Abstract: An improved thermal swing adsorption process is set forth which addresses the problem of water ingress into the adsorbent by periodically heating the adsorbent to a temperature greater than the temperature used in the normal regeneration cycle.

Abstract: A method for process plant design which comprises (a) preparing a detailed design for a process plant in a product line including a detailed design of at least one engineered component and (b) preparing a detailed design for another process plant in a different product line wherein the detailed design of the at least one engineered component of (a) is reused in (b).

Abstract: A process for cleaning a glass-coating reactor includes: (a) providing the reactor to be cleaned, wherein the reactor contains a glass substrate within a chamber and the chamber has an internal surface coated with at least one substance selected from the group consisting of Si3N4 or SiO2; (b) terminating a flow of a deposition gas to the reactor; (c) adding to the reactor at least one cleaning gas to react with the at least one substance to form at least one volatile product; and (d) removing from the reactor the at least one volatile product.

Abstract: A method for recovering krypton and xenon from air comprises (a) separating an air feed stream into oxygen-enriched and nitrogen-enriched product streams; (b) reacting the oxygen-rich product stream with a hydrocarbon feed in a synthesis gas generation process to yield a synthesis gas stream comprising hydrogen, carbon oxides, krypton, and xenon, which synthesis gas stream contains essentially no oxygen; (c) introducing the synthesis gas stream into a synthesis gas conversion process and converting the synthesis gas stream into a liquid synthesis product stream and an unreacted synthesis gas stream; (d) recycling at least a portion of the unreacted synthesis gas stream to the synthesis gas generation process; (e) reducing the pressure of the liquid synthesis product stream to yield a two-phase reduced-pressure product stream, and separating the two-phase reduced-pressure product stream into a final liquid synthesis product stream and a gas stream enriched in krypton and xenon; and (f) separating the gas strea

Abstract: A tunnel freezer having a metal belt for carrying product therethrough, wherein the weight of said belt is from 1 kg per square meter of surface area to 6 kg per square meter of surface area.

Abstract: A process is set forth for cold rolling of a metal strip, wherein the metal strip passes through a nip between two counter-rotating rolls, driven in counter-rotation substantially at room temperature, wherein a cold and/or liquefied gas, preferably an inert gas, is blown into the area of the nip or roll gap. A roll stand according to the present invention comprises two counter-rotating rolls forming a nip or rolling gap and nozzle means for blowing a cold and/or liquefied gas, preferably an inert gas, through at least one orifice of said nozzle means into the area of the roll nip. Preferably, the temperature of the cold and/or liquefied gas is appreciably lower than room temperature.

Abstract: A control scheme is set forth for conversion of variable composition synthesis gas to liquid fuels in a three-phase or slurry bubble column reactor (SBCR). The control scheme allows one to achieve constant or optimum liquid fuel production and constant or limited purge gas flow with highly variable synthesis gas feed condition. This is accomplished by adjusting one or more of the following independent variables: recycle ratio, water addition, and bypass flow.

Abstract: A process is set forth for producing DME by dehydrating the effluent stream from a methanol reactor where the methanol reactor is a slurry bubble column reactor (SBCR) containing a methanol synthesis catalyst that converts a synthesis gas stream comprising hydrogen and carbon monoxide into an effluent stream comprising methanol. A key to the process is that the SBCR methanol can produce a relatively low water content methanol stream, thereby avoiding an intervening water removal unit between the SBCR methanol unit and the dehydration unit and/or an incremental increase in the water that must be processed by the dehydration unit.

Abstract: A cryogenic fluid distributor for turret machine tools (e.g., lathes) directs a stream of cryogenic fluid from an external, pressurized cryogen source to a working position of a machine tool to prevent overheating of the tool. Designed for easy retrofitting and synchronizing with multi-tool turret machines, the distributor allows for a “dual-fluid” machining capability combining a cryogenic fluid and a conventional cutting fluid (flowing via a conventional coolant system built into a given machine tool). Made of low thermal-mass, insulating polymer and metallic parts, the distributor utilizes the different thermal contraction coefficients of the parts to establish cryogenic sealing connections, which eliminates undesired turret plate cooling and assures rapid cryogen flow start-up.

Abstract: Method and apparatus for continuation of combustion with an oxy-fuel combustion system when the supply of oxygen is temporally reduced or stopped. Air or oxygen enriched air and fuel are introduced into the device being heated in place of the oxy-fuel mixture to effect combustion and maintain the heating level in the furnace. Water cooling of the furnace gases is used to reduce the volume of exhaust gases when operating in the air or oxygen enriched air mode.

Abstract: A process and furnace for melting glass is set forth wherein the majority of the combustion energy over the melting zone of the furnace is provided by oxy-fuel combustion while a majority of the combustion energy over the fining zone of the furnace is provided by air-fuel combustion. In many cases, it will be preferable to provide greater than 70% and up to and including 100% of the combustion energy over the melting zone by oxy-fuel combustion and greater than 70% and up to and including 100% of the combustion energy over the fining zone by air-fuel combustion. By proper tailoring of the combustion space atmosphere through oxy-fuel and air-fuel firing, the present invention can result in an improvement in glass productivity and quality. The present invention can be applied in the construction of a new furnace or can be applied to existing air-fuel furnaces.

