Patents Represented by Attorney Sudhir G. Deshmukh
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Patent number: 8211970Abstract: The invention relates to aqueous pigment dispersions comprising at least one dispersed pigment, an aqueous carrier and a copolymer prepared by polymerization of at least one macromonomer (1) having a terminal olefinic unsaturation with a mixture of olefinically unsaturated monomers (2), wherein the macromonomer (1) comprises 1a) 5-100% by weight of at least one polymerized acid functional unsaturated monomer, 1b) optionally at least one polymerized hydroxy functional unsaturated monomer, and optionally 1c) at least one further polymerized olefinically unsaturated monomer, and wherein the mixture of olefinically unsaturated monomers (2) comprises 2a) 5-80% by weight of at least one unsaturated vinyl aromatic monomer, 2b) 5-50% by weight of at least one vinyl monomer with at least one polar heterocyclic group with a 5 or 6 membered ring containing at least one ring nitrogen atom which is not connected to a hydrogen atom, and optionally 2c) other olefinically unsaturated monomers.Type: GrantFiled: February 20, 2008Date of Patent: July 3, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Jozef Theresia Huybrechts, Paul P. Bruylants, Alexander K. Sorser, Michael Koerner
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Patent number: 8197905Abstract: The present invention is directed to a process of applying a solvent-based coating composition on a substrate to produce a multi-layer coating thereon. The binder component of the composition includes at least one hydroxy-functional polyether obtained from at least one polyol having at least three hydroxyl groups and at least one monoglycidyl ester of a branched monocarboxylic acid. The crosslinking component of the composition includes at least one cross-linking agent that is capable of entering into a cross-linking reaction with the hydroxyl groups of- the hydroxy-functional polyether. The process further includes curing the multi-layer coating. The process is well suited for producing clear coats and pigmented topcoats in automotive refinishing.Type: GrantFiled: September 25, 2006Date of Patent: June 12, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Jozef Theresia Huybrechts, Leen Tanghe
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Patent number: 8008394Abstract: The invention is directed to coating compositions for direct coating of plastic substrates, comprising the following components: A) a hydroxy-functional binder component, comprising at least one branched hydroxy-functional polyester having a hydroxyl value of 50-300 mg KOH/g solid, a polydispersity of <2 and a number average molecular weight (Mn) of 300 to 4000, having at least three branches, and having at least one hydroxyl group on each of the at least three branches, B) a crosslinking component for the hydroxyfunctional binder component A), C) at least one adhesion promoting component and optionally, D) organic solvents, additives conventionally found in paints as well as pigments and/or fillers.Type: GrantFiled: July 13, 2005Date of Patent: August 30, 2011Assignee: E.I. du Pont de Nemours & CompanyInventors: Wolfgang Stricker, Udo Hellmann, Yvonne Seulen, Rolf Lackmann
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Patent number: 7976903Abstract: Non-aqueous, liquid coating compositions which contain at least one epoxy-functional binder A and at least one carboxyl-functional cross-linking resin B, wherein the at least one cross-linking resin B is present as particles having a melting temperature of 40 to 180° C.Type: GrantFiled: January 26, 2007Date of Patent: July 12, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Carmen Flosbach, Karl-Friedrich Doessel, Wiebke Becker
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Patent number: 7968151Abstract: A process for the production of special effect multi-layer coatings, comprising the successive steps: (1) applying a 10 to 30 ?m thick base coat layer onto a substrate provided with an EDC primer, (2) applying a clear coat layer onto the base coat layer, (3) jointly curing the base coat and clear coat layers, wherein the base coat layer is applied in a first layer and in a second layer; the first layer comprises a modified water-borne base coat produced by mixing an unmodified water-borne base coat with an admixture component and the second layer comprises the unmodified water-borne base coat, wherein the unmodified water-borne base coat has a ratio by weight of pigment content to resin solids content of 0.05:1 to 0.6:1 and wherein the pigment content of the unmodified water-borne base coat comprises at least one metal flake pigment having a thickness of 10 to 100 nm corresponding to a proportion of 0.1 to 5 wt.Type: GrantFiled: July 8, 2005Date of Patent: June 28, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Marc Chilla, Michael Georgiadis, Volker Kegel, Gunter Richter
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Patent number: 7943197Abstract: A process for producing two-tone coated substrates, comprising the successive steps: a) providing a non-color-imparting pre-coated substrate, b) applying a color-imparting coating of Color 1 at least to one or more regions of the substrate side facing an external observer, c) curing the coating of Color 1, d) masking the desired region of the coating of Color 1, e) applying a color-imparting coating of Color 2 to the unmasked regions of the substrate side facing the external observer without deliberately curing the coating of Color 2, f) unmasking the regions masked in step d), g) applying a clear coat to the whole of the substrate side facing the external observer and h) curing the clear coat.Type: GrantFiled: January 20, 2004Date of Patent: May 17, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Frank Lieverz, Juergen Doebert
