Patents Represented by Attorney S. H. Markowitz
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Patent number: 4914068Abstract: This invention relates to methods for dispersing Group-VIII and other metals containing zeolites, particularly large pore zeolites.Type: GrantFiled: March 21, 1988Date of Patent: April 3, 1990Assignee: Exxon Chemical Patents Inc.Inventors: Virginia R. Cross, Jar L. Kao, Thomas H. Vanderspurt, Murray Nadler, Theodorus M. Wortel
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Patent number: 4894214Abstract: Zeolite L containing caesium is prepared by a process in which said zeolite L is crystallized from a synthesis mixture with a molar composition (expressed as oxides) of:K.sub.2 O/SiO.sub.2 : 0.15 to 0.40K.sub.2 O/Cs.sub.2 O: 3 to 10H.sub.2 O/K.sub.2 O: 40 to 100, andSiO.sub.2 /Al.sub.2 O.sub.3 : 7 to 13and containing 0.5 to 15 ppm (by weight) of divalent metal carbons, e.g. Mg ions. The zeolite L can form part of a dehydrocyclization and/or isomerization catalyst.Type: GrantFiled: February 25, 1988Date of Patent: January 16, 1990Assignee: Exxon Research & Engineering CompanyInventors: Johannes P. Verduijn, Pieter E. Gellings
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Patent number: 4882406Abstract: Nodular copolymer and method of preparing a nodular copolymer by preparing a copolymer chain and coupling it with a coupling agent. The copolymers which form the nodular copolymer are formed of first and second segments, of which the second segments, containing the coupling agent, react to form the nodular region. The nodular copolymer is particularly useful as a lube oil additive.Type: GrantFiled: March 5, 1986Date of Patent: November 21, 1989Assignee: Exxon Research & Engineering CompanyInventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 4851605Abstract: A process for preparing a zeolite, e.g. ZSM-5, under controlled conditions of pH adjustment with an acid; SiO.sub.2 /Al.sub.2 O.sub.3 mole ratio, and in the substantial absence of alkali metal cations, is disclosed, as well as a process for using the same to synthesize olefins from methanol and/or dimethyl ether.Type: GrantFiled: July 13, 1984Date of Patent: July 25, 1989Assignee: Exxon Research & Engineering Co.Inventors: Arie Bortinger, Wim Pieters, Elena N. Suciu
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Patent number: 4849361Abstract: Method of characterizing the coking tendency of a baseoil, by:(a) exposing the baseoil to conditions which accelerate asphaltene formation in the baseoil; and(b) testing for the onset and/or progression of asphaltene formation as a function of time.The technique is also useful for determining the efficacy of oil additives.Type: GrantFiled: June 20, 1986Date of Patent: July 18, 1989Assignee: Exxon Chemical Patents Inc.Inventor: Ghazi B. Dickakian
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Patent number: 4843129Abstract: A composition comprising:(a) at least one copolymer having at least one of M.sub.w /M.sub.n less than 2 and M.sub.z /M.sub.w less than 1.8; and(b) at least one plastic composition.The composition can be produced by preparing the elastomer and then blending it with the plastic. The composition can be subjected to an additional step of curing.Type: GrantFiled: March 3, 1986Date of Patent: June 27, 1989Assignee: Exxon Research & Engineering CompanyInventors: Lawrence Spenadel, Joel H. Grosser, Stephen M. Dwyer
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Patent number: 4839320Abstract: This invention relates to a method for treating zeolite-containing catalysts. It is particularly suitable for making catalytic compositions made up of large pore zeolites of which a large percentage of the cationic substitution sites therein contain an alkali or alkaline earth metal and further containing one or more other Group VIII noble metals and a binder. The binder preferably is formed of a particular ratio of alumina from both a sol and boehmite. The step of impregnating the zeolite with a catalytic metal may be carried out at a particular pH range so as to promote aromatics yield after later regeneration. The formed catalyst is treated with a solution of a particular pH at one or more instances either in the catalyst production procedure or after its use to stabilize the catalyst after regeneration. This catalyst is suitable for use as a reforming catalyst or in the production of benzene. The catalyst has quite high activity, selectivity, and excellent physical characteristics.Type: GrantFiled: October 13, 1987Date of Patent: June 13, 1989Assignee: Exxon Research & Engineering Co.Inventors: Theodore D. Trowbridge, Shun C. Fung
