Abstract: A three layer heat shrinkable film is disclosed, along with preferred process for making it. The film comprises a first heat sealable layer of an ionomer, a second layer of a vinylidene chloride copolymer, and a third layer of a blend of an ionomer and an EVA copolymer. The EVA content is no greater than 20% of the blend by weight, and the vinyl acetate content is at least 4.5% of the blend by weight. In the preferred process, a three layer tape is coextruded and cooled, and reheated to 197.degree.-203.degree. F., and oriented in a conventional double bubble process.

Abstract: A novel coextruded plastic film has, as an adhesive layer between polypropylene and nylon layers, a blend of polypropylene and a graft copolymer of maleic anhydride onto an olefin polymer or copolymer, the adhesive blend containing from about 0.005% to 0.75% maleic anhydride based on the total weight of the entire blend composition.

Abstract: A laminate web, suitable for conversion into a container for degenerative products, is produced from aluminum foil and an extrusion coating of an ethylene/acrylic acid-type copolymer, utilizing a polyacrylic acid chromium complex primer to enhance the bond at the interface. The laminate web will usually be formed into a tube with the copolymer disposed on the product side, which can advantageously be used to package fluoride toothpaste, and the like.

Abstract: Molecularly oriented plastic films have five molecularly oriented layers. A first layer provides a barrier to gaseous transmission through the film and has a composition of 0% to 50% nylon or nylon copolymer, and conversely 50% to 100% ethylene vinyl alcohol. Second and third adhesive layers are adhered to the surfaces of the first layer, and have compositions comprising olefinic polymers, or copolymers, or blends thereof, the compositions having carboxyl modifications therein. Fourth and fifth layers are adhered to the second and third layers on the respective surfaces opposite the first layer. The fourth and fifth layers comprise 40% to 100% ethylene vinyl acetate and 0% to 60% linear low density polyethylene. Also disclosed are processes for making the oriented five layer films.

Abstract: This disclosure includes a means by which a precoating for a metal plate can be made to withstand stresses imposed upon it and the plate during forming operations such as stretching and drawing by first adding a dry film lubricant to the coating. The lubricant has a softening point as high or higher than the coating.

Abstract: A laminated packaging material suitable for use in flexible containers for potato chips, cookies, and the like comprises (A) as an outer layer, a transparent sheet of nylon coated on its inner surface with an acrylic latex, (B) a coextruded laminate of pigmented polyethylene and ethylene acrylic acid copolymer, (C) a metallic foil, preferably aluminum, and (D) a heat-sealable polyolefin as the inner layer. This packaging material not only prints well but also can be formed by co-extrusion lamination to achieve excellent lamination bond strength. Bags prepared from this packaging material have excellent moisture resistance and sealing properties.

Abstract: An EVOH copolymer blend is extrudable to produce films of uniform caliper and excellent oxygen barrier properties. Aromatic sulfonamides are desirably utilized as plasticizers, and superior composite films including a layer of the plasticized EVOH are produced.

Abstract: A novel coextruded plastic film has as an adhesive layer between polypropylene and nylon layers, a blend of polypropylene and a graft copolymer of maleic anhydride onto a polypropylene backbone, the graft copolymer having been produced in a reaction carried out at a temperature of from about 80.degree. C. up to about 10.degree. C. below the melting point of the polypropylene.

Abstract: A multiple layer polymeric-based sheet structure is suitable for forming dispensing tubes. The abuse resistance of the tube is improved by incorporating in the sheet structure a layer of oriented polypropylene. A layer of linear low density polyethylene provides for heat sealing and has substantially improved stress crack resistance and resistance to generation of polydust.

Abstract: A method and apparatus for processing of workpieces comprising the steps of continuously transferring the workpieces to and fro among a plurality of rotating members, wherein each member carries a plurality of sets of work stations. Workpieces, such as precut tubular sleeves, and tube heads, are sealed to form containers, utilizing continuously rotating turrets and cooperating rotating members designed to produce such containers efficiently and at high rate of production.

