Abstract: A baffle ring suitable for retrofitting an existing shell-and-tube heat exchanger with rod baffle supports and a method of retrofitting an existing shell-and-tube heat exchanger with a rod baffle support is provided. The rod baffle rings comprise a first semi-circular member and a second semi-circular member with a first semi-circular member hinged to the second semi-circular member such that they can be hinged open to allow installation on the existing tube bundle and hinged closed to provide a completed rod baffle ring around the tube bundle.
Abstract: A composition which is the reaction product of a mercaptoalcohol and the molybdenum compounds selected from the group consisting of molybdic acids, alkali metal salts of molybdic acids and ammonium salts of molybdic acids. The reaction product is useful in improving the lubricating characteristics of fluids used in metal working operations.
Abstract: A method is provided for forming poly(arylene sulfide) fibrids by flashing a solution which is comprised of a poly(arylene sulfide) polymer in a polar organic compound and which is essentially free of solids under suitable conditions to form a solidified product comprising poly(arylene sulfide) fibrids.
Type:
Grant
Filed:
September 17, 1993
Date of Patent:
February 28, 1995
Assignee:
Phillips Petroleum Company
Inventors:
Carlton E. Ash, Harold D. Yelton, Owen H. Decker, Jon F. Geibel
Abstract: An improved rod baffle heat exchanger and method for manufacturing the same are disclosed in which cross-support members are used to prevent support rod movement and to provide increased rigidity in the heat exchanger. The cross-support members have a threaded circular section at each end, to which threaded nuts are attached. The threaded nuts rest on a protective pad, which is adjacent to the outermost tubes. As the nuts are tightened at each end of the threaded cross-support member, the baffle support rods are brought into firm contact with adjacent tubes.
Abstract: In a polymerization process utilizing a high pressure flash to separate polymer from unreacted monomer contained in the effluent stream from the reactor, the concentration of unreacted monomer in the reaction effluent is determined by withdrawing from the reactor an effective analyzing amount of effluent, exposing the amount to a low pressure flash and analyzing the vaporized portion to determine the concentration of monomer.
Type:
Grant
Filed:
February 8, 1993
Date of Patent:
February 7, 1995
Assignee:
Phillips Petroleum Company
Inventors:
John D. Hottovy, Frederick C. Lawrence, Nelson T. Black
Abstract: The invention relates to inhibiting the degradation of fuel oils by the addition of phosphines and phosphites. Additionally, the invention relates to inhibiting the degradation of fuel oils by drying the fuel oil and adding phosphines and phosphites.
Abstract: An apparatus and method are provided for the defluorination of a liquid hydrocarbon mixture, containing organic fluorides, produced during the conversion of hydrocarbons using a fluorine-containing catalyst. In one embodiment, both thermal means and a contacting material are used to effectuate a more complete defluorination.The liquid hydrocarbon mixture is extracted from a distillation column and heated sufficiently in the thermal means to decompose at least some of the organic fluorides. The effluent from the thermal means is separated into a vaporous and a liquid effluent. The liquid effluent is passed to the bottom of the distillation column where it undergoes further defluorination through contact with the contacting material.
Abstract: A composition and method for forming the composition of poly(arylene sulfide) having improved impact strength and crack resistance. The invention involves mixing poly(arylene sulfide) with a polymeric rubber, a metal hydroxide, and a carboxylic anhydride, each in sufficient amounts and in proportions needed to improve impact strength and crack resistance.
Abstract: An improved alkylation recontactor is provided, wherein the recontactor utilizes an internal mixer for mixing hydrocarbon effluent from an alkylation zone with an acid catalyst from an acid inventory vessel in fluid flow communication with the interior of the recontactor.
Abstract: Poly(biphenylene sulfide/poly(phenylene sulfide) copolymers are produced by contacting a p-dihalobenzene and a bis-p-halobiphenyl under polymerization condiditons. Additionally a poly(biphenylene sulfide)/poly(phenylene sulfide) copolymer/fiber reinforced composite is provided.
Abstract: A high temperature film wrapping is used to wrap thermoplastic materials before they are molded. The thermoplastic material can then be molded by applying heat and pressure and the resulting thermoplastic material will contain reduced cracks and voids compared with thermoplastic materials molded without the wrapping.
Type:
Grant
Filed:
April 15, 1991
Date of Patent:
June 14, 1994
Assignee:
Phillips Petroleum Company
Inventors:
Charles M. Hall, Wen W. Tseng, Ralph Beavers
Abstract: A method for determining the suitability of a distillate fuel for use after storage by measuring the absorption of ultraviolet light by the fuel.
Abstract: A composition comprising a polyolefin and a hydroxylamine is disclosed as having improved clarity and viscosity. In addition, a method of reducing the viscosity and improving the clarity of a polyolefin is disclosed, wherein the process comprises visbreaking the polyolefin in the presence of a hydroxylamine.
Type:
Grant
Filed:
October 21, 1992
Date of Patent:
December 14, 1993
Assignee:
Phillips Petroleum Company
Inventors:
Kenneth W. Willcox, Francis X. Mueller, Jr.
Abstract: A catalytic cracking composition comprising a physical blend of a cracking catalyst component with alcohol treated Sr(OH).sub.2 and alcohol is used to crack hydrocarbon-containing feedstocks that further contain quantities of vanadium.
Abstract: A method and apparatus to melt and withdraw petroleum residue from a storage site at a convenient location while causing the residue from more distant locations to melt and flow in a stream, to the removal location. A heated wand is utilized to heat the petroleum residue. The wand has one pivotally supported end and is moved in an arc about the pivotally supported end across the storage site with removal of heated petroleum residue occurring at substantially the center of the arc.
Abstract: Processes and compositions for improving the mechanical properties of arylene sulfide polymers used in molding processes are described. A composition comprising poly(arylene sulfide) and bi-lobal fiber selected from the group consisting of glass, carbon, rock, slag, and combinations of any two or more thereof, is disclosed as useful in the molding of articles.
Abstract: Poly(biphenylene sulfide/poly(phenylene sulfide) copolymers are produced by contacting a p-dihalobenzene and a bis-p-halobiphenyl under polymerization conditions. Additionally a poly(biphenylene sulfide)/poly(phenylene sulfide) copolymer/fiber reinforced composite is provided.
Abstract: A defect detection system for the optical inspection of defects in transparent and translucent sheets of materials. The system utilizes the differing optical properties of different defects to distinguish between such defects as fisheye defects, speck defects and scratches.
Type:
Grant
Filed:
December 19, 1991
Date of Patent:
June 15, 1993
Assignee:
Phillips Petroleum Company
Inventors:
Mark J. Dreiling, Frankie K. Wood-Black, George A. Moczygemba
Abstract: An improved alkylation recontactor is provided, wherein the recontactor utilizes an internal mixer for mixing hydrocarbon effluent from an alkylation zone with an acid catalyst from an acid inventory vessel in fluid flow communication with the interior of the recontactor.
Abstract: Cyclic polyenes are selectively hydrogenated to cyclic monoenes under suitable hydrogenation conditions in the presence of an activated ruthenium catalyst complexes. The ruthenium catalyst complex is activated by hydrogenating a minimal amount of cyclic polyene under suitable hydrogenation conditions.