Abstract: N,N'-Bis(4,4,4-trinitrobutyryl)hydrazine which is prepared by reacting 4,-trinitrobutyryl chloride with hydrazine in methanol at low temperature. This compound is sensitive enough to be used as an initiating explosive and thermally stable enough to be used in missile warheads.

Abstract: A process for bonding two diamond surfaces together by(1) forming a layer of opaque nondiamond carbon material between the two mond surfaces;(2) pressing the diamond surfaces together with the opaque nondiamond material sandwiched between the diamond surfaces;(3) used pulse lased light to quickly melt all the opaque nondiamond carbon material before a significant amount of heat is lost through the diamond surface; and then(4) allowing the resulting carbon melt to cool and solidify as polycrystalline diamond which grows homoepitaxially from the diamond surfaces, bonding those surfaces together.

Abstract: Ternary metallic alloys of the formula Li.sub.x B.sub.y Mg.sub.z wherein 5.ltoreq.x.ltoreq.0.90, 0.05.ltoreq.y.ltoreq.0.90, 0.05.ltoreq.z.ltoreq.0.90, and x+y+z=1 and a method of preparing them. These alloys find use in areas where superlight weight, high specific strength (strength/weight ratio) and oxidation resistance are required.

Abstract: A method of preparing dichloroformals of the formula(RCH.sub.2 O).sub.2 CCl.sub.2by reaction of one mole of a thionocarbonate of the formula(RCH.sub.2 O).sub.2 C.dbd.Swith two moles of benzenesulfenyl chloride, chlorobenzenesulfenyl chloride, r methanesulfenyl chloride wherein R is --C(NO.sub.2).sub.3, --CF(NO.sub.2).sub.2, --CF.sub.2 (NO.sub.2), --CCl(NO.sub.2).sub.2, --C(NO.sub.2).sub.2 CH.sub.3, --CCl.sub.3, --CF.sub.3, or --CF.sub.2 CF.sub.3. These energetic dichloroformals are useful as explosive and propellant ingredients and as intermediates in the synthesis of other energetic explosive and propellant ingredients.

Abstract: A non-magnetic, wear resistant composite of from 10 to 45 volume percent of titanium carbide or tungsten carbide particles bonded in a matrix of a nickel-titanium alloy wherein nickel comprises from 53 to 62 weight percent of the alloy with the remainder being essentially titanium.

Abstract: A high power pulse of electrical current causes a metal conductor to expl and initiate a reaction between an aluminum or aluminum alloy powder and water which generates hydrogen gas at a high temperature and pressure. The reaction mixture is released into a second larger chamber equipped with heat exchanger which extracts useful heat energy and cools down the reaction mixture. The hydrogen gas is then separated from the solid metal oxide byproducts in the cooled reaction mixture.

Abstract: A reaction vessel comprising (1) a porous ceramic structure having intercecting, open pores and (2) silver metal coating the inner ceramic surfaces of the reaction vessel and filling the interconnecting, open pores to form a strong bond between the porous ceramic structure and the silver coating.The reaction vessel can be produced by(1) coating the inner surface and infiltrating the continuous, open pores of an unglazed porous ceramic structure (or vessel) with molten AgNO.sub.3 ;(2) decomposing the AgNO.sub.3 to silver metal; and then(3) repeating steps (1) and (2) until all the pores are filled with silver metal.

Abstract: An energetic composite made of a mixture of(1) a solid nitrate ester of a cyclodextrin or a mixture of cyclodextrins; nd(2) an energetic organic nitrate ester plasticizer.

Abstract: A method of bonding two carbon/carbon composite pieces or a carbon/carbon mposite piece and a graphite/aluminum metal matrix composite piece together by(1) forming a uniform coating of molten AgNO.sub.3 on the surfaces to be bonded at a temperature above the melting point of AgNO.sub.3 but below the decomposition temperature of AgNO.sub.3 ;(2) placing the molten AgNO.sub.3 coated surfaces to be bonded into contact with each other;(3) decomposing the molten AgNO.sub.3 to form a silver metal layer bonding the pieces together.If a graphite/aluminum metal matrix composite piece is being bonded, a silver diffusion step may be added at the end of the process to strengthen the silver bond to the metal cladding or metal matrix of the metal matrix composite piece.

Abstract: A process for silver coating superconducting ceramic powder by(1) mixing AgNO.sub.3 with the superconducting ceramic powder particles;(2) melting the AgNO.sub.3 so that it wets and forms a uniform coating over he surfaces of the particles; and(3) decomposing the AgNO.sub.3 to form a thin, uniform coating of silver metal on the surfaces of the particles.The product is a loose powder of superconducting ceramic particles which are uniformly coated with silver metal. The powder can be cold worked (e.g., swaged, forged, etc.) to form superconducting structures such as rods or wires.