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Patent number: 7910169Abstract: Non-aqueous, liquid coating compositions which contain at least one epoxy-functional polyurethane resin A and at least one carboxyl-functional cross-linking component B, wherein the at least one epoxy-functional polyurethane resin A is present as particles having a melting temperature of 40 to 180° C.Type: GrantFiled: February 13, 2007Date of Patent: March 22, 2011Assignee: E. I. du Pont de Nemours and CompanyInventor: Carmen Flosbach
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Patent number: 7825173Abstract: A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a mixture A of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture A of 10 to 100 mg of KOH/g and 0.5 to 5 wt.Type: GrantFiled: November 15, 2005Date of Patent: November 2, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Tonnie Willems, Matthieu Barrere, Kok-Far Lee, Frank Tessari, Stefan Wiggershaus, Paul P. Bruylants, Eric C. Houze
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Patent number: 7822845Abstract: The present invention is directed to a monitoring device for producing a target composition, such as an automotive paint or an architectural paint. The device includes a client computer in communication with a host computer and means for dispensing required items for making a desired amount of the target composition. The computer readable program code means in the computers identify one or more formulas associated with identification criteria of the target composition and dispense through means for dispensing the required items listed in the formula. The code means search for the required items in the various inventories, including updating the inventories if required. The device can be also used to control the inventory by shipping just in time any components required to produce target compositions, such as refinish tints used in automotive refinish paints.Type: GrantFiled: December 29, 2004Date of Patent: October 26, 2010Assignee: E. I. du Pont de Nemours & Co.Inventors: Christine Darlene Ames Polarine, James D. Goldschneider, John Paul Gallagher, Robert Vincent Canning, Jr., James Fredrick MacFawn
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Patent number: 7714062Abstract: A powder coating composition comprising (A) at least one hydroxyl functional polyurethane resin binder, and (B) at least one polyurethane resin as cross-linking agent containing blocked isocyanate groups, wherein the at least one hydroxyl functional polyurethane resin binder (A) and the at least one polyurethane resin (B) both having a melting temperature of 60 to 180° C., in particular, 80 to 160° C.; the powder coating composition makes it possible to achieve a low melt viscosity and an excellent processability along with a good storage stability and in particular, to form thin films of the coating layers having high flexibility in combination with an excellent weather resistance.Type: GrantFiled: December 18, 2007Date of Patent: May 11, 2010Inventors: Carmen Flosbach, Kristina Iland, Tanja Renkes
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Patent number: 7700160Abstract: The invention is directed to a process for the production of a scratch-resistant vehicle coating comprising the following steps: I. applying a top coat layer of colour- and/or special effect-imparting base coat and a transparent clear coat or of a pigmented one-layer top coat onto a prior coating, II. optionally, applying a sealing layer of a transparent sealing coat onto the top coat layer applied in step I and III.Type: GrantFiled: August 24, 2006Date of Patent: April 20, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Uwe Wilkenhoener, Martin Wulf, Paer Winkelmann
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Patent number: 7662875Abstract: The invention is directed to aqueous coating compositions with improved rheology performance, comprising A) at least one water-dilutable binder, optionally, at least one cross-linking agent B), at least one sagging control agent C) obtainable by reacting a polyisocyanate with an amine, water and optionally usual coating additives, pigments and/or organic solvents, wherein the sagging control agent is obtained by reacting in an aqueous phase in presence of a water-dilutable binder C1) at least one polyisocyanate with C2) at least one amine having at least one primary amino group and at least one hydroxyl group.Type: GrantFiled: May 18, 2006Date of Patent: February 16, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Josef Huybrechts, Koen Linsen, Paul Bruylants
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Patent number: 7585924Abstract: The present invention is directed to a novel high temperature polymerization process operating at high pressures for producing a polymer. The process includes conveying hybrid reactor mixtures, which include one or more hybrid reactor monomers and one or more hybrid reactor initiators to one or more hybrid reactors. The hybrid reactors are maintained at effective hybrid polymerization temperatures and sub-reflux polymerization gage pressures to cause polymerization of a portion of the hybrid reactor monomers into the polymer. The process further includes conveying hybrid reactor contents from the hybrid reactors to one or more batch reactors maintained at effective batch polymerization temperatures and reflux polymerization pressures to cause polymerization of a remaining portion of the hybrid reactor monomers into the polymer. The hybrid reactors are smaller in volume than the batch reactors.Type: GrantFiled: July 10, 2003Date of Patent: September 8, 2009Assignee: E. I. du Pont de Nemours and CompanyInventor: Michael Charles Grady
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Patent number: 7572506Abstract: The invention relates to aqueous coating compositions for producing primer and/or filler layers in a multi-layer coating, in particular in vehicle coating, comprising the following components: A) at least one water-dilutable epoxy resin, B) at least one polyamine curing agent, C) optionally, at least one water-dilutable polyurethane resin, D) water and E) optionally, pigments, fillers, conventional paint additives and/or organic solvents, wherein the polyamine curing agent B) comprises: B1) 5-95% by weight of at least one amino functional compound with at least two secondary and/or primary amino groups and B2) 95-5% by weight of at least one water-dilutable (meth)acrylic copolymer, wherein the percentages by weight of components B1) and B2) are based on the solids and add up to 100% by weight.Type: GrantFiled: June 22, 2005Date of Patent: August 11, 2009Assignee: E. I. du Pont de Nemours and CompanyInventors: Klaus Wissing, Wilfried Collong
