Abstract: A process for oligomerizing isobutene includes contacting a feedstock including isobutene with a catalyst comprising an EMM-10 molecular sieve under conditions effective to oligomerize said isobutene and produce an effluent containing less isobutene than the feedstock.
Type:
Grant
Filed:
October 26, 2007
Date of Patent:
August 31, 2010
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Jane C. Cheng, Ivy D. Johnson, Wieslaw J. Roth, Michael C. Kerby
Abstract: Reactor designs and processes for operating such reactor designs to minimize or eliminate fouling in homogeneous polymerization processes (solution and supercritical). The process includes providing a reactor with one or more feed entry ports, wherein the reactor feed components are fed through each of the one or more feed entry ports at a linear velocity of greater than or equal to 0.3 m/min. The one or more feed entry ports may also be optionally extended beyond the interior reactor wall by greater than or equal to 2% of the internal radius of the reactor to further decrease the propensity for fouling. A stirred reactor may also include a stirrer feed port for purging the stirrer with a stirrer purge stream at a linear velocity of greater than or equal to 0.3 m/min to decrease stirrer fouling.
Type:
Grant
Filed:
June 13, 2008
Date of Patent:
June 29, 2010
Assignee:
Exxonmobil Research and Engineering Company
Inventors:
Gabor Kiss, Robert P. Reynolds, Jr., Charles K. Morgan, John W. Chu, Megan Meier