Patents Represented by Attorney, Agent or Law Firm Samuel B. Laferty
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Patent number: 8338558Abstract: Polymeric urethane dispersants with solubilizing polymer chains and with reactive carbon to carbon double bonds are described. The reactive double bonds facilitate molecular weight build-up of the dispersant on dispersed particles (enhancing colloidal stability) or enhance the ability of the dispersants to be crosslinked into a matrix material.Type: GrantFiled: June 1, 2006Date of Patent: December 25, 2012Assignee: Lubrizol Advanced Materials, Inc.Inventors: Stuart N. Richards, Andrew J. Shooter
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Patent number: 8268925Abstract: The invention relates to a graft copolymer with a polyester side chain and at least one quaternised tertiary amine group. The tertiary amine may be aliphatic, aromatic or heterocyclic. The invention further relates to the use of the compound as a dispersant, particularly for pigments.Type: GrantFiled: May 23, 2008Date of Patent: September 18, 2012Assignee: Lubrizol LimitedInventors: Stuart N. Richards, Andrew J. Shooter
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Patent number: 8242205Abstract: A novel method of preparing an aqueous dispersion of non-uniform polyurethane particles which comprises (a) preparing at least two isocyanate-terminated polyurethane prepolymers having different hydrophilicities; (b) preparing a uniform mixture of said prepolymers, and (c) dispersing the mixed prepolymers in an aqueous medium. The resulting dispersion of the prepolymers may optionally be chain extended. This method enables the preparation of core-shell particles as well as particles of other morphologies, including “raspberry”, interpenetrating network, “salt-and-pepper”, “ice-cream cone” and particles of gradient composition. Similarly, an aqueous dispersion of two different polyurethane polymers may be obtained by first preparing at least two different isocyanate-terminated polyurethane prepolymers, preparing a uniform mixture of such prepolymers and thereafter dispersing the mixture in an aqueous medium.Type: GrantFiled: August 24, 2009Date of Patent: August 14, 2012Assignee: Lubrizol Advanced Materials, Inc.Inventors: Alexander V. Lubnin, Dennis Malaba, Vic Stanislawczyk, Gary D. Calhoun
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Patent number: 8168713Abstract: The present invention provides a dispersant of Formula (1): E-O—(Y)x-T-NR?-A-Z—W0-v, and salts thereof, wherein E is R or R—NR?-T-; R is H or C1-50-optionally substituted hydrocarbyl; R? is a residue of an optionally substituted alkyl (meth)acrylate or (meth)acrylamide, or a residue of an epoxide, or a C1-8-optionally substituted hydrocarbyl group; Y is C2-4-alkyleneoxy; T is C2-4 alkylene; A is the residue of a dibasic acid or anhydride thereof; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof; x is from 2 to 90; and v represents an integer variable. The invention further provides a composition comprising a particulate solid, an organic medium and/or water and the dispersant.Type: GrantFiled: May 1, 2006Date of Patent: May 1, 2012Assignee: Lubrizol LimitedInventor: Dean Thetford
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Patent number: 8167992Abstract: A composition comprising a particulate Solid, an organic medium and a compound with an alkyleneoxy compound with an inorganic acidic polar head group (Z), wherein the compound is defined by Formula (1) and salts thereof: U—(Y)x-T-N(G)r(B—Z)q (Formula 1) wherein U is independently R?—N—(C)-T?-O—, or R—O—; R or R? may be the same or different and are independently H or C1-50-optionally substituted hydrocarbyl, or hydrocarbonyl group (acyl group), or the residue of an epoxide, or the residue of an optionally substituted (meth) acrylic ester or amide group; Y is C2-4-alkyleneoxy; T or T? is independently C2-4 alkylene; B is an alkylene group, such as, methylene; Z is an inorganic acidic polar head group, such as, a sulphur or phosphorus acidic polar head group; G and G? may be the same or different and are independently H or C1-50-optionally substituted hydrocarbyl or C1-50-optionally substituted hydrocarbyl or hydrocarbonyl group or the residue of an epoxide, or the residue of an optionally substituted (meth) acType: GrantFiled: December 14, 2006Date of Patent: May 1, 2012Assignee: Lubrizol LimitedInventors: Dean Thetford, Patrick J. Sunderland, Neil L. Simpson
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Patent number: 8133914Abstract: The invention relates to novel compounds containing a carboxylic acid head group. The invention further provides compositions containing the novel compounds, a particulate solid and an organic medium or water.Type: GrantFiled: September 7, 2007Date of Patent: March 13, 2012Assignee: Lubrizol LimitedInventor: Dean Thetford
