desired area in the casing. A camera and light are disposed at the bottom of the apparatus so that the interior of a well casing is illuminated and an image is transmitted to the operator for proper actuation of the steering sub.

Abstract: Subterranean formation treating fluid concentrates, treating fluids and methods are provided by the present invention. The treating fluid concentrates are basically comprised of water and a substantially fully hydrated depolymerized polymer. The treating fluids which are formed by adding water to the treating fluid concentrates are basically comprised of water, a substantially fully hydrated depolymerized polymer and a crosslinking agent for crosslinking the hydrated depolymerized polymer.

Abstract: A packer with an equalizing valve for automatically equalizing the pressure above and below the packer element. The packer comprises a housing having an equalizing valve disposed therein. A packer element is disposed about the housing for sealingly engaging the wellbore. An equalizing valve is disposed in the housing and seals the housing to prevent flow therethrough when the packer element is actuated to engage the wellbore. The valve is movable in the closed position wherein communication through the housing is prevented to an open position so that the portion of the wellbore above the packer element may be communicated with a portion of the wellbore below the packer element while the element is in the set position so that pressure above and below the element may be equalized. Once the pressure is equalized, the packer can be unset and retrieved from the wellbore.

Abstract: The present invention provides improved lightweight well cement compositions useful for performing a variety of cementing applications in subterranean formations and particularly for cementing conductor pipe in offshore wells. A preferred cement composition basically comprises a hydraulic cement, an effective amount of an iron salt selected from the group of ferric chloride, ferrous chloride or mixtures thereof to reduce the transition time of the composition, sufficient water to form a pumpable slurry, an effective amount of a foaming additive for producing a foamed slurry, and sufficient gas to foam the slurry.

Abstract: The present invention provides environmentally safe foamed fracturing fluids, additives for foaming and stabilizing foamed fracturing fluids and methods of fracturing subterranean zones. The foamed fracturing fluids of this invention are basically comprised of water, a gelling agent for forming the water into gelled water and increasing the viscosity thereof, sufficient gas to form a foam, and an effective amount of an additive for foaming and stabilizing the gelled water comprised of hydrolyzed keratin.

Abstract: An apparatus and method for wellbore and formation heating. In the method, after perforation of the well, fracturing material is pumped into the perforations to fracture the formation. This fracturing material comprises a mixture of sand and thermosetting plastic. Heat is subsequently applied to the formation and thereby to the plastic to cause the plastic to set so that flow-back of the plastic and sand is prevented while still allowing fluid flow from the formation through the sand into the well casing. The heating apparatus comprises a dual tubing string with a burner chamber attached to the lower end thereof The outer tubing of the dual tubing string is adapted for connection to an oxygen source, and the inner tubing string is adapted for connection to a fuel source. The apparatus also comprises an ignition source for providing a spark to ignite the fuel and oxygen mixture.

Abstract: Well drilling and servicing fluids for use in producing formations and methods of removing filter cake therefrom are provided. The methods basically comprise using a drilling or servicing fluid comprised of water, a density increasing water soluble salt, a fluid loss control agent, a hydratable polymer solid suspending agent and a particulate solid bridging agent which is soluble in an aqueous ammonium salt solution. Thereafter, the filter cake deposited by the drilling or servicing fluid is contacted with a clean-up solution comprised of water and an ammonium salt for a period of time such that the bridging agent is dissolved thereby.

Abstract: An acidizing composition and a method of acidizing a hydrocarbon bearing subterranean formation in the presence of ferric ions are provided. The acidizing composition includes a strong mineral acid solution, an electron donor agent, a primary electron transfer agent and a secondary electron transfer agent. The primary electron transfer agent is a source of rhenium ions. The secondary electron transfer agent is a source of iodide ion or iodine. The electron donor agent and primary and secondary electron transfer agents function together to reduce ferric ion present in the mineral acid solution to ferrous ion which in turn prevents ferric hydroxide and/or free sulfur from precipitating out of the solution and reduces the formation of sludge in crude oil in the formation. The particular electron transfer agents used in connection with the invention function with virtually all known electron donor agents.

Abstract: Improved methods of treating water and hydrocarbons producing subterranean formations to reduce the water permeabilities of the formations without substantially reducing the hydrocarbons permeabilities thereof are provided. The methods basically comprise introducing into the formation a chemical which does not resist water flow and attaches to adsorption sites on surfaces within the porosity of the formation but slowly washes off the sites as another fluid flows through the treated formation. Thereafter, a water flow resisting polymer is introduced into the formation so that it flows deeply into the porosity of the formation before the previously introduced chemical washes off and attaches to the adsorption sites as the chemical washes off.

Abstract: The present invention relates to a method of breaking an aqueous fracturing fluid comprising introducing said aqueous fracturing fluid into contact with an encapsulated viscosity reducing agent said encapsulated viscosity reducing agent comprising an aqueous fluid soluble breaker for said fracturing fluid encapsulated within a membrane comprising a partially hydrolyzed acrylic crosslinked with either an aziridine prepolymer or a carbodiimide, said membrane having an embrittlement effective amount of a micron sized particulate present therein and said membrane having been cured at a temperature of at least about 115° F., such that an aqueous fluid in said fracturing fluid can contact said breaker after fracture failure of said membrane to dissolve at least a portion of said breaker and break the fracturing fluid in contact therewith.

