Abstract: Partially epoxidized compounds obtained from Diels Alder adducts of dicyclopentadiene with fatty oils having a iodine number of 70 or greater and their transesterification products with C.sub.1 to C.sub.10 alkanols are disclosed. 100% solids radiation and heat curable coating compositions containing the epoxidized compounds and/or their transesterification products are also disclosed.
Type:
Grant
Filed:
October 23, 1997
Date of Patent:
September 7, 1999
Assignee:
Elf Atochem North America, Inc.
Inventors:
Fred Budde, Mohammed R. Kazemizadeh, Walter P. Kosar, Jr.
Abstract: An uncatalyzed liquid phase process is provided for the preparation of oligomer free 1233zd via the fluorination of 1230za with a high molar excess of HF. The 1233zd is a known intermediate useful for preparing 245fa.
Abstract: A novel and safe ethylenically unsaturated peroxyester composition derived from an ethylenically unsaturated dicarboxylic acid is provided, as well as processes for making and using the composition. The peroxyester composition comprises about 0.04 to about 0.70 mole fraction of a first component compound having a formula I: ##STR1## about 0.32 to about 0.50 mole fraction of a second component compound having a formula II: ##STR2## about 0.04 to about 0.70 mole fraction of a third component compound having a formula III: ##STR3## wherein Q is an unsaturated ethylene divalent radical and R.sup.1 and R.sup.2 are organic substituents. Polymeric-peroxides are prepared via polymerizing the peroxyester compositions. The peroxyester compositions are also used for curing unsaturated polyester resins and for initiating polymerization of ethylenically unsaturated monomers.