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Patent number: 4828681Abstract: The invention relates to carrying out thermal cracking of hydrocarbons, or other thermal conversions of organic substances in a reactor, for which a suitable reaction time is extremely short, e.g. of the order of milliseconds. Particulate solids are used as heat carrier and as feed an organic substance is used in the form of a gas which may contain some liquid; the hot particulate solids are introduced at low or no velocity into contact with the gas, which is at substantially higher velocity; the solids accelerate in passing through the reactor but the reaction is terminated substantially before the solids attain the velocity of the product gas. Contact times are short so that the solids do not accelerate to erosive speeds. The velocity differential enhances the heat transfer rate which makes short reaction times feasible.Type: GrantFiled: January 15, 1987Date of Patent: May 9, 1989Assignee: Exxon Research & Engineering CompanyInventors: John B. Yourtee, John M. Matsen
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Patent number: 4824816Abstract: This invention relates to a method for producing zeolite-containing catalysts. It is particularly suitable for making catalytic compositions made up of large pore zeolites of which a large percentage of the cationic substitution sites therein contain an alkali or alkaline earth metal and further containing one or more other Group VIII noble metals and a binder. The binder preferably is formed of a particular ratio of alumina from both a sol and boehmite. The step of impregnating the zeolite with a catalytic metal is carried out at a particular pH range so as to promote aromatics yield after later regeneration. This catalyst is suitable for use as a reforming catalyst or in the production of benzene. The catalyst has quite high activity, selectivity, and excellent physical characteristics.Type: GrantFiled: September 21, 1987Date of Patent: April 25, 1989Assignee: Exxon Research & Engineering CompanyInventors: Theodore D. Trowbridge, Shun C. Fung, Thomas H. Vanderspurt
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Patent number: 4824969Abstract: A process for reacting in admixture, an olefin with oxygen, CO, and water, to form a cyclic alkylene carbonate, in the presence of a catalyst composition comprising a catalytically active osmium compound, copper containing co-catalyst I (e.g. CuBr.sub.2) and a co-catalyst II (e.g. pyridine) is disclosed.Type: GrantFiled: December 24, 1984Date of Patent: April 25, 1989Assignee: Exxon Research & Engineering Co.Inventors: Richard G. Austin, Robert C. Michaelson, Richard S. Myers
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Patent number: 4804800Abstract: A process for preparing a zeolite, e.g. ZSM-5, under controlled conditions of initial pH adjustment with an acid, SiO.sub.2 /Al.sub.2 O.sub.3 mole ratio, and in the presence of sodium cations, is disclosed, as well as a process for using the same to synthesize olefins from methanol and/or dimethyl ether.Type: GrantFiled: November 16, 1987Date of Patent: February 14, 1989Assignee: Exxon Research & Engineering Co.Inventors: Arie Bortinger, Robert A. Maggio, Wim J. M. Pieters
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Patent number: 4801654Abstract: A block copolymer is disclosed which includes an ethylene-propylene copolymer segment (A) and a tetrahydrofuran segment (B). The weight ratio of (A) to (B) is 5/95 to 95/5, and the block copolymer has a number-average molecular weight of about 1,000 to about 1,000,000.Type: GrantFiled: June 12, 1987Date of Patent: January 31, 1989Assignee: Toa Nenryo Kogyo K.K.Inventors: Tokuo Makishima, deceased, by Nobuko Makishima, legal representative, Satoshi Ueki, Chihiro Imai
