Patents Represented by Attorney S. Preston Jones
  • Patent number: 5787686
    Abstract: The present invention further provides a substantially non-aqueous agricultural pesticide concentrate formulation of a non-ionic surfactant and a amphipathic graft copolymer composition in admixture with a water-insoluble organic agricultural pesticide which concentrate formulation can be easily diluted with water to form non-settling, freeze-thaw stable formulations.The present invention further provides methods for the use of water-diluted agricultural pesticide concentrate formulations of the above non-ionic surfactant concentrate formulations in the kill and control of agricultural pest.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: August 4, 1998
    Assignee: The Dow Chemical Company
    Inventors: Craig J. Bott, Dale M. Pickelman, Ritchie A. Wessling
  • Patent number: 5777167
    Abstract: The instant invention is directed to a process for removing odor from alkylthioethylamine reaction product mixtures having said odor. The process comprises first contacting an alkylthioethanamine reaction product mixture with a neutralizing amount of aqueous alkali metal hydroxide to form an organic phase and an aqueous phase. Next, the organic phase is separated from the aqueous phase. After separation, a sufficient amount of an aqueous hydrohalic acid is added to the organic phase to form an alkylthioethanamine hydrohalide which has reduced odor.
    Type: Grant
    Filed: September 14, 1996
    Date of Patent: July 7, 1998
    Assignee: The Dow Chemical Company
    Inventors: Charles D. Gartner, George A. Paul
  • Patent number: 5753766
    Abstract: The present invention provides amphipathic graft copolymers which comprises a hydrophobic polymer portion to which is grafted at least one amphipathic polymer portion containing pH independent ionic groups. The amphipathic graft copolymers can be prepared employing a procedure which comprises polymerizing at least two hydrophobic monomers, wherein at least one of the monomers is a graftable monomer, and at least one hydrophilic monomer, including at least one anionic and/or cationic pH independent ionic monomer, or a post reactive non-ionic monomer that can be converted to a pH independent ionic derivative, in a reaction medium and recovering the thus prepared amphipathic graft copolymer. Stable, substantially non-aqueous solution compositions of said amphipathic graft copolymer containing less than 15 percent by weight water are also provided.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: May 19, 1998
    Assignee: The Dow Chemical Company
    Inventors: Craig J. Bott, Dale M. Pickelman, Thomas E. Fisk
  • Patent number: 5753248
    Abstract: The present invention further provides a substantially non-aqueous agricultural pesticide concentrate formulation of a non-ionic surfactant and a amphipathic graft copolymer composition in admixture with a water-insoluble organic agricultural pesticide which concentrate formulation can be easily diluted with water to form non-settling, freeze-thaw stable formulations.The present invention further provides methods for the use of water-diluted agricultural pesticide concentrate formulations of the above non-ionic surfactant concentrate formulations in the kill and control of agricultural pest.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: May 19, 1998
    Assignee: The Dow Chemical Company
    Inventors: Craig J. Bott, Dale M. Pickelman, Ritchie A. Wessling
  • Patent number: 5723486
    Abstract: Disclosed are 1,3-dithiolo(4,5-d)-1,3-dithiino-2-thione compounds corresponding to one of the formulae: ##STR1## wherein R.sup.1 represents --Br, --Cl, --F, --CN or --CH(CH.sub.2).sub.n CH.sub.3 and n is an integer of from 0 to 10.These compounds as well as the unsubstituted compound have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: March 3, 1998
    Assignee: The Dow Chemical Company
    Inventors: Weishi W. Wu, Duane R. Romer, Ravi B. Shankar, R. Garth Pews
  • Patent number: 5703102
    Abstract: Disclosed are compositions containing 1,2,5-thiadiazolo-1,3-dithiole-2-one or thione corresponding to the formula: ##STR1## wherein Z is oxygen or sulfur and the use thereof as antimicrobial and marine antifouling agents.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: December 30, 1997