Abstract: A slow rotating apparatus for use in performing downhole operations. The apparatus generally consists of a motor section with a rotor rotatable in response to fluid flow, a speed reducer section connected to the motor section such that an output speed of the speed reducer section is less than an output speed of the rotor, and a jetting section or other head attached to the speed reducer section and rotated thereby at the speed reducer output speed. A flow passage is defined through the speed reducer section so that fluid may communicate therefrom into the jetting head. The speed reducer section includes an input shaft attached to the rotor. The input shaft has an eccentric portion and has an input gear disposed about the eccentric portion. The input gear is a solid gear having a first outer geared surface and a second outer geared surface. The pitch diameter of the first outer geared surface is less than the pitch diameter of the second outer geared surface.

Abstract: A packer apparatus for sealing between a tubing string and a casing in a wellbore is disclosed. The packer apparatus includes a seal assembly disposed about a packer mandrel. Upper and lower seal wedges are disposed about the packer mandrel above and below the seal assembly and may be inserted between the seal assembly and the packer mandrel to radially expand the seal assembly into engagement with the casing. The seal assembly includes an expandable elastomeric seal element having anti-extrusion bridge elements disposed in recesses at the upper and lower ends thereof. The anti-extrusion elements form an almost complete circle and thus are arcuately shaped having first and second ends with a gap therebetween.

Abstract: Methods and acidizing compositions for reducing the corrosion of the metal surfaces of tubular goods and the like and reducing the precipitation of metal sulfide from the acidizing compositions are provided. The methods basically comprise the steps of combining an aldol-amine adduct with an aqueous acid solution to preferentially react with sulfide ions subsequently dissolved by the aqueous acid solution and thereby prevent subsequently dissolved metal ions from reacting therewith and precipitating, and then introducing the aqueous acid solution containing the aldol-amine adduct into a well or other location to be acidized.

Abstract: Improved hardenable resin compositions and methods of consolidating particulate solids in subterranean zones penetrated by well bores are provided. The improved hardenable resin compositions of the invention are basically comprised of a hardenable organic resin, an aminosilane resin-to-particulate solid coupling agent, a viscous carrier fluid breaker for breaking separating films of viscous carrier fluid between resin coated particulate solids and a surface active agent for causing the resin composition to flow to the contact points between resin coated particulate solids.

Abstract: The present invention provides improved cross-linked well treating fluids and methods for preparing and using the fluids in treating wells such as fracturing subterranean zones therein. The improved cross-linked treating fluids comprise water, a galactomannan gelling agent, a cross-linking agent for cross-linking the galactomannan gelling agent, and a viscosity stabilizing agent selected from the group consisting of formaldehyde, formic acid, or mixtures thereof. The viscosity stabilizing agent alters the properties of the well treating fluids and enables them to retain their viscosity over prolonged periods of time when compared to prior well treating fluids.

Abstract: A wireless coiled tubing joint locator for locating joints or collars in a production tubing string. An electromagnetic coil assembly or giant magnetoresistive digital field sensor senses the increased mass of a pipe joint, and provides a signal to an electric circuit which generates a signal received by a pilot solenoid valve. The solenoid valve momentarily opens a pilot passageway which activates a piston to close a circulation port in the joint locator, resulting in an increase in a surface pressure reading observable by the operator. In one embodiment, a rupture disk is provided so that pressure cannot be applied to any downhole tool below the joint locator prematurely. A seat sleeve prevents premature communication of fluid to the rupture disk but can be opened by dropping a ball into the joint locator. A second embodiment may be used for either logging or washing operations or both. The electronic circuit can provide a selected one of a plurality of time delays.

Abstract: Improved methods of completing subterranean producing zones containing unconsolidated sands penetrated by well bores are provided. The methods are basically comprised of placing a sand screen in the zone, isolating the annulus between the sand screen and the well bore in the zone, introducing particulate solids and foam forming pellets or open cell foam pieces with or without particulate solids and foam forming pellets into the annulus between the sand screen and the well bore to thereby form a formation sand screening permeable pack in the annulus. When utilized, the foam forming pellets are activated by heat or other means to form a foam which expands and solidifies in the pack thereby eliminating voids and strengthening the pack.

Abstract: A method and apparatus using hydrajetting of fluid to cut a lateral casing window for drilling a side track. The apparatus comprises a J-sub having a J-slot therein which guides movement of a jetting nozzle such that a window may be abrasively jetted in well casing in the general shape of the J-slot. In an alternate embodiment, a hydraulically activated actuator sub is used to operate the J-sub. The actuator sub is activated by alternately pressurizing and depressurizing the actuator sub to apply longitudinal movement and torque to the J-sub.