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Patent number: 8133961Abstract: This invention relates to waterborne coatings with enhanced early water blushing resistance, chemical resistance, and adhesion to substrates. These waterborne coatings can be paints, varnishes, and water sealers that offer excellent early water blushing as well as excellent resistance to common household chemicals, such as gasoline, motor oil, brake fluid, transmission fluid, household cleaners, window cleaning fluids, antifreeze, and the like.Type: GrantFiled: December 9, 2008Date of Patent: March 13, 2012Assignee: Lubrizol Advanced Materials, Inc.Inventors: Shui-Jen Raymond Hsu, Elizabeth Blankschaen
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Patent number: 8123823Abstract: The present invention provides a dispersion composition containing (a) a metal base selected from the group consisting of: (i) a metal hydroxide with a solids content of greater than about 51 wt % of the composition; (ii) a metal base other than a metal hydroxide with a solids content of greater than about 15 wt % of the composition; and (iii) mixtures thereof; (b) a surfactant; and (c) an organic medium containing less than about 2 wt % of water. The invention further provides a process for preparing the composition and a method for its use.Type: GrantFiled: March 31, 2005Date of Patent: February 28, 2012Assignee: The Lurbizol CorporationInventors: David Hobson, Benjamin Boulay, Alexander F. Psaila
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Patent number: 8076409Abstract: The present invention provides a dispersant and compositions thereof. The dispersant is a residue of a non-aromatic hydrocarbyl substituted carboxylic acid containing three or more acid groups (A), wherein the dispersant may be represented by the Formula and salts thereof: [U—(Y)x-T-N(R1)c-A]d-Z(Q1)j-Wc, wherein the variables are defined herein.Type: GrantFiled: December 5, 2006Date of Patent: December 13, 2011Assignee: Lubrizol LimitedInventors: Dean Thetford, Neil L. Simpson
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Patent number: 8076378Abstract: A dispersant comprising a polyester chain obtainable by polymerising a hydroxy carboxylic acid or lactone thereof such as ?-caprolactone with a cyclic alkylene carbonate such as 5,5-dimethyltrimethylene carbonate. The dispersant may be in the form of a phosphate ester where the polyester chain is reacted with a phosphating agent such as polyphosphoric acid or the polyester chain may be attached to a polyamine or polyimine such as polyethyleneimine.Type: GrantFiled: February 1, 2008Date of Patent: December 13, 2011Assignee: The Lubrizol CorporationInventor: Dean Thetford
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Patent number: 7943714Abstract: A water activated adhesive system is described that is particularly suited for applying non-paper polymeric labels to surfaces which have low moisture permeability. The adhesive system is characterized by a dry non-tacky surface that becomes tacky in less than one second when contacted with a water-based activator. While it is a water activated adhesive, it is also characterized after aging bonded to a substrate by resistance to adhesive failure during 72 hours of immersion in ice/water mixture. The adhesive is beneficial to allow use of existing paper labeling equipment with polymeric labels.Type: GrantFiled: September 13, 2007Date of Patent: May 17, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventors: Lawrence J. Schnieders, Alexander V. Lubnin
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Patent number: 7931972Abstract: Acrylate latexes are described which provide properties of good balance of moderate elongation, low dirt pick up, alkaline resistance, UV light resistance, and efflorescence resistance for masonry coatings. These latexes have a large portion of repeating units from C8-C12 alcohol esters of acrylic acid and/or vinyl versatates along with 5-15 weight percent of repeating units from acrylonitrile. They have a glass transition temperature of ?50 to +10° C.Type: GrantFiled: April 20, 2007Date of Patent: April 26, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventors: Shui-Jen Raymond Hsu, Elizabeth Blankschaen
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Patent number: 7928169Abstract: A CPVC composition having good impact and heat stability includes a siloxane-acrylic copolymer impact modifier and an aluminosilicate zeolite, and a reduced amount of a liquid stabilizer such as a tin compound. Such compositions can be formed into piping for indoor and outdoor water systems including hot water.Type: GrantFiled: April 14, 2008Date of Patent: April 19, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventors: Girish T. Dalal, Ann Giovannitti-Jensen, Theodore J. Schmitz, David A. Wendell, Mark D. Julius, Robert S. Newby