    Assignee: The Dow Chemical Company
    Inventors: Ravi B. Shankar, Duane R. Romer, R. Garth Pews
  • Patent number: 5703114
    Abstract: Disclosed is the use of compositions employing a 4,5-dicyano-1,3-dithiole-2-one (or thione) compound corresponding to the formula: ##STR1## wherein Z is oxygen or sulfur as the active antimicrobial and marine antifouling agent.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: December 30, 1997
    Assignee: The Dow Chemical Company
    Inventors: Ravi B. Shankar, Duane R. Romer, R. Garth Pews
  • Patent number: 5693716
    Abstract: The present invention provides amphipathic graft copolymers which comprises a hydrophobic polymer portion to which is grafted at least one amphipathic polymer portion containing pH independent ionic groups. The amphipathic graft copolymers can be prepared employing a procedure which comprises polymerizing at least two hydrophobic monomers, wherein at least one of the monomers is a graftable monomer, and at least one hydrophilic monomer, including at least one anionic and/or cationic pH independent ionic monomer, or a post reactive non-ionic monomer that can be converted to a pH independent ionic derivative, in a reaction medium and recovering the thus prepared amphipathic graft copolymer. Stable, substantially non-aqueous solution compositions of said amphipathic graft copolymer containing less than 15 percent by weight water are also provided.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: December 2, 1997
    Assignee: The Dow Chemical Company
    Inventors: Craig J. Bott, Dale M. Pickelman, Thomas E. Fisk
  • Patent number: 5661165
    Abstract: Disclosed are ((4-phenyl-1,2,5--thiadiazol-3-yl)oxy)methyl ester thiocyanic acid compounds corresponding to the formula: ##STR1## wherein X represents --Br, --Cl, --F, --CF.sub.3, --OCF.sub.3, --CN, C.sub.1 -C.sub.7 straight or branched chain alkyl, C.sub.1 -C.sub.7 straight or branched chain alkoxy or --COOR wherein R is --H or C.sub.1 -C.sub.7 straight or branched chain alkyl and n is an integer of from 0-5.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: August 26, 1997
    Assignee: The Dow Chemical Company
    Inventors: Ravi B. Shankar, R. Garth Pews, Duane R. Romer
  • Patent number: 5661176
    Abstract: Disclosed are (2-one (or thione)-1,3-dithiole-4,5-diyl)bis(thiomethylthiocyanate) compounds corresponding to the formula: ##STR1## wherein Z is oxygen or sulfur, compositions containing said compounds and their use as antimicrobial and marine antifouling agents.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: August 26, 1997
    Assignee: The Dow Chemical Company
    Inventors: Duane R. Romer, Weishi W. Wu, Ravi B. Shankar, R. Garth Pews
  • Patent number: 5631277
    Abstract: Disclosed is (2-thione-1,3-dithiole 4,5-diyl) bis(thiocyanate), its preparation and its use as an antimicrobial and marine antifouling agent.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: May 20, 1997
    Assignee: The Dow Chemical Company
    Inventors: Duane R. Romer, Weishi W. Wu, Ravi B. Shankar, R. Garth Pews
  • Patent number: 5631207
    Abstract: Disclosed is the use of compositions employing 5-alkyl-1,3,4-oxadiazol(or thiadiazol)-2-thiomethylthiocyanates as the active marine antifouling agent.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: May 20, 1997
    Assignee: The Dow Chemical Company
    Inventors: Duane R. Romer, Ravi B. Shankar, R. Garth Pews
  • Patent number: 5560909
    Abstract: The invention concerns certain insecticidal compositions of ingestible insecticides selected from the group consisting of DNA viruses, RNA viruses and bacteria of the order Bacillus such as, for example, Bacillus thuringiensis var. israelensis entrapped by a suitable charged polymer. The invention also concerns a process for the preparation of and the use of such insecticidal compositions.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: October 1, 1996
    Assignee: DowElanco
    Inventors: Lisa J. Rheaume, Julia A. Gegner, James J. Jakubowski, Daniel H. Haigh, James Peters
  • Patent number: 5508035
