Abstract: A decanter centrifuge including a discontinuous screw conveyor having flights only within the generally cylindrical portion of the centrifuge bowl. A restricting disc is provided adjacent to the heavy phase material discharge ports such that the restriction contacts the build-up of heavy phase within the portion of the bowl where the flights are discontinuous.
Abstract: 1,1-Dichloro-1-fluoroethane and 1-chloro-1,1-difluoroethane are prepared from the liquid phase fluorination of 1,1,1-trichloroethane by HF in the presence of a homogenous catalyst. 1,1-Dichloro-1-fluoroethane or 1-chloro-1,1-difluoroethane are selectively produced substantially free of vinylidene chloride.