Patents Represented by Attorney, Agent or Law Firm S. R. Bresch
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Patent number: 6228917Abstract: A composition comprising: (a) polyethylene; (b) as a scorch inhibitor, 4,4′-thiobis(2-methyl-6-t-butylphenol); 2,2′ thiobis(6-t-butyl-4-methylphenol); or mixtures thereof; (c) optionally, a cure booster; and (d) an organic peroxide.Type: GrantFiled: June 16, 1998Date of Patent: May 8, 2001Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Michael John Keogh
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Patent number: 6143843Abstract: A process comprising contacting one or more monomers with a catalyst, in the gas phase, under polymerization conditions, in a fluidized bed reactor, with the proviso that the reactor is at least partially cooled internally by the vaporization of a liquid cryogen directly into the reactor.Type: GrantFiled: January 22, 1999Date of Patent: November 7, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Saul R. Bresch
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Patent number: 6136748Abstract: A catalyst composition for the polymerization of olefins is provided, which comprises a) a catalyst comprising a metal atom complexed with a non-cycloalkadienyl anionic ligand, wherein the chemical hardness, .eta., and chemical potential, .mu., of said non-cycloalkadienyl anionic ligand calculated using the MOPAC (PM3) computer program satisfy the relationship: .eta.=3.0+0.75.mu..+-.0.2 eV; and b) an activating cocatalyst.Type: GrantFiled: June 12, 1998Date of Patent: October 24, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Jack Allen Smith
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Patent number: 6136747Abstract: A mixed catalyst composition comprising a) a solid Ziegler-Natta catalyst; b) a liquid single site catalyst; and c) at least one activating cocatalyst is provided. Polymers having a broad or bimodal molecular weight distribution may be made with this catalyst composition.Type: GrantFiled: June 19, 1998Date of Patent: October 24, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Sun-Chueh Kao, Frederick John Karol, Paul Theodore Daniell, Gregory Mark Goode
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Patent number: 6114475Abstract: There is provided a process for drying a fluidized reactor system comprising introducing a boiling point depressing agent into said system optionally while heating said system.Type: GrantFiled: April 6, 1998Date of Patent: September 5, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Mark Gregory Goode, Eldon Ronald Larsen, Hemal Ranchhod Patel, Jeffery Scott Bradley
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Patent number: 6096676Abstract: A catalyst precursor having the formula: ##STR1## wherein M is a Group IVB metal; each L is a monovalent, bivalent, or trivalent anion;X and Y are each heteroatoms;each Cyclo is a cyclic moiety;each R.sup.1 is a group containing 1 to 50 atoms selected from the group consisting of hydrogen and Group IIIA to Group VIIA elements, and two or more adjacent R.sup.1 groups may be joined to form a cyclic moiety;each R.sup.2 is a group containing 1 to 50 atoms selected from the group consisting of hydrogen and Group IIIA to Group VIIA elements, and two or more adjacent R.sup.2 groups may be joined to form a cyclic moiety;W is a bridging group; andeach m is independently an integer from 0 to 5.Type: GrantFiled: June 18, 1998Date of Patent: August 1, 2000Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Rex Eugene Murray
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Patent number: 6007913Abstract: An article of manufacture comprising (i) a plurality of electrical conductors, each surrounded by one or more layers of a composition comprising (a) one or more polyolefins and, blended therewith, (b) a mixture containing one or more alkylhydroxyphenylalkanoyl hydrazines and one or more defined functionalized hindered amines; and (ii) hydrocarbon cable filler grease within the interstices between said surrounded conductors.Type: GrantFiled: April 17, 1998Date of Patent: December 28, 1999Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Jeffrey Morris Cogen, Michael John Keogh, Geoffrey David Brown
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Patent number: 5981065Abstract: An article of manufacture comprising (i) a plurality of electrical conductors, each surrounded by one or more layers of a mixture comprising one or more polyolefins and the reaction product of (a) a functionalized hindered amine amic acid hydrazide and (b) a functionalized hindered phenol or a functionalized hindered amine hydrazide and (ii) hydrocarbon cable filler grease within the interstices between said surrounded conductors.Type: GrantFiled: May 26, 1992Date of Patent: November 9, 1999Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Michael John Keogh, Geoffrey David Brown
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Patent number: 5442018Abstract: A process for producing polyethylene having a broad molecular weight distribution is provided, in which ethylene and optionally a comonomer are contacted in two reactors connected in series, one reactor containing a titanium-based catalyst and the other reactor containing a vanadium-based catalyst and a halohydrocarbon promoter, or alternatively, both reactors containing a mixed metal catalyst comprising both titanium and vanadium. In the latter case, the halohydrocarbon promoter is present in only one of the reactors to activate the vanadium sites of the catalyst and deactivate the titanium sites of the catalyst simultaneously.Type: GrantFiled: April 1, 1994Date of Patent: August 15, 1995Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Kevin J. Cann, James W. Nicoletti, Frederick J. Karol, Arthur E. Marcinkowsky, Thomas E. Spriggs, Mark C. Hwu
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Patent number: 5155145Abstract: A polymer impurity deactivator comprising a metal hydroxide, a hydrotalcite, or another metal oxide compound, or mixtures thereof, each of which compounds or mixtures(i) contain at least one zinc, magnesium, or aluminum cation; and(ii) have been surface treated, or mixed, with a hydrocarbon based or siloxane based amphiphatic compound, each amphipathic compound having one or more polar groups incorporated into its molecular structure to provide a polar group frequency factor of at least about 0.01.Type: GrantFiled: December 11, 1990Date of Patent: October 13, 1992Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: George N. Foster, Walter T. Reichle
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Patent number: 5153382Abstract: A process for extruding a thermoplastic polymer comprising:(a) introducing into an extruder a copolymer of ethylene wherein one of the copolymerized monomers has the following formula:CH.sub.2 .dbd.C[(CH.sub.2).sub.n --CH.sub.3 ]-Si(OR).sub.3wherein eachR is independently a saturated aliphatic group having 1 to 4 carbon atoms; andn is 0, 1 or 2;(b) extruding the copolymer of step (a); and, thereafter,(c) contacting the extrudate with sufficient moisture to effect crosslinking.Type: GrantFiled: April 18, 1991Date of Patent: October 6, 1992Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Laurence H. Gross, Jeffrey D. Umpleby
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Patent number: 4707520Abstract: Water-curable compositions, based on thermoplastic polymers having pendant thereto hydrolyzable silane moieties and metal carboxylate silanol condensation catalysts, which can be water cured in a relatively short period of time to crosslinked products characterized by an excellent balance of commercially acceptable properties. The compositions of this invention are particularly useful as extrudates about wires and cables.Type: GrantFiled: August 21, 1985Date of Patent: November 17, 1987Assignee: Union Carbide CorporationInventor: Michael J. Keogh