Patents Represented by Attorney T. N. Wallin
  • Patent number: 3972982
    Abstract: Fluorine compounds are removed from aqueous phosphoric acid by extraction with a mixture of a silane and a long-chain hydrocarbyl amine.BACKGROUND OF THE INVENTIONThis invention relates to a process for removing fluorine from aqueous phosphoric acid.It is known that wet-process phosphoric acid obtained by acidulation of phosphate rock contains substantial amounts of fluorine, predominantly in the form of fluorine compounds such as fluorophosphates and various metal fluorides. Even following purification by known extraction processes, for example, extraction with various organic amines, ethers, etc., such phosphoric acid generally remains contaminated with undesirably high quantities of fluorine compounds with fluorine contents of 1,000 parts per million (ppm) by weight or more not being uncommon.Fluorine contents of this magnitude introduce complications relative to the use of the acid in various applications.
    Type: Grant
    Filed: March 3, 1975
    Date of Patent: August 3, 1976
    Assignee: Monsanto Company
    Inventor: Louis F. Centofanti
  • Patent number: 3972922
    Abstract: Sequestrant compounds represented by the ##EQU1## wherein X is alkali metal or hydrogen, are prepared by oxidation of a compound represented by the formula ##EQU2##
    Type: Grant
    Filed: March 18, 1974
    Date of Patent: August 3, 1976
    Assignee: Monsanto Company
    Inventors: Russel D. Harken, F. Wyman Morgan
  • Patent number: 3970698
    Abstract: Hydroxy ether carboxylates represented by the formula ##EQU1## wherein M is alkali metal, ammonium, alkyl ammonium or alkanol ammonium and A is hydrogen, methyl, ethyl, or CH.sub.2 OH, are useful as complexing agents and detergency builders. The ester and acid forms of such compounds are useful as intermediates for preparation of the salts.
    Type: Grant
    Filed: December 19, 1973
    Date of Patent: July 20, 1976
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 3965169
    Abstract: Trisodium carboxymethyloxysuccinate monohydrate is useful as a metal complexing agent, detergency builder and desiccant.
    Type: Grant
    Filed: February 25, 1974
    Date of Patent: June 22, 1976
    Assignee: Monsanto Company
    Inventor: N. Earl Stahlheber
  • Patent number: 3954884
    Abstract: This invention relates to methods for rapidly producing beta hydroxy ethylene glycol ethers by reacting internal epoxyalkanes with mono or poly ethylene glycols in the presence of critical amounts of acidic catalysts under controlled temperature conditions.
    Type: Grant
    Filed: July 24, 1972
    Date of Patent: May 4, 1976
    Assignee: Monsanto Company
    Inventor: Roger L. Kidwell
  • Patent number: 3952054
    Abstract: Diglycolic acid is prepared by oxidation of p-dioxanone.
    Type: Grant
    Filed: December 5, 1974
    Date of Patent: April 20, 1976
    Assignee: Monsanto Company
    Inventor: Chung Y. Shen
  • Patent number: 3950388
    Abstract: Organic compounds having a substituent represented by the formula ##EQU1## wherein M is alkali metal or ammonium which are useful complexing agents for metal and/or alkaline earth metal ions are prepared by reaction of a conjugate base of a hemiketal of a ketomalonic acid diester and an alcohol with a bromo or iodo acetate ester and saponifying the resulting product.
    Type: Grant
    Filed: May 24, 1974
    Date of Patent: April 13, 1976
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 3940424
    Abstract: Compounds represented by the formula ##EQU1## and salts thereof represented by the formula ##EQU2## wherein Q is bromine, chlorine, --O-alkali metal or OH; R is hydrogen or an alkyl group containing from 1 to 20 carbon atoms; M is alkali metal; and Rx is ##EQU3## n being an integer from 4 to 10, or ##EQU4## Rz being hydrogen, alkyl phenyl alkyl, alkoxy alkyl, alkoxy phenyl, alkoxy phenyl alkyl or --COOX, X being R or M, are useful as intermediates for the preparation of sequestrants.
    Type: Grant
    Filed: December 19, 1973
    Date of Patent: February 24, 1976
    Assignee: Monsanto Company
    Inventor: Kent P. Lannert
  • Patent number: 3939262
    Abstract: Dental creams, particularly translucent dental creams, containing finely divided synthetic amorphous silica polishing agents, such polishing agents have an average refractive index of from about 1.410 to 1.440.
    Type: Grant
    Filed: January 21, 1974
    Date of Patent: February 17, 1976
    Assignee: Monsanto Company
    Inventor: Keun Y. Kim