Abstract: An ultra-high solids coating composition is disclosed. The composition comprises a polyol blend of a liquid acrylic polyol and a resinous polyol. The polyol blend is crosslinked with a multifunctional isocyanate, melamine, or silane to form a variety of coatings. The coating composition has a significantly higher solid % than that is formulated from a single resin that has similar composition of the combination of the polyol blend. The coatings include less than about 35% by weight of an organic solvent.

Abstract: An ultra-high-molecular-weight polyethylene (UHMWPE) is disclosed. The UHMWPE has a weight average molecular weight (Mw) greater than about 3,000,000 and molecular weight distribution less than about 5. A process for making the UHMWPE is also disclosed. The process is performed with a heteroatomic ligand-containing single-site catalyst in the presence of a non-alumoxane activator, but in the absence of an &agr;-olefin, an aromatic solvent, and hydrogen.

Abstract: A gas phase copolymerization of ethylene is disclosed. The process uses a supported single-site catalyst that contains a heteroatomic ligand and produces polyethylene that has a reduced density. Suitable heteroatomic ligands include boraaryl, azaborolinyl, pyridinyl, pyrrolyl, indolyl, carbazolyl and quinolinyl.

Abstract: A moisture-cure urethane composition is disclosed. The urethane is formulated from an NCO-terminated alkoxylated phenolic resin that has long oxyalkylene chains. It has greater than 70 wt % solids and has excellent resistance to acids, bases, and chemicals.

Abstract: A continuous process for making a comb-branched copolymer of an acrylic monomer and a polyether macromonomer is disclosed. The process is performed by continuously feeding a reaction zone with a monomer stream that contains an acrylic acid and a polyether macromonomer, and an initiator stream. The comb-branched copolymer made thereby performs better as water reducing agent in cement compared to that made by a batch process.

Abstract: An additive for distillate fuels and a fuel composition having improved wax anti-settling properties. The additive is incorporated into a major proportion of distillate fuel and is a maleic anhydride &agr;-olefin copolymer or a imide having the following structure wherein R has at least 60% by weight of a hydrocarbon substituent from about 20 to about 40 carbon atoms, X is oxygen or wherein N is nitrogen and R′ has at least 80% by weight of a hydrocarbon substituent having from 16 to 18 carbon atoms, and n is from about 2 to about 8 for the maleic anhydride &agr;-olefin copolymer and from about 1 to about 8 for the imide. The additive can be combined with an ethylene vinyl acetate copolymer, ethylene vinyl acetate isobutylene terpolymer, or combinations thereof, to improve cold flow of the distillate fuel.

Abstract: An additive combination for distillate fuels and a fuel composition having improved cold flow properties. The additive combination is incorporated into a major proportion of distillate fuel and is comprised of an ethylene vinyl acetate isobutylene terpolymer in combination with one or more of a maleic anhydride &agr;-olefin copolymer component, a polyimide component, and an alkyl phenol component each having one or more hydrocarbon substituents within specified carbon number ranges. Optionally, an ethylene vinyl acetate copolymer may also be incorporated as a component therein.

Abstract: An ethylene polymerization catalyst and catalyst system which produces ethylene copolymers having unique melt elastic properties at high catalytic activity. The catalyst is produced by the steps which include contacting silica having a surface area of between above about 500 m2/g and about 800 m2/g, a particle size in the range of between about 10 microns and about 200 microns and a pore volume of between about 0.5 cc/g and about 3.0 cc/g with an organosilicon compound. This product is contacted with a dialkylmagnesium compound or complex. The product of this step, in turn, is contacted with an alcohol or silane compound. Finally, the thus formed product is contacted with a transition metal compound.

Abstract: Improved adhesives useful for the manufacture of composite structures by lamination, extrusion and coextrusion processes are provided. The compositions of the invention utilize ethylene copolymers having a network structure and exhibiting unique melt elasticity characteristics in combination with modified polyolefins containing acid or acid derivative functionality and, optionally, elastomeric polymers. Composite structures wherein the adhesives are adhered to one or more substrates and, particularly composite structures comprising metal or barrier resin layers with one or a plurality of crosslinked or uncrosslinked polyethylene resin layers, are also described.

Abstract: The present invention provides an ethylene copolymer resin that has unique melt elastic properties not observed in ethylene copolymers heretofore known. Specifically, the ethylene copolymer resin of the present invention when in pelletized form has a reduction in melt elasticity (ER) of 10% or more to a final value of 1.0 or less upon rheometric low shear modification or solution dissolution. Moreover, the resin of the present invention when in reactor-made form exhibits at least a partially reversible increase of 10% or more in ER when pelletizing the same. An ethylene polymerization catalyst, a process of preparing the ethylene copolymer resin and a high-impact film are also provided herein.

Abstract: A process for making hydroxy-functional resins based on acrylate, hydroxyalkylacrylate, and allyl monomers is disclosed. The key to the process is to add the hydroxyalkylacrylate monomer in an amount and manner effective to produce a resin that contains, without vacuum stripping, less than about 1 wt. % of residual unreacted allyl monomers. Eliminating the need to vacuum strip the allyl monomer reduces process costs and enables the synthesis of new resins. The hydroxy-functional resins are readily crosslinked with melamines, polyisocyanates, or epoxies to give thermoset polymers.

Abstract: An additive for distillate and a fuel composition having improved cloud point depressant properties. The additive is incorporated into a major proportion of distillate fuel and is a maleic anhydride .alpha.-olefin copolymer or a polyimide having the following structure: ##STR1## wherein R has at least 80% by weight of a hydrocarbon substituent from about 14 to about 16 carbons, X is oxygen or ##STR2## wherein N is nitrogen and R' has at least 80% by weight of a hydrocarbon substituent from 16 to 18 carbons, and n is from about 2 to about 30 when X is oxygen, and from about 2 to about 17 when X is ##STR3## Alternatively, the cloud point additive can be an ethylene vinyl acetate isobutylene terpolymer.

Abstract: A multiple stage or multiple zone process for making olefin polymers is disclosed. A single-site catalyst, preferably one that contains a heteroatomic ligand, is used in the first stage or zone, and a Ziegler-Natta catalyst is used at a higher temperature in later stages or zones. A parallel multiple zone process is also described. The processes, which can be performed adiabatically, give polymers with improved thermal processing ability.

Abstract: Allylic copolymer resins and processes for making them are disclosed. The resins are made by copolymerizing an ethylenic monomer, a monofunctional allyl monomer, and a multifunctional allyl monomer under free-radical conditions. The multifunctional allyl monomer is used in an amount and manner effective to give a copolymer resin having a polydispersity (Mw/Mn) within the range of about 5 to about 30. The resins, which are easy to make with even bulk polymerization, are particularly valuable, for example, as toner resins, thermoset resins, reactive plasticizers, and rheology modifiers.