Abstract: A liquid photopolymer layer covering a phototool image surface with one surface exposed to air is exposed by radiation through the phototool to partially harden in a pattern defined by the image the photopolymer layer through a part of its thickness. The air exposed surface portion is thus left in liquid form for contacting the surface of a printed wiring board, preferably by scanning along the length of a phototool with a pressurized roll or blade to contact and adhere the preimaged laminate to board surface in an air bubble free lamination where subsequent radiation exposure finishes the curing and bonds the cured portion of the polymer layer to the PWB substrate. After removal of the phototool, the polymer layer is developed by washing out uncured polymer portions as defined by the image pattern.

Abstract: A composition including a mixture of UV curable urethane acrylate and a urethane diacrylate compounds provides an aqueous alkaline developable, flexible solder mask having excellent electrical insulation resistance under hydrolytic testing conditions at elevated temperatures.

Abstract: What is described herein is a method of electroplating an adherent chromium deposit on a chromium substrate. The process is characterized by chemically oxidizing the chromium substrate before starting the electrodeposition of chromium thereon. A suitable chemical oxidizing agent is hydrogen ion, which can be furnished by a dilute acid solution. The invention is applicable to any chromium electroplating bath, including high energy efficient chromium baths, such as HEEF-40 baths, which are presently in commercial use.

Abstract: A composition including a mixture of UV curable urethane acrylate and a urethane diacrylate compounds provides an aqueous alkaline developable, flexible solder mask having excellent electrical insulation resistance under hydrolytic testing conditions at elevated temperatures.

Abstract: A tin oxide coated article characterized by including a transparent, haze-free tin oxide coating on a substrate, such as glass. The tin oxide coating is formed by deposition from a liquid coating composition including an organotin compound, such as an alkyltin trichloride, and a haze-reducing additive, such as a fluorocarboxylic acid or acid anhydride.

Abstract: Transparent, non-iridescent, infrared-reflecting glass window structures which are haze-free are provided herein. These structures comprise a glass sheet, an infrared-reflecting tin oxide coating on one major surface of the sheet, and an iridescence-reducing tin oxide coating on the opposed major surface of the sheet. The iridescence-reducing tin oxide coating is particularly characterized by being haze-free by virtue of its being made by contacting said sheet with monophenyltin trichloride in an oxygen-containing atmosphere.

Abstract: Polyimides or poly(amide-imides), especially those containing a polysiloxane unit are improved by heating such polymers or their polyamic acid precursors with a polyfunctional aromatic compound. The polyfunctional aromatic compound is one which contains at least two reactive groups which may be --NH.sub.2, --COOH, --OH or secondary amino groups with at least one of the reactive groups being --NH.sub.2 or --COOH.

Abstract: What is described herein is an improved method of electroplating an adherent chromium deposit on a chromium substrate. The process is characterized by chemically oxidizing the chromium substrate before starting the electrodeposition of chromium thereon. A suitable chemical oxidizing agent is hydrogen ion, which can be furnished by a dilute acid solution. In this invention, the acid is characterized by being destroyed in the plating bath, if dragged therein. Suitable acids include oxalic and citric acids. The process is applicable to any chromium electroplating bath, including high energy efficient chromium baths, such as HEEF-40 baths, which are presently in commercial use.

Abstract: This invention relates to organotin compounds containing fluorine which are particularly useful for forming fluorine-doped tin oxide coatings by the chemical vapor deposition method. In the preferred embodiment, the compound is monobutyldichlorotin trifluoroacetate, which is prepared by reaction of monobutyltin trichloride and trifluoroacetic acid.

Abstract: An improved liquid coating composition for producing high quality, high performance fluorine-doped tin oxide coatings by chemical vapor deposition includes the reaction product of a reactive fluorine dopant compound and an organotin compound, preferably 1-30 wt. % of the fluorine dopant and 70-99 wt. % of the organotin compound. The preferred liquid coating composition includes the reaction product of trifluoroacetic acid and monobutyltin trichloride.

Abstract: An adherent, smooth electrodeposit of chromium is produced on a nodular cast iron substrate from a chromium plating bath. The desired deposit is provided herein by activating the substrate, subjecting the activated substrate to an ultrasonic treatment, and thereafter plating chromium from a chromium plating bath. The method is particularly effective for electrodeposition of chromium on such substrates from commercial high energy efficient chromium electroplating baths, where ordinarily only roughened deposits are obtained.

Abstract: Apparatus for coating an optical fiber with a metal oxide coating material in vapor form, includes a coating chamber through which the fiber moves, the coating chamber including an inlet supplied with the coating material in vapor form, a circumferential passage for supplying the coating material to the fiber, a flow restriction passage in fluid communication between the inlet and the circumferential passage for supplying the coating material from the inlet to the circumferential passage, the flow restriction passage including a tortuous circumferential path through a plurality of circumferentially arranged orifices and a through a narrow gap, and an oil jacket containing heated oil surrounding the walls of the coating chamber for heating the same; an evaporator for supplying the coating material in vapor form to the inlet; and a heating assembly for supplying heated air to the evaporator to entrain the coating material and for supplying heated oil to the evaporator for heating the coating material and to the

Abstract: The two-step electrolytic activation process comprises anodic treatment in a polarizing solution followed sequentially by a cathodic treatment in an electrolyte solution. The activation process is useful for cast iron substrates to enable electrodeposition of chromium thereon which is adherent, bright, smooth and hard, particularly from high energy efficient chromium baths.

Abstract: An aqueous alkaline developable UV curable urethane acrylate compound and composition are used for making flexible solder mask coatings, characterized by rapid development in an aqueous, alkaline medium, and advantageous performance properties.

Abstract: Copper substantially free of micro-pores is electrodeposited on a polished surface of a stainless steel, titanium, or chromium-plated steel press plate. The copper layer is then provided with a matte surface of copper of dendritic structure which is subsequently bonded to a dielectric material under the application of heat and pressure in a laminating press. The resulting copper-clad dielectric board separates from the press plate, which can then be re-used.

Abstract: A printed circuit board having improved adhesion between solder mask and metal includes a primer film on the metal deposited from an aqueous solution which includes 0.01 to 10% by weight of a carboxyl-containing polymer or copolymer.

Abstract: An activation composition and method for producing chromium electrodeposits having excellent adhesion on both soft and hardened ferrous substrates from high energy efficient chromium baths is described. The activation composition is a solution containing iodate and fluoroborate ions, optionally with cerium ion as a stabilizer. The method includes electrolytically etching the substrate in the activation solution, preceded or followed by reverse etching in chromic acid. The chromium electrodeposit can be carried out effectively to provide the desired adherent deposit from a high energy efficient (HEEF) chromium plating bath.

Abstract: An apparatus for applying a phototool to a light sensitive substrate by means of a roller for applying the phototool to the substrate and a vacuum restraining means for restraining the phototool to maintain it under tension during application of the phototool to the substrate.

Abstract: In accordance with the invention, there is provided herein an improved chemical vapor deposition method for forming fluorine-doped tin oxide coatings using a liquid coating composition which includes a reactive organic fluorine dopant and an organotin compound. The method is carried out under a defined set of process conditions such that the coating produced has a minimum and constant sheet resistance which is substantially independent of deposition temperature.

Abstract: A novel polymeric binder for use in an antifouling paint includes an acrylic or methacrylic ester monomer having selected substituted aryl or arylalkyl substituent groups in the ester moiety so that the ester is hydrolyzable at a suitable rate in seawater, and a copolymerizable ethylenically unsaturated monomer unit.