Patents Represented by Attorney, Agent or Law Firm Shlomo R. Frieman
  • Patent number: 6255256
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about −30° C. (−22° F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: December 8, 1998
    Date of Patent: July 3, 2001
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 6159907
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: December 12, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 6110874
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: August 29, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 6107255
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: August 22, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 6034037
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: March 7, 2000
    Assignee: Union Oil Company of California,
    Inventor: Donald C. Van Slyke
  • Patent number: 6017854
    Abstract: Simplified drilling fluids (and other well bore fluids) contain a non-aqueous-base fluid and a viscosifying/fluid loss agent that meets certain performance criteria.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: January 25, 2000
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5979556
    Abstract: A method for continuously acidizing a geological rock formation for at least 3 months comprising adding a dilute acid to a geothermal carrier fluid in a concentration less than 0.1 weight percent to produce an acidified fluid and continuously contacting the rock formation with the acidified fluid until the permeability of the formation is increased.
    Type: Grant
    Filed: July 25, 1996
    Date of Patent: November 9, 1999
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, Tim G. Rossknecht
  • Patent number: 5965031
    Abstract: Sulfurous acid and/or sulfurous acid precursors, such as sulfur dioxide, are introduced into a hydrogen sulfide-containing geothermal brine or fluid prior to extracting energy from the resulting mixture by, e.g., passing the mixture through a flash vessel or a heat exchanger. The introduction of the sulfurous acid or its precursors into the geothermal brine or fluid inhibits scale formation and/or removes previously formed scale during processing of the brine or fluid.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: October 12, 1999
    Assignee: Union Oil Company of California
    Inventors: Kevin R. Kitz, Darrell L. Gallup
  • Patent number: 5958845
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 90 weight percent total paraffins, (v) about 1 or less weight percent naphthenics, (vi) less than 0.1 volume percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: September 28, 1999
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5957203
    Abstract: Cationic polymer-containing gels are stable at elevated temperatures in soft and hard waters.
    Type: Grant
    Filed: November 30, 1994
    Date of Patent: September 28, 1999
    Assignee: Union Oil Company of California
    Inventors: Richard D. Hutchins, Hoai T. Dovan, Burton B. Sandiford
  • Patent number: 5879433
    Abstract: One or more contaminants selected from the group consisting of acidic gases, inert particulates, and mixtures thereof are removed from steam by contacting the contaminated steam with a nonaqueous sorbent such as crystalline molecular sieves, silica gels, soda ash, carbonaceous adsorbents, and amine liquid ion exchange resins.
    Type: Grant
    Filed: July 31, 1997
    Date of Patent: March 9, 1999
    Assignee: Union Oil Company of California
    Inventors: Darrell L. Gallup, Thomas S. Powell
  • Patent number: 5858245
    Abstract: A method for controlling fouling of a production or reinjection well, a flashing vessel or a heat-exchange surface exposed to a high-enthalpy geothermal brine that forms metal/silicon-containing scale comprises the addition of a metal complexing agent to the brine to form a fluid mixture containing a soluble metal/silicon component complex that inhibits the amount of scale formation when the temperature of the fluid mixture is reduced. The addition of a preferred metal complexing agent such as forms of EDTA, citric acid or acetic acid maintains dissolved aluminum species in the brine and inhibits the formation of aluminum silicate precipitate.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: January 12, 1999
    Assignee: Union Oil Company of California
    Inventor: Darrell L. Gallup
  • Patent number: 5788781
    Abstract: A method for cleaning oil-contaminated substrates employing a composition includes a diluent oil, a first surfactant having a HLB value of at least 10, and a second surfactant having a higher HLB value. The difference in the HLB values of the first and second surfactants is at least 3 and a mixture of the surfactants would have a HLB value of at least 11.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: August 4, 1998
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5780407
    Abstract: Compositions comprising (a) a surfactant and (b) a diluent oil are employed in oil-based drilling fluids and processes for cleaning oil-contaminated substrates (e.g., oil-contaminated animals, drill cuttings) as well as in processes for cementing well casings, enhanced oil recovery, and lifting oil from wellbores.
    Type: Grant
    Filed: June 26, 1997
    Date of Patent: July 14, 1998
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5762141
    Abstract: Cationic polymer-containing gels are stable at elevated temperatures in soft and hard waters.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: June 9, 1998
    Assignee: Union Oil Company Of California
    Inventors: Richard D. Hutchins, Hoai T. Dovan, Burton B. Sandiford
  • Patent number: 5723423
    Abstract: Compositions comprising (a) a surfactant and (b) a diluent oil are employed in oil-based drilling fluids and processes for cleaning oil-contaminated substrates (e.g., oil-contaminated animals, drill cuttings) as well as in processes for cementing well casings, enhanced oil recovery, and lifting oil from wellbores.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: March 3, 1998
    Assignee: Union Oil Company of California, dba UNOCAL
    Inventor: Donald C. Van Slyke
  • Patent number: 5710111
    Abstract: Solids-free, essentially all-oil and invert emulsion wellbore fluids are employed in well drilling, completion, and workover operations. Techniques for remediating dense aromatic solvents wellbore fluids entail removal and/or dissolution of particulate matter.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: January 20, 1998
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5700763
    Abstract: Oil-base drilling fluids containing a non-sulfonated polymer and/or a non-organophilic clay maintain desirable rheological properties at elevated temperatures.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: December 23, 1997
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5696058
    Abstract: A solids-free, essentially all-oil wellbore fluid comprises an organic fluid having (i) a melting point less than about 20.degree. C. (about 68.degree. F.), (ii) a flash point greater than about 54.4.degree. C. (about 130.degree. F.), and (iii) a dipole moment greater than 0 debye (D) and/or an aromatic solvent having a density at about 15.6.degree. C. (60.degree. F.) of at least about 0.9 g/ml (7.5 pounds per gallon (ppg)), a flash point of greater than about 54.4.degree. C. (130.degree. F.), a solubility in water at about 25.degree. C. (77.degree. F.) of less than about 1 weight percent, a solubility in benzene at about 25.degree. C. (77.degree. F.) of at least about 80 weight percent, and a pour point of less than about 15.6.degree. C. (60.degree. F.). Generally, a salt is dissolved in the organic fluid. The wellbore fluid is employed in well drilling, completion, and work-over operations.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: December 9, 1997
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke
  • Patent number: 5635457
    Abstract: A non-toxic, inexpensive synthetic fluid for use in wellbore fluids (e.g., drilling fluids) is selected from the group consisting of (A) fluids having (I) a pour point greater than about -30.degree. C. (-22.degree. F.) and (II) a cetane index greater than 50, and comprising (i) at least about 95 weight percent hydrocarbons containing 11 or more carbon atoms, (ii) greater than 5 weight percent hydrocarbons containing 18 or more carbon atoms, (iii) at least about 50 weight percent isoparaffins, (iv) at least about 80 weight percent total paraffins, (v) less than 10 weight percent naphthenics, (vi) less than 0.1 weight percent aromatics, and (vii) at least 2 hydrocarbons containing a consecutive number of carbon atoms, and (B) fluids comprising (i) at least about 95 weight percent hydrocarbons containing 10 or more carbon atoms and (ii) at least about 90 weight percent n-paraffins.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: June 3, 1997
    Assignee: Union Oil Company of California
    Inventor: Donald C. Van Slyke