Patents Represented by Attorney, Agent or Law Firm Rosemary M. Miano
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Patent number: 6511658Abstract: A high efficacy antiperspirant/deodorant stick product may be made by combining (a) 30-70% volatile cyclomethicone; (b) 10-25% of an antiperspirant active; (c) 1-15% of an emollient; (d) 1-14% of polyethylene comprising one or more members selected from the group consisting of homopolymers and copolymers of polyethylene wherein the polyethylene (i) is at least 90% linear; (ii) has a molecular weight in the range of 300-3000 (especially 300-1000 and more especially 300-500); (iii) has a melting point in the range of 50-129 degrees C.; and (iv) has a polymer backbone of CH3CH2—(CH2—CH2)n—H, where n is an average number and is selected to be in the range of 10-106; (e) 0.3-7% of a wax as a co-gellant with the polyethylene wherein the wax has a melting point in the range of 40-97 degrees C.Type: GrantFiled: November 9, 2001Date of Patent: January 28, 2003Assignee: Colgate-Palmolive CompanyInventors: Jairajh Mattai, Eric Guenin, Wilson Lee, Patricia Hall-Puzio, Anne Gale
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Patent number: 6503491Abstract: A high efficacy antiperspirant/deodorant stick product may be made by combining (a) 30-70% volatile cyclomethicone; (b) 10-25% of an antiperspirant active; (c) 1-15% of an emollient; (d) 1-14% of polyethylene comprising one or more members selected from the group consisting of homopolymers and copolymers of polyethylene wherein the polyethylene (i) is at least 90% linear; (ii) has a molecular weight in the range of 300-3000 (especially 300-1000 and more especially 300-500); (iii) has a melting point in the range of 50-129 degrees C; and (iv) has a polymer backbone of CH3CH2—(CH2—CH2)n—H, where n is an average number and is selected to be in the range of 10-106; (e) 0.3-7% of a wax as a co-gellant with the polyethylene wherein the wax has a melting point in the range of 40-97 degrees C.; provided that the ratio of wax:polyethylene is in the range of 1:1-1:10.Type: GrantFiled: November 9, 2001Date of Patent: January 7, 2003Assignee: Colgate-Palmolive CompanyInventors: Eric Guenin, Jairajh Mattai, Anne Gale, Patricia Hall-Puzio, Wilson Lee
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Patent number: 6500412Abstract: A non-sticky, clear water-in-oil emulsion comprising: (a) 65-90 weight % of an internal phase comprising 5-35 weight % of an antiperspirant salt (anhydrous basis) having a metal:chloride ratio in the range of 0.9-1.4:1; 5-15 weight % of tripropylene glycol; and 35-70 weight % water; and (b) 10-35 weight % of an external phase comprising 1-40 weight % of a volatile silicone which is not an elastomer; 0.1-5 weight % of a silicone copolyol surfactant; and 0-20 weight % of a nonvolatile silicone which is not an elastomer; wherein the composition is free of (1) C1-5 saturated alcohols, (2) added propylene glycol, (3) elastomer gelling agents, (4) soap gelling agents (5) borate gelling agents, and (6) coupling agents, and wherein all amounts are in % by weight based on the total weight of the composition.Type: GrantFiled: April 8, 2002Date of Patent: December 31, 2002Assignee: Colgate-Palmolive CompanyInventors: Marie Johansson, John Brahms
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Patent number: 6485716Abstract: The invention is a clear, elastomer-free, gel composition comprising: (a) 0.1-25 weight % of an antiperspirant active having a low metal to chloride ratio in the range of 0.9-1.3: 1; (b) 9-23.95 weight % of one or more volatile silicones having a flash point of 100 degrees C or less; (c) 0.05-0.5 weight % of a silicone surfactant having an HLB value≦8; (d) 30-70 weight % water; (e) 0-50 weight % selected water soluble organic solvents; and (f) 0-10 weight % of an emollient; wherein the composition is a liquid gel having a viscosity in the range of 5-50,000 centipoise and a ratio of oil phase to water phase in the range of 10:90 to 24:76.Type: GrantFiled: October 5, 2001Date of Patent: November 26, 2002Assignee: Colgate-Palmolive CompanyInventors: Lin Fei, Suman Chopra, Eric Guenin, Peter Hilliard, Jr., Jairajh Mattai, Neeta Patel