Abstract: A method and apparatus are set forth for transferring a cryogenic fluid. A polymeric, coaxial (i.e. “tube-in-tube” geometry) transfer line is utilized where a first portion of the cryogenic fluid flows through the inner tube while a second portion flows through an annulus between the inner tube and outer tube which annulus is at a lower pressure than the inside tube. In one embodiment, the inner tube is substantially non-porous and the transfer line is preceded by a flow control means to distribute at least part of the first and second portions of the cryogenic fluid to the inner tube and annulus respectively. In a second embodiment, the inner tube is porous with respect to both gas permeation and liquid permeation such that both a gaseous part and a liquid part of the first portion permeates into the annulus to form at least a part of the second portion.

Abstract: Volatile compounds (“VCs”), especially volatile organic compounds (“VOCs”), are cryogenically removed from a process gas stream (pW) by cooling the gas stream in a condenser to condense the VC to form both liquid VC and VC ice and providing a treated process gas essentially freed of the VC but containing entrained VC ice particles, which are subsequently removed by passing the treated process gas through a filter downstream of the condenser to remove at least particles of a size greater than 50 &mgr;m. The condensation can be conducted in an indirect heat exchanger or by direct contact of the process gas with a liquid cryogen such as liquid nitrogen. It is preferred that the filter removes VC ice particles greater than 1 &mgr;m.

Abstract: An improvement to the process for separating dimethyl ether (DME) from byproducts in a one-step catalytic conversion of synthesis gas (syngas), the improvement comprising using a scrubbing solvent comprising a mixture of dimethyl ether and methanol for the separation of dimethyl ether and carbon dioxide from the unconverted synthesis gas in a scrubbing column. Additional improvements include recycling of the scrubbing solution, multi-step processing of the liquid effluent from the scrubber, and methods of processing the methanol-water effluent of the flash column that is interposed between the DME reactor and the scrubber.

Abstract: A method of freezing a product, which method comprises the steps of vaporizing a cryogenic liquid and warming the vapor thus formed in indirect heat exchange with a product to be frozen, work expanding the warmed vapor, and using the work expanded vapor thus obtained to refrigerate the or another product.

Abstract: A process for methylating an alpha carbon adjacent to an electron withdrawing group includes reacting dimethyl ether with a molecule containing the alpha carbon and the electron withdrawing group to substitute a methyl group on the alpha carbon. The process can be conducted in a vapor phase and can be represented by Equation I: R(CH2)nCH2-EWG+CH3OCH3→R(CH2)nCH(CH3)-EWG+CH3OH  (I) where EWG is the electron withdrawing group, and R is H when n is 0, 1 or 2, and R is alkyl, EWG or aryl when n>2. For example, the molecule reacted with dimethyl ether can be acetic acid, propionic acid, methyl acetate, methyl propionate, acetonitrile, propionitrile and acetone. The process is catalyzed by an acid catalyst containing a Lewis acid functionality. When the electron withdrawing group is an acid, a methyl ester can be formed by esterifying the electron withdrawing group with methanol liberated from dimethyl ether.

Abstract: Oxygen-enhanced combustion in a manufacturing plant using a nitrogen plant to obtain a nitrogen product stream for use in the plant is effected by utilizing the oxygen-rich vent, waste, or exhaust stream as the primary source of oxidant for combustion of fuel in burners used to heat furnaces and the like in the same plant. Processes according to the invention employ a vent stream in place of a high purity oxygen stream for oxy-fuel combustion, oxygen lancing, and oxygen boosting.

Abstract: A method of cooling an aqueous liquid, which method comprises the steps of:a) placing said aqueous liquid in a vessel;b) reducing the pressure in said vessel to cause said aqueous liquid to boil;c) condensing at least some of the liquid in the vapour created as said aqueous liquid boils by heat exchange with a liquid cryogen; andd) using vapour from said liquid cryogen to at least assist in step (b).

Abstract: A technique is set forth to reduce the heat requirement of conventional distillation processes which separate feed mixtures containing three or more components. The technique provides a great deal of flexibility in adjusting the temperatures of the required utilities including a scenario where the heat requirement is reduced without a need for additional higher temperature (and more costly) heat utility. In this technique, when a liquid bottoms stream (or gaseous overhead stream) containing two or more components is sent from an earlier column to a subsequent column, then a return vapor (or liquid) stream is implemented between the same locations in the two columns.

Abstract: The present invention concerns a cryogenic air separation process which intermittently diverts a portion of the air feed as repressurization gas for a front-end two bed pressure swing adsorption adsorption system which system is used to remove impurities from the air feed. In particular, the present invention is an improvement to said process for at least partially eliminating reductions in the purity of the product streams from the air separation unit caused by the intermittent diversions of the air feed as repressurization gas. The improvement comprises reducing the flow of both the nitrogen-enriched waste stream and the crude liquid oxygen stream from the air separation unit during those intermittent periods when repressurization gas is required in the pressure swing adsorption system.