    Abstract: Stable emulsions of water-insoluble organic pesticides are formed by mixing the pesticide with an aqueous dispersion of a graft copolymer comprising a reactive polymeric surfactant base polymer and a nonionic hydrophobic grafted composition. The graft copolymer spontaneously absorbs organic pesticides with low water solubility upon simple mixing. The resulting product is much more stable to coalescence than emulsions made with conventional or polymeric surfactants.Emulsifiable organic based concentrates, having a continuous oil phase, which are formed from admixtures of pesticidally active water-insoluble organic pesticides with graft copolymers can be diluted with or in water, thus, inverting the continuous oil phase to stable water based oil-in-water emulsions of the active pesticide.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: April 16, 1996
    Assignee: DowElanco
    Inventors: Ritchie A. Wessling, Dale M. Pickelman, Dennis G. Wujek
  • Patent number: 5498773
    Abstract: Disclosed are herbicidal concentrate formulation compositions having reduced grass crop plant phytotoxicity comprising certain sulfonamide or sulfonylurea herbicides in admixture with a non-herbicidal organic or inorganic acid or mixture thereof in an amount sufficient to insure that during the post-emergent agricultural uses thereof in water diluted form the pH of the mixture is below about 5; also disclosed is the preparation of said compositions, aqueous formulations of said concentrate and the use of said formulations.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: March 12, 1996
    Assignee: DowElanco
    Inventors: Robert L. Noveroske, Ronald W. McCormick
  • Patent number: 5491155
    Abstract: Substituted thiadiazoles which correspond to the formula: ##STR1## wherein X and Y each independently represents --Br, --Cl, --OCH.sub.3, --SCN, --OCH.sub.2 SCN, --SCH.sub.2 SCN, --OCH.sub.2 CH.sub.2 SCN or --SCH.sub.2 CH.sub.2 SCN, provided that at least one of X or Y represents --SCN, --OCH.sub.2 SCN, --SCH.sub.2 SCN, --OCH.sub.2 CH.sub.2 SCN or --SCH.sub.2 CH.sub.2 SCN are disclosed.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: February 13, 1996
    Assignee: The Dow Chemical Company
    Inventors: Ravi B. Shankar, R. Garth Pews, Duane R. Romer
  • Patent number: 5488051
    Abstract: Substituted 5,6-dihydro-5-oxo-1,4-dithiino-(2,3-d)-pyridazine-2,3-dicarbonitriles are prepared which correspond to the formula: ##STR1## wherein R represents ##STR2## wherein X.sup.1 is Cl, Br, NO.sub.2 or CH.sub.3, y is 0 or 1 and n is 0, 1 or 2.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: April 21, 1994
    Date of Patent: January 30, 1996
    Assignee: The Dow Chemical Company
    Inventors: Duane R. Romer, R. Garth Pews, Ravi B. Shankar, Charles A. Wilson
  • Patent number: 5488060
    Abstract: Substituted thiadiazoles which correspond to the formula: ##STR1## wherein R represents ##STR2## X represents --Br, --Cl, --F, --CH.sub.3, --OCH.sub.3, --COOCH.sub.3, --NO.sub.2, --SCH.sub.3, --SO.sub.2 CH.sub.3 or --CF.sub.3 and Y is --SCN or --SCH.sub.2 SCN.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: January 30, 1996
    Assignee: The Dow Chemical Company
    Inventors: Ravi B. Shanker, Duane R. Romer, R. Garth Pews
  • Patent number: 5466707
    Abstract: Various 4,5-dimercapto-1,3-dithiolo-2-one or thione maleimides corresponding to the formula ##STR1## wherein R represents --H, phenyl, benzyl, phenethyl, a C.sub.1 -C.sub.10 straight or branched chain alkyl radical, a C.sub.3 -C.sub.10 cycloalkyl radical, a C.sub.1 -C.sub.10 straight or branched chain alkoxy radical, a C.sub.3 -C.sub.10 cycloalkoxy, an ester of the formula --CH.sub.2 CH.sub.2 O--C(O)--R.sup.1, wherein R.sup.1 represents a C.sub.1 -C.sub.5 straight or branched chain alkyl radical or a C.sub.3 -C.sub.5 cycloalkyl radical and Z represents oxygen or sulfur are disclosed.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: November 14, 1995
    Assignee: The Dow Chemical Company
    Inventors: Weishi W. Wu, Ravi B. Shankar, Duane R. Romer, R. Garth Pews
  • Patent number: 5399542
    Abstract: The present disclosure is directed to substituted cyclohexanedione compounds, the preparation of said compounds, compositions containing said compounds and the use of said compositions in the selective pre- and postemergent kill and control of grassy weeds in the presence of various broad-leafed and grassy crop plants.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: March 21, 1995
    Assignee: DowElanco
    Inventors: Christopher T. Hamilton, Lowell D. Markley, Todd C. Geselius