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Patent number: 6468511Abstract: This invention relates to an anhydrous cosmetic composition comprising: (a) 15-33% of an external phase (also called the oil phase) which is made with at least one selected naphthalate organic ester; a volatile silicone based emulsifier; and a volatile silicone; and (b) 85-67% of an internal phase which is made with an active ingredient, such as an antiperspirant active, in a glycol solvent. For the external phase all or a major portion of what would have been a non-volatile silicone component has been replaced by the naphthalate ester. While a dimethicone copolyol is still included, the use of this particular naphthalate ester obviates the need for the use of any other non-ionic emulsifiers.Type: GrantFiled: May 19, 2000Date of Patent: October 22, 2002Assignee: Colgate-Palmolive CompanyInventors: Suman Kumar Chopra, Bhal Moghe
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Patent number: 6451295Abstract: Clear antiperspirant and/or deodorant compositions, especially clear sticks having good structural integrity, can be formed by incorporating at least 8% by weight based on the total weight of the composition of a selected siliconized polyamide into a product formulated with at least one silicone material and at least one non-silicone emollient. The siliconized polyamides have the silicone portion in the acid side of the polyamide and are selected so that: (a) the degree of polymerization in the silicone portion is in the range of 12-18; (b) the average molecular weight of the siliconized polyamide is at least 50,000 daltons with at least 95% of the polyamide having a molecular weight greater than 10,000 as measured by size exclusion chromatography; and (c) the polydispersity is less than 20.Type: GrantFiled: August 3, 2001Date of Patent: September 17, 2002Assignees: Colgate-Palmolive Company, Dow-Corning CorporationInventors: Heng Cai, Adriana Urrutia-Gutierrez, Aixing Fan
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Patent number: 6436382Abstract: A suspension cosmetic product for reducing wetness under the arm which product is a stick or a soft solid comprising: (a) 0.01-20 weight % of a water lock superabsorbent polymer selected from the group consisting of starch graft homopolymers and copolymers of poly(2-propenamide-co-2-propenioic acid) sodium salt; (b) 10-88 weight % of a volatile silicone; (c) a selected gelling agent; (d) 0-5 weight % of a surfactant with a hydrophilic/lipophilic balance in the range of 3-13; (e) 0-10 weight % of an antiperspirant active or an effective amount of a deodorizing agent which is not an antiperspirant active; (f) 0-20 weight % of a nonvolatile silicone; and (g) 0-20 weight % of an emollient; wherein the product is not made with any separately added water.Type: GrantFiled: October 5, 2001Date of Patent: August 20, 2002Assignee: Colgate-Palmolive CompanyInventors: Suman Chopra, Lin Fei, Eric Guenin, Jairajh Mattai
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Patent number: 6426062Abstract: A gelled stick or soft gel composition for reducing underarm wetness comprising: (a) 0.01-20 weight % selected from the group consisting of starch graft homopolymers and copolymers of poly(2-propenamide-co-2-propenioic acid) sodium salt; (b) 10-88 weight % of a volatile silicone; (c) a gelling agent selected from (i) a group consisting of 5-20 weight % siliconized polyamide if a gelled stick is formed; and (ii) 0-5 weight % of a siliconized polyamide and 0-5% of a silicone elastomer if a soft gel is formed; (d) 0.05-85 weight % of water or a water soluble organic solvent; (e) for products which are not sticks, 0.05-5 weight % of a surfactant with a HLB value in the range of 3-13; (f) 0-10 weight % of an antiperspirant active or an effective amount of a deodorizing agent which is not an antiperspirant active; (g) 0-20 weight % of a nonvolatile silicone; and (h) 0-20 weight % of an emollient.Type: GrantFiled: October 5, 2001Date of Patent: July 30, 2002Assignee: Colgate-Palmolive CompanyInventors: Suman Chopra, Jairajh Mattai, Lin Fei, Eric Guenin