Abstract: A silver coated superconducting ceramic powder made by(1) coating the superconducting ceramic powder particles with AgNO.sub.3 ;(2) melting the AgNO.sub.3 so that it wets and forms a uniform coating over the surfaces of the particles; and(3) decomposing the AgNO.sub.3 to form a thin, uniform coating of silver metal on the surfaces of the particles.The product is a loose powder of superconducting ceramic particels which are uniformly coated with a thin layer of silver metal. The powder can be cold worked (e.g., swaged, forged, etc.) to form superconducting structures such as rods or wires.

Abstract: A process for producing a diamond composite comprising diamond powder parles bonded together by polycrystalline diamond by (1) pressing an intimate mixture of fine opaque nondiamond carbon powder and transparent diamond powder to form a green body that is confined in either a thin walled transparent quartz vessel or a polycrystalline diamond coating; (2) using a pulse laser to quickly melt the opaque nondiamond carbon powder, and (3) allowing the carbon melt to cool and grow homoepitaxially from the surfaces of the diamond particles producing a polycrystalline diamond that bonds the diamond particles together.

Abstract: A nitrate ester which is 2,4,6-trinitro-1-(2-hydroxyethylamino)-3- (2-hydyethylnitramino)benzenedinitrate; 2,4,6-trinitro-1,3,5-tris(2-hydroxyethylamino)benzenetrinitrate; 2,2',4,4',6,6'-hexanitro-3-(2-hydroxyethylnitramino)stilbenitrate; 2,5-bis[3-(hydroxyethylaminonitrate)-2,4,6-trinitrophenyl]1,3,4-oxadiazole ; or 2,5-bis[3-(hydroxyethylaminonitrate)-5- (hydroxyethylnitraminonitrate)-2,4,6-trinitrophenyl]-1,3,4-oxiazole and a process for preparing these compounds.

Abstract: A method of propelling a projectile from a device by applying a high power pulse of electrical current to a thin metal conductor wire causing the wire to explode and disperse hot spots of molten metal throughout an aluminum fuel powder/water mixture which reacts to generate hydrogen gas at high pressure in a chamber. The hydrogen gas is used to push the projectile from the device.

Abstract: A process for producing high temperature, oxidation resistant silver metal oatings on carbon/carbon composite structures by coating the carbon/carbon surfaces with molten AgNO.sub.3 at a temperature above the melting point of AgNO.sub.3 but below the decomposition temperature of AgNO.sub.3, and then heating the resulting uniform coating of molten AgNO.sub.3 at a temperature of from the decomposition temperature of AgNO.sub.3 to about 700.degree. C. to decompose the molten AgNO.sub.3 and form a uniform coating of silver metal.

Abstract: A method for producing lightweight silver-nickel composite electrodes by(1) infiltrating a graphite fiber plaque with a suspension of finely divi nickel powder in an aqueous solution of AgNO.sub.3 ;(2) drying the graphite fiber plaque to produce a coating of AgNO.sub.3 crystals and nickel particles on the surfaces of the graphite fibers;(3) heating the coated graphite fiber plaque at a temperature about the melting point of AgNO.sub.3 but below the decomposition temperature of AgNO.sub.3 until the AgNO.sub.3 melts and wets the nickel particles and the surfaces of the graphite fibers; and(4) heating the molten AgNO.sub.3 coated graphite fiber plaque at a temperature from the decomposition temperature of AgNO.sub.3 to about 600.degree. C. until the AgNO.sub.3 decomposes to form a thin uniform silver metal coating over the nickel particles and the surfaces of the graphite fibers.The silver-nickel particle coated graphite plaques is electrochemically treated to convert the silver to silver active material (Ag.

Abstract: A process for preparing monoclinic celsian from AlF.sub.3, Al.sub.2 O.sub.3, BaCO.sub.3, and fused SiO.sub.2 powders by heating an intimate mixture of the powders (1) at from about 700.degree. to 900.degree. C. to form topaz and then (2) at a temperature as low as 900.degree. C. to produce monoclinic celsian. The reactions take place in an atmosphere of the gases generated by the reactions.

Abstract: 5-carboxy-1,3-diamino-2,4,6-trinitrobenzene (DATBA), ##STR1## which is prepared by reacting 5-fluoro-1,3-diamino-2,4,6-trinitrobenzene with cyanotrimethylsilane to form 5-cyano-1,3-diamino-2,4,6-trinitrobenzene which is then hydrolyzed with a strong acid to form the DATBA.

Abstract: The production of 3-nitro-1,2,4-triazol-5-one (NTO) having finely divided rticles of uniform size by dissolving conventionally produced large, jagged, rods of NTO in hot dimethylsulfoxide and then injecting the hot solution through a small orifice into methylene chloride at a temperature of from about -10.degree. C. to about 30.degree. C.

Abstract: A composite armor shield comprising alternating layers of steel and a polymeric material which is either a polymethyl methacrylate of the general formula ##STR1## or a polycarbonate of the general formula ##STR2##