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Patent number: 7491419Abstract: A process for repairing a vehicle coating, comprising the following steps: I) applying a UV radiation coating composition onto a coated vehicle or vehicle part, having a blemished area on the coated surface to be repaired, wherein the coating composition comprises A) at least one free-radically polymerizable oligomeric and/or polymeric binder containing olefinically unsaturated groups, B) optionally, at least one free-radically polymerizable monomeric reactive diluent containing one or more olefinically unsaturated groups, C) at least one photoinitiator, D) at least one metal compound of a metal salt containing the metal in the cation and/or anion of the compound, organometallic compounds, metal coordination compounds and mixtures thereof, wherein the metal is from groups 13-14 of the periodic system of elements and a transition metal, and is able to occur in at least 2 oxidation states other than zero and E) optionally, water, organic solvents, pigments, fillers and/or conventional coating additives, andType: GrantFiled: January 11, 2006Date of Patent: February 17, 2009Assignee: EI du Pont de Nemours & CompanyInventors: Juergen Peter Stropp, Martin Wulf, Helmut Loeffler, Dmitry Chernyshov
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Patent number: 7470467Abstract: The invention relates to modified nanoparticles based on pyrogenic silica which are produced by treating pyrogenic silica with compounds of the general formula I Me(OR1)4, and/or of the general formula II Me(OCOR1)4, wherein R1 means an alkyl, aryl and/or aralkyl residue and Me means zirconium and/or titanium and to coating compositions containing the modified nanoparticles.Type: GrantFiled: August 24, 2006Date of Patent: December 30, 2008Assignee: E.I. du Pont de Nemours and CompanyInventors: Uwe Wilkenhoener, Martin Wulf, Paer Winkelmann
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Patent number: 7466415Abstract: The present invention is directed to a method and device that use spectral measurements of the color of a target coating on a substrate, such as auto body being matched. The method utilizes pigment mixture models to produce a matched coating composition that when applied as a coating matches in appearance with that of the target coating, while also providing other desired coating properties, such as durability, gloss and adhesion. The method of the present invention is well suited for producing automotive refinish paints used in automotive refinish applications wherein the undamaged portion of the autobody is color matched to produce a matched refinish paint that can be then applied over a repaired portion of autobody.Type: GrantFiled: May 6, 2004Date of Patent: December 16, 2008Assignee: E.I. du Pont de Nemours & CompanyInventors: Mark Alan Gibson, David Lee Griffus, Allan Blase Joseph Rodrigues, Michelle Grace Ward
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Patent number: 7395722Abstract: This invention is directed to the measurement of stress-strain relationships in thin films using substantially flat, parallel test surfaces with minimal width. This invention is further directed to the measurement of stress-strain relationships in thin films at controlled temperatures and at high strain rates above 100% per second.Type: GrantFiled: November 21, 2006Date of Patent: July 8, 2008Assignee: E.I. du Pont de Nemours and CompanyInventor: Li Lin
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Patent number: 7276288Abstract: A coating composition comprising a binder of a. polyisocyanate crosslinking agent; b. an isocyanate-reactive component having at least one compound having the following formula: wherein X is an aliphatic or cycloaliphatic group, R1 and R2 are the same or different organic groups that are inert to isocyanate groups, and n is 2 to 4, and c. optionally, a polymeric component having a number average molecular weight of 5,000 to 50,000 having reactive groups that crosslink with an isocyanate, where the reactive groups are hydroxyl, carboxyl, glycidyl, amine and any mixtures thereof; and d.Type: GrantFiled: December 16, 2003Date of Patent: October 2, 2007Assignee: E. I. du Pont de Nemours & Co.Inventors: Patrick Henry Corcoran, Joseph Norbert Weber
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Patent number: 7273530Abstract: The invention relates to a process for the production of decorative coatings, comprising the following steps: A) providing a substrate to be coated and a backing film coated on one side with an uncured or only partially cured coating of a coating composition curable by means of high-energy radiation, B) forming zones on the backing film which are opaque to high-energy radiation and correspond to the negative image of a desired pattern or decoration, C) applying the coated side of the backing film having the uncured or only partially cured coating of a coating composition curable by means of high-energy radiation with the coated side thereof onto a substrate surface, D) curing the coating applied by the backing film by irradiation with high-energy radiation through the backing film, E) removing the backing film from the coating which remains on the substrate, and F) removing the un-irradiated and thus uncured parts of the coating remaining on the substrate to obtain the desired pattern or decoration.Type: GrantFiled: April 5, 2004Date of Patent: September 25, 2007Assignee: E.I. du Pont de Nemours & CompanyInventors: Carmen Flosbach, Peter Frese, Phu Qui Nguyen, Martin Wulf