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Patent number: 6403067Abstract: Low water emulsions are described which are useful for antiperspirants and/or deodorants wherein the emulsions are made by combining (I) 15-33% of an external phase comprising: (a) 1-25% of an organic ester having a refractive index in the range of 1.43-1.60 and capable of releasing an antiperspirant active to achieve a specified conductivity; (b) a sufficient amount of a silicone copolyol to achieve a solids content of 0.25-10%; (c) a sufficient amount of a volatile silicone to achieve a total amount of the external phase as 15-33%; (c) 0-5% of a silicone elastomer (on an actives basis); and (d) 0-15% of at least one emollient; and (II) 67-85% of an internal phase comprising: (a) an effective amount of at least one cosmetically active ingredient; (b) a sufficient amount of a solvent component to dissolve the cosmetically active ingredient with a maximum amount being about 80%; (c) 0.Type: GrantFiled: May 19, 2000Date of Patent: June 11, 2002Assignee: Colgate-Palmolive CompanyInventors: Thomas Schamper, Suman Kumar Chopra, Bhal Moghe, John Carl-Frederick Brahms, Mardoqueo Bustos, Peter Hilliard, Jr., Marie Johansson, Claudo Ortiz, Christine Popoff
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Patent number: 6403069Abstract: A clear antiperspirant and/or deodorant composition is disclosed in the form of an emulsion having a refractive index less than 1.42 and comprising: (a) 25-70% of an external phase comprising: (i) 0.1-10%, on an actives basis, of at least one elastomer which is a dimethicone/vinyldimethicone crosspolymer composition made by reacting a polymethylhydrogensiloxane with an alpha, omega-divinylpolydimethyl siloxane for which the dimethicone/vinyl-dimethicone crosspolymer composition is used at a concentration of 4-10% in cyclomethicone, has a refractive index in the range of 1.392-1.402 at 25 degrees C and a viscosity in the range of 0.013-1×104 Pascal seconds; (ii) 0.1-5% of a silicone copolyol having an HLB value ≦8; (iii) 0.Type: GrantFiled: October 20, 2000Date of Patent: June 11, 2002Assignee: Colgate-Palmolive CompanyInventors: Suman Chopra, Jairajh Mattai, Lin Fei, Eric Guenin, Xiaozhong Tang
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Patent number: 6387357Abstract: A clear antiperspirant and/or deodorant composition is disclosed in the form of an emulsion having a refractive index less than 1.42 and comprising: (a) 25-70% of an external phase comprising: (i) 0.1-10%, on an actives basis, of at least one elastomer which is a cyclomethicone (and) dimethicone crosspolymer made with an ≡Si—H containing polysiloxane and an alpha, omega-diene of formula CH2═CH(CH2)xCH═CH2, where x=1-20, to form a gel by crosslinking and addition of ≡Si—H across double bonds in the alpha, omega diene, which crosspolymer has a viscosity in the range of 50,000-3,000,000 centipoise; (ii) 0.1-5% of a silicone copolyol having an HLB value ≦8; (iii) 0.Type: GrantFiled: October 20, 2000Date of Patent: May 14, 2002Assignee: Colgate-Palmolive CompanyInventors: Suman Chopra, Jairajh Mattai, Lin Fei, Eric Guenin, Xiaozhong Tang, Claudio Ortiz
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Patent number: 6387356Abstract: Personal care products are disclosed which comprises an alcohol based composition which includes a film forming system comprising cellulose esters, which product (1) is capable of forming a thin film on the skin which film is characterized by selected hardness, and water transport properties and (2) reduces or eliminates wetness such as wetness caused by perspiration. These compositions can be used in cosmetic products, especially antiperspirants, deodorants, and combination antiperspirant/deodorants. The compositions comprise: (a) an alcohol based solvent system; and (b) a cellulose ester component which is soluble in alcohol.Type: GrantFiled: January 27, 2000Date of Patent: May 14, 2002Assignee: Colgate-Palmolive CompanyInventors: Jeffrey Joseph Csernica, Peter R. Hilliard, Jr., Paul Joseph Vincenti
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Patent number: 6375937Abstract: This invention comprises aluminum zirconium salts which have a metal to chloride molar ratio in the range of 0.9-1.2:1 and a glycine:zirconium molar ratio greater than 1.3:1 and antiperspirant compositions made with such salts.Type: GrantFiled: October 20, 2000Date of Patent: April 23, 2002Assignee: Colgate-Palmolive CompanyInventors: Suman Chopra, Xiaozhong Tang, Peter Hilliard, Jr.