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Patent number: 7919190Abstract: The disclosed invention relates to a composition, comprising: (A) at least one halogen-free polymer, the polymer exhibiting a total loss of mass of at least about 7% by weight at a temperature of 370° C. when subjected to thermogravimetric analysis; (B) at least one acid source; (C) at least one carbon-yielding source; and (D) at least one blowing agent.Type: GrantFiled: November 8, 2005Date of Patent: April 5, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventors: Ioan Marcu, Pravinchandra K. Shah, Scott T. Cornman, Stephan A. Horvath, Jerry D. Church, Donald L. Reeves
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Patent number: 7910635Abstract: The specification describes a process for making gelled ink resins which exhibit improved properties such as lower viscosity under low shear and less viscosity decrease with increasing shear. In a preferred embodiment, a rosin-based or hydrocarbon-based resin is mixed with an organic solvent and reacted with a polyamine reactant, such as melamine-formaldehyde resin or hexamethylene diamine, under conditions sufficient to produce a substantially covalently cross-link gelled resin. The resulting gelled resin resists viscosity breakdown under high shear conditions and may be used directly for making ink compositions, obviating the need for further gelation and avoiding the use of conventional organo-metallic gelling agents.Type: GrantFiled: October 14, 2006Date of Patent: March 22, 2011Assignee: Lubrizol Advanced Materials, Inc.Inventors: John H. Larsen, Joshua M. Rosenheck, Robert E. Quinn
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Patent number: 7872070Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof Formula 1 wherein R is H or C1-30-optionally substituted hydrocarbyl; or R may be R?C?O (an acyl group where R? is hydrogen, alkyl, aryl or an optionally substituted alkyl or aryl); U is oxygen, —NH or —NR??; R?? is a C1-30-optionally substituted hydrocarbyl Y is C2-4-alkyleneoxy; T is the residue of substituted acetic acid or propionic acid; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof, or mixtures thereof; x is from 2 to 90; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group R—U—(Y)x-T-.Type: GrantFiled: December 6, 2005Date of Patent: January 18, 2011Assignee: Lubrizol LimitedInventor: Dean Thetford
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Patent number: 7857899Abstract: An emulsion composition comprises water, a hydrocarbon distillate having a boiling point of 215 to 325° C., and a surfactant having a hydrophilic lipophilic balance number of 10 or less. A vehicle composition, an ink composition, a lithographic printing process and a method to improve a lithographic printing process comprise the emulsion composition which when used in a lithographic printing ink can reduce emission of volatile organic compounds and reduce the time at start-up to establish print quality.Type: GrantFiled: May 20, 2005Date of Patent: December 28, 2010Assignee: The Lubrizol CorporationInventors: John J. Mullay, John H. Larsen, Joshua M. Rosenheck, George A. Malchow, Jr., Robert A. Pollack, Harshida C. Dave
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Patent number: 7795183Abstract: The present invention provides a method of asphaltene control in a hydrocarbon fluid, the method employing a composition comprising: a dispersant of formulae (I) or (II), including salts thereof, wherein T or T? is hydrogen or a polymerizing terminating group; A is C16-20 alkylene or alkenylene group; B is C10-20 alkylene or alkenylene group; Z and Z? are the residue of a polyamine or polyimine; n is 2 to 50; m is 0 to 25; p and p? are 2 or more, in one embodiment not greater than 2000 and in another embodiment not greater than 1000; A? is C8-20 alkylene or alkenylene group; n? is 2 to 10; and the weight ratio of T-(O-A-CO)n (O—B—CO)m to Z or T?-(O-A?-CO)n to Z? is at least 5:1.Type: GrantFiled: October 26, 2005Date of Patent: September 14, 2010Assignee: The Lubrizol CorporationInventors: Mark F. Wilkes, Mark C. Davies
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Patent number: 7767750Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof; wherein R is C1-50-optionally substituted hydrocarbyl; Y is C2-4-alkyleneoxy; T is C2-4 alkylene; A is the residue of a dibasic acid or anhydride thereof; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof; x is from 2 to 60; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group RO—(Y)x-T-NH-A-. The invention further discloses the composition as a dispersant for an organic media.Type: GrantFiled: July 14, 2004Date of Patent: August 3, 2010Assignee: The Lubrizol CorporationInventor: Dean Thetford
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Patent number: 7743615Abstract: A formate salt based heat transfer fluid having a pH containing a phosphate for a secondary refrigeration loop is disclosed. The formate based heat transfer fluid generally is a more effective heat transfer medium than a glycol based fluid designed to operate in the same temperature range. The formate based fluid also has lower toxicity and environmental risks than the glycol fluid.Type: GrantFiled: February 17, 2004Date of Patent: June 29, 2010Assignee: The Lubrizol CorporationInventors: Gilbert R. Malone, Stephen H. Stoldt