Abstract: An improved package, including an oil-containing product, includes a multiple layer packaging sheet material which is free from cockling. The multiple layer sheet material includes a layer which is susceptible to being swelled when in contact with oil, giving a cockled appearance. With reference to the package structure, the sheet material also includes an oil barrier layer between the oil-containing product and the layer which is susceptible to being swelled when in contact with oil. The barrier layer comprises either nylon or ethylene vinyl alcohol.

Abstract: A three layer heat shrinkable film is disclosed, along with preferred process for making it. The film comprises a first heat sealable layer of an ionomer, a second layer of a vinylidene chloride copolymer, and a third layer of a blend of an ionomer and an EVA copolymer. The EVA content is no greater than 20% of the blend by weight, and the vinyl acetate content is at least 4.5% of the blend by weight. In the preferred process, a three layer tape is coextruded and cooled, and reheated to 197.degree.-203.degree. F., and oriented in a conventional double bubble process.

Abstract: A plastic laminate sheet for making collapsible dispensing container comprises an outer layer of filled-plastic made of polypropylene or a blend of polypropylene, and high density polyethylene, and a filler, preferably calcium carbonate, incorporated therein. The outer filled-plastic layer is coextensively bonded to an inner layer of high density polyethylene to form the laminate sheet. An intermediate layer of an oxygen barrier plastic may be interposed in the laminate sheet in order to impart oxygen impermeability thereto.

Abstract: A multi-layer laminate structure comprises a separate layer of scrap produced from the several thermoplastic resins used in making the laminate structure. In a preferred construction, the multi-layer laminate structure comprises an outer thermoplastic polyolefin layer, an inner thermoplastic polyolefin layer and an intermediate oxygen barrier layer preferably made of ethylene-vinyl alcohol copolymer. An adhesive layer bonds the barrier layer to the inner polyolefin layer and a separate scrap layer is disposed interiorly of the outer polyolefin layer. A second adhesive layer bonds the scrap layer to the intermediate barrier layer. Containers having excellent oxygen barrier properties and good transparency are made by forming a parison from the multilayer laminate structure and blow molding the parison to the desired container shape.

Abstract: A perforated plastic film is produced by forming a pattern of light absorbing material (e.g., in dot and/or circular forms) on the film and subjecting the printed film to radiant energy from a light source in order to melt the film areas covered with the light absorbing material, thus producing a corresponding plurality of perforations in the plastic film.

Abstract: A metal container comprising a seamless body and an end wall integral therewith and having on at least its interior surface a protective coating which is the reaction product of a citric acid ester utilized as a lubricant in forming the container and an after-applied synthetic resin.

Abstract: An unbalanced polymeric film has a plurality of adjacent molecularly oriented layers. The first, second, and third layers are molecularly oriented, and are, respectively (1) polypropylene, (2) anhydride modified polypropylene and (3) a barrier layer of either ethylene vinyl alcohol or nylon or a blend of ethylene vinyl alcohol and nylon. A fourth layer is optionally oriented and serves as a heat sealable layer having good adhesion to the barrier layer. In a more sophisticated structure, the fourth layer is oriented and serves an adhesive layer between the barrier layer and a fifth sealant layer. The fifth layer is then optionally oriented. A process for making the films comprises heating the exterior surfaces of the two surface layers to a temperature between 10.degree. and 100.degree. F. below the respective heat sealing temperature of each of the respective surface layers, stretching the so-heated film, annealing the stretched film, and cooling the annealed film.

Abstract: An unbalanced multiple layer polymeric film having good interfacial adhesions has a first molecularly oriented polymeric surface layer of nylon on one surface thereof, and a second molecularly oriented polymeric surface layer of a heat sealable ethylene-based polymer or copolymer on the other surface thereof. Films are disclosed having interior functional layers of EVOH and HDPE, along with adhesive polymers selected for good interfacial adhesion after orientation of the film in the machine direction. Processes for making and orienting the films are also disclosed.

Abstract: An improved flux used for the recovery of metallic aluminum from dross in a reverberatory furnace. The flux is an alloyed mixture of sodium chloride and potassium chloride in approximately equal parts by weight which has been preheated and then cooled to form an alloyed mixture. A small amount of cryolite can be added to the liquid mixture before cooling to improve the recovery of metal obtained than when the salt and potash flux mixture is used alone.