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Patent number: 6358499Abstract: This invention comprises a one-phase cosmetic composition which can be made as a stick, gel or cream and which has low residue, low tack and improved fragrance substantivity. The cosmetic compositions are formed by (a) from 0.5-50 weight percent of a dimethicone copolyol ester compound soluble in propylene glycol; (b) from 50-98 weight percent of a gellant/solvent system which comprises a mixture of; (i) 0.5-4.0 weight percent dibenzylidene sorbitol; (ii) 0.05-1.0 weight percent of a co-gellant or structural integrity enhancer; (iii) 0.1-80 weight percent of a polyhydric alcohol solvent; (c) 0.5-10% of a small particle size zinc oxide having a particle size in the range of 20 nanometers-200 microns; and (d) 0.1-3.0% fragrance.Type: GrantFiled: February 9, 2001Date of Patent: March 19, 2002Assignee: Colgate-Palmolive CompanyInventors: Patricia Ann Hall-Puzio, Anne Elisabeth Vickery Gale, John Carl-Frederick Brahms
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Patent number: 6353076Abstract: An invention is disclosed which comprises siloxane-based polyamides as gelling agents for cosmetic products, methods for making such agents, formulations thereof and cosmetic formulations therewith. These polyamides contain siloxane groups in the main chain and act to thicken compositions containing volatile and/or non-volatile silicone fluids.Type: GrantFiled: November 3, 1999Date of Patent: March 5, 2002Assignees: Colgate-Palmolive, Dow Corning CorporationInventors: Morton L. Barr, Heng Cai, Anthony Esposito, Joel Freundlich, Douglas W. King, Michael Mendolia, Bhalchandra Moghe, Lenin James Petroff, Thomas Schamper, Michael Ward Skinner, Paul Joseph Vincenti, Ching-min Kimmy Wu, Kenneth Edward Zimmerman
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Patent number: 6350460Abstract: A cosmetic stick product, especially an antiperspirant and/or deodorant is disclosed which is made with a combination of dipropylene glycol, diethyl phthalate and stearyl alcohol. This stick employs the deliberate use of diethyl phthalate even in a system which is free of added fragrance to achieve improved stability and allow for the use of reduced amounts of dipropylene glycol.Type: GrantFiled: February 16, 2000Date of Patent: February 26, 2002Assignee: Colgate-Palmolive CompanyInventors: Peter M. Andrews, Patrick Dubois, Shannon Campbell
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Patent number: 6342210Abstract: A method for forming micronized antiperspirant salts is disclosed wherein the method comprises the steps of: (1) forming an aqueous salt solution of a parent salt wherein the solution has a glycol content of less than 5 weight %; (2) pouring the salt solution onto a bounded flat surface; (3) evaporating the solvent from the salt solution so as to form a glass; (4) breaking up the glass using one or more steps to form particles having an average size in the range of 0.5-2.00 cm2; (5) mixing the particles from step (4) with a non-aqueous liquid vehicle in which the salt is not appreciably soluble and subjecting the mixture to an intermediate grinding process to form a suspension with particles having an average size of less than 200 microns; and (6) grinding the mixture from step (5) at a temperature in the range of 20-70 degrees C. without added water or external heating being required so that the particles in the suspension have an average particle size of less than or equal to 20 microns.Type: GrantFiled: April 20, 2001Date of Patent: January 29, 2002Assignee: Colgate-Palmolive CompanyInventors: Heng Cai, Xiaozhong Tang, Aixing Fan
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Patent number: 6338841Abstract: This invention comprises a clear to translucent anhydrous stick or gel antiperspirant and/or deodorant product having low tack and comprising: (a) a solvent phase comprising: (i) 0.2-4.0 weight % dibenzylidene sorbitol; (ii) 0.05-1.0 weight % of a co-gellant or structural integrity enhancer; (iii) 25-75 weight % of a solvent selected from the group consisting of polyhydric alcohols; (iv) an effective amount of an antiperspirant or deodorant; and (v) 0.1-5 weight % dimethicone copolyol; and (b) an oil phase comprising: (i) 0.25-5 weight % of a silicone elastomer (on a solids basis) in a first dimethicone wherein the dimethicone has a viscosity in the range of 6-100 centistokes and a flashpoint in the range of about greater than 115 degrees C. to 300 degrees C.Type: GrantFiled: July 19, 2001Date of Patent: January 15, 2002Assignee: Colgate-Palmolive CompanyInventors: Jairajh Mattai, Claudio Ortiz, Eric Guenin, John Afflitto
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Patent number: 6294159Abstract: This invention relates to an improved formulation hair volumizers which comprise: (a) from 0.01-15 percent by weight (based on the total weight of the composition) of a selected liquid MQ resin having an M:Q ratio of 0.5-1.5 and a medium viscosity in the range of 1.0×103-1×106 centipoise; and (b) from 85-99.99 percent by weight (based on the total weight of the composition) of a hair care carrier (also called a vehicle). The compositions of this invention provide hair with increased volume without significant stiffness or stickiness and may be made in the form of a shampoo, conditioner, combination shampoo/conditioner, sprays, liquid rinses, gels or mousses.Type: GrantFiled: September 27, 1999Date of Patent: September 25, 2001Assignee: Colgate Palmolive CompanyInventors: Charles Reich, Elizabeth Paradi, Janine Chupa, Cheryl L. Kozubal, Dean Terng-Tzong Su
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Patent number: 6287545Abstract: A system for enhancing the freezing and freeze-thaw stability of hair conditioning compositions has been developed which comprises incorporating therein a combination of low HLB (from about 2.0 to about 9.0) and high (from about 10.0 to about 19.0) HLB ethoxylated branched-chain fatty alcohol ethers and/or esters as freeze-thaw stabilizers while maintaining the pH of said emulsion in a range of about 2.0 to about 5.5.Type: GrantFiled: December 1, 1995Date of Patent: September 11, 2001Assignee: Colgate-Palmolive CompanyInventor: Dean Terng-Tzong Su