Patents Represented by Attorney, Agent or Law Firm S. R. Bresch
  • Patent number: 6228917
    Abstract: A composition comprising: (a) polyethylene; (b) as a scorch inhibitor, 4,4′-thiobis(2-methyl-6-t-butylphenol); 2,2′ thiobis(6-t-butyl-4-methylphenol); or mixtures thereof; (c) optionally, a cure booster; and (d) an organic peroxide.
    Type: Grant
    Filed: June 16, 1998
    Date of Patent: May 8, 2001
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Michael John Keogh
  • Patent number: 6143843
    Abstract: A process comprising contacting one or more monomers with a catalyst, in the gas phase, under polymerization conditions, in a fluidized bed reactor, with the proviso that the reactor is at least partially cooled internally by the vaporization of a liquid cryogen directly into the reactor.
    Type: Grant
    Filed: January 22, 1999
    Date of Patent: November 7, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Saul R. Bresch
  • Patent number: 6136748
    Abstract: A catalyst composition for the polymerization of olefins is provided, which comprises a) a catalyst comprising a metal atom complexed with a non-cycloalkadienyl anionic ligand, wherein the chemical hardness, .eta., and chemical potential, .mu., of said non-cycloalkadienyl anionic ligand calculated using the MOPAC (PM3) computer program satisfy the relationship: .eta.=3.0+0.75.mu..+-.0.2 eV; and b) an activating cocatalyst.
    Type: Grant
    Filed: June 12, 1998
    Date of Patent: October 24, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Jack Allen Smith
  • Patent number: 6136747
    Abstract: A mixed catalyst composition comprising a) a solid Ziegler-Natta catalyst; b) a liquid single site catalyst; and c) at least one activating cocatalyst is provided. Polymers having a broad or bimodal molecular weight distribution may be made with this catalyst composition.
    Type: Grant
    Filed: June 19, 1998
    Date of Patent: October 24, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Sun-Chueh Kao, Frederick John Karol, Paul Theodore Daniell, Gregory Mark Goode
  • Patent number: 6114475
    Abstract: There is provided a process for drying a fluidized reactor system comprising introducing a boiling point depressing agent into said system optionally while heating said system.
    Type: Grant
    Filed: April 6, 1998
    Date of Patent: September 5, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Mark Gregory Goode, Eldon Ronald Larsen, Hemal Ranchhod Patel, Jeffery Scott Bradley
  • Patent number: 6096676
    Abstract: A catalyst precursor having the formula: ##STR1## wherein M is a Group IVB metal; each L is a monovalent, bivalent, or trivalent anion;X and Y are each heteroatoms;each Cyclo is a cyclic moiety;each R.sup.1 is a group containing 1 to 50 atoms selected from the group consisting of hydrogen and Group IIIA to Group VIIA elements, and two or more adjacent R.sup.1 groups may be joined to form a cyclic moiety;each R.sup.2 is a group containing 1 to 50 atoms selected from the group consisting of hydrogen and Group IIIA to Group VIIA elements, and two or more adjacent R.sup.2 groups may be joined to form a cyclic moiety;W is a bridging group; andeach m is independently an integer from 0 to 5.
    Type: Grant
    Filed: June 18, 1998
    Date of Patent: August 1, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Rex Eugene Murray
  • Patent number: 6007913
    Abstract: An article of manufacture comprising (i) a plurality of electrical conductors, each surrounded by one or more layers of a composition comprising (a) one or more polyolefins and, blended therewith, (b) a mixture containing one or more alkylhydroxyphenylalkanoyl hydrazines and one or more defined functionalized hindered amines; and (ii) hydrocarbon cable filler grease within the interstices between said surrounded conductors.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: December 28, 1999
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Jeffrey Morris Cogen, Michael John Keogh, Geoffrey David Brown
  • Patent number: 5981065
    Abstract: An article of manufacture comprising (i) a plurality of electrical conductors, each surrounded by one or more layers of a mixture comprising one or more polyolefins and the reaction product of (a) a functionalized hindered amine amic acid hydrazide and (b) a functionalized hindered phenol or a functionalized hindered amine hydrazide and (ii) hydrocarbon cable filler grease within the interstices between said surrounded conductors.
    Type: Grant
    Filed: May 26, 1992
    Date of Patent: November 9, 1999
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Michael John Keogh, Geoffrey David Brown
  • Patent number: 5442018
    Abstract: A process for producing polyethylene having a broad molecular weight distribution is provided, in which ethylene and optionally a comonomer are contacted in two reactors connected in series, one reactor containing a titanium-based catalyst and the other reactor containing a vanadium-based catalyst and a halohydrocarbon promoter, or alternatively, both reactors containing a mixed metal catalyst comprising both titanium and vanadium. In the latter case, the halohydrocarbon promoter is present in only one of the reactors to activate the vanadium sites of the catalyst and deactivate the titanium sites of the catalyst simultaneously.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: August 15, 1995
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Kevin J. Cann, James W. Nicoletti, Frederick J. Karol, Arthur E. Marcinkowsky, Thomas E. Spriggs, Mark C. Hwu
  • Patent number: 5155145
    Abstract: A polymer impurity deactivator comprising a metal hydroxide, a hydrotalcite, or another metal oxide compound, or mixtures thereof, each of which compounds or mixtures(i) contain at least one zinc, magnesium, or aluminum cation; and(ii) have been surface treated, or mixed, with a hydrocarbon based or siloxane based amphiphatic compound, each amphipathic compound having one or more polar groups incorporated into its molecular structure to provide a polar group frequency factor of at least about 0.01.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: October 13, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: George N. Foster, Walter T. Reichle
  • Patent number: 5153382
    Abstract: A process for extruding a thermoplastic polymer comprising:(a) introducing into an extruder a copolymer of ethylene wherein one of the copolymerized monomers has the following formula:CH.sub.2 .dbd.C[(CH.sub.2).sub.n --CH.sub.3 ]-Si(OR).sub.3wherein eachR is independently a saturated aliphatic group having 1 to 4 carbon atoms; andn is 0, 1 or 2;(b) extruding the copolymer of step (a); and, thereafter,(c) contacting the extrudate with sufficient moisture to effect crosslinking.
    Type: Grant
    Filed: April 18, 1991
    Date of Patent: October 6, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Laurence H. Gross, Jeffrey D. Umpleby
  • Patent number: 4707520
    Abstract: Water-curable compositions, based on thermoplastic polymers having pendant thereto hydrolyzable silane moieties and metal carboxylate silanol condensation catalysts, which can be water cured in a relatively short period of time to crosslinked products characterized by an excellent balance of commercially acceptable properties. The compositions of this invention are particularly useful as extrudates about wires and cables.
    Type: Grant
    Filed: August 21, 1985
    Date of Patent: November 17, 1987
    Assignee: Union Carbide Corporation
    Inventor: Michael J. Keogh