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Patent number: 4792595Abstract: The present invention relates to novel copolymers of alpha-olefins comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains.Type: GrantFiled: June 17, 1985Date of Patent: December 20, 1988Assignee: Exxon Research & Engineering Co.Inventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 4786697Abstract: Polymodal MWD ethylene copolymer comprising at least two modes of differing molecular weights. Each mode has at least one of M.sub.w /M.sub.n of less than 2.0, and a M.sub.z /M.sub.w of less than 1.8. The polymodal character of the copolymer is achieved by either (1) withdrawing polymer modes from the reactor from at least one takeoff port, and blending such modes with the reactor effluent, or (2) utilizing at least two catalyst species in the reaction to produce modes of differing molecular weights.Type: GrantFiled: May 4, 1987Date of Patent: November 22, 1988Assignee: Exxon Research & Engineering Co.Inventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 4764356Abstract: A process for preparing a zeolite, e.g. ZSM-5, under controlled conditions of initial pH adjustment with an acid, SiO.sub.2 /Al.sub.2 O.sub.3 mole ratio, and in the presence of sodium cations, is disclosed, as well as a process for using the same to synthesize olefins from methanol and/or dimethyl ether.Type: GrantFiled: December 21, 1984Date of Patent: August 16, 1988Assignee: Exxon Research & Engineering Co.Inventors: Arie Bortinger, Robert A. Maggio, Wim J. M. Pieters
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Patent number: 4741840Abstract: A process is disclosed for treating sludge to remove the liquid hydrocarbons from the insoluble particles in the sludge to provide treated particles which are environmentally safe. The process involves mixing the sludge with a hydrocarbon diluent, separating the particles from the diluent-sludge mixture, then mixing the separated particles and remaining diluent with water and distilling off the remaining diluent to obtain the treated particles.Type: GrantFiled: June 25, 1986Date of Patent: May 3, 1988Assignee: Exxon Research & Engineering Co.Inventors: George A. Atherton, Ghazi A. Dickakian, Edward D. Grant, Jr.
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Patent number: 4737301Abstract: Inexpensive lubricating oil antioxidants having a solubilizing group which comprises alkyl and cycloalkyl-substituted aromatics and a reducing thiophenyl group, which are useful motor oil additives. Method of reducing coking tendencies of lubricating oils by incorporating the substituted aromatic antioxidants.Type: GrantFiled: June 20, 1986Date of Patent: April 12, 1988Assignee: Exxon Chemical Patents Inc.Inventors: Ricardo Bloch, Ghazi B. Dickakian
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Patent number: 4722971Abstract: By selecting the composition and intermolecular compositional distribution with respect to ethylene and diene content and the molecular weight and molecular weight distribution, ethylene-propylene-diene terpolymers can have both improved processing properties and compound vulcanizate physical properties. The lower molecular weight fractions of 10.sup.4 to about 5.times.10.sup.5 have at least 2 times the diene content of the higher molecular weight fractions and an ethylene content of 30-80 wt. %. The higher molecular weight fractions of 2.times.10.sup.5 to about 10.sup.7 have a higher ethylene content than the lower molecular weight fractions and are less than 90 wt. % ethylene.Type: GrantFiled: February 24, 1987Date of Patent: February 2, 1988Assignee: Exxon Chemical Patents Inc.Inventors: Sudhin Datta, Edward N. Kresge
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Patent number: 4716207Abstract: A method of preparing a nodular polymer by preparing a copolymer chain and coupling it to a coupling agent. The coupling agent is a non-conjugated diene. Preferably the non-conjugated diene has both double bonds Ziegler catalyst polymerizable. The preferred product comprises a norbornadiene coupled ethylene copolymer wherein the ethylene copolymer has a M.sub.z /M.sub.m of less than 2.0 and a M.sub.w /M.sub.n of less than 1.8 before coupling.Type: GrantFiled: September 4, 1986Date of Patent: December 29, 1987Assignee: Exxon Research & Engineering Co.Inventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 4705830Abstract: A block copolymer is disclosed which includes an ethylene-propylene copolymer segment (A) and a tetrahydrofuran segment (B). The weight ratio of (A) to (B) is 5/95 to 95/5, and the block copolymer has a number-average molecular weight of about 1,000 to about 1,000,000.Type: GrantFiled: May 24, 1985Date of Patent: November 10, 1987Assignee: Toa Nenryo Kogyo Kabushiki KaishaInventors: Tokuo Makishima, deceased, by Nobuko Makishima, legal representative, by Satoshi Ueki, legal representative, by Chichiro Imai, legal representative