Patents Represented by Attorney, Agent or Law Firm Thomas F. Roland
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Patent number: 7858165Abstract: The present invention relates to a multilayer tube comprising, in its radial direction from the outside inwards: an optional layer (1) made of nylon-11 or nylon-12 polyamide; an intermediate layer (2) comprising by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X, Y/Z or 6, Y2/Z, in which X denotes residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms, Z denotes at least one unit chosen from residues of a lactam, residues of an ?,?-aminocarboxylic acid, the unit X1, Y1, in which X1 denotes residues of a diamine and Y1 denotes residues of a diacid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%, and 0 to 50% of nylon-11 or nylon-12 polyamide; an optional layer (3) made of nylon-11 or nylon-12 polyamide, with the condition that at least one of the layers (1) and (3)Type: GrantFiled: April 28, 2006Date of Patent: December 28, 2010Assignee: Arkema FranceInventors: Nicolas Amouroux, Michaela Steng
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Patent number: 7833450Abstract: The present invention relates to the use of a microcrystalline polyamide for obtaining an object having all or part of its outer surface formed from this microcrystalline polyamide and having a particular surface finish, in which: the manufacture of the object comprises steps carried out hot between the Tg (glass transition temperature) and the Tm (melting point) of this microcrystalline polyamide; the transparency of the microcrystalline polyamide is such that the light transmission at 560 nm on a polished object 1 mm in thickness is greater than 80%, advantageously greater than 88%, the transparency being measured on the object obtained by standard processing methods, such as injection moulding and sheet extrusion/calendering.Type: GrantFiled: June 22, 2005Date of Patent: November 16, 2010Assignee: Arkema FranceInventors: Thibaut Montanari, Christelle Recoquille
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Patent number: 7815986Abstract: The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.Type: GrantFiled: June 18, 2008Date of Patent: October 19, 2010Assignee: Arkema Inc.Inventors: James T. Goldbach, Scott Gaboury, Robert J. Umpleby, Julien Parvole, David A. Mountz
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Patent number: 7811659Abstract: The invention relates to a high optical purity toughened copolymer film or coating. The copolymer is a graft or block copolymer, preferably acrylic, preferably produced by a controlled radical polymerization having an extremely low degree of particulate contamination and excellent optical properties. The film or coating is preferably formed by solvent-casting on a temporary substrate or solvent-coating on a permanent substrate.Type: GrantFiled: December 14, 2006Date of Patent: October 12, 2010Assignee: Arkema FranceInventors: Brian Edgecombe, Florence Mehlmann, Ryan Dirkx, Manuel Garcia
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Patent number: 7803891Abstract: The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.Type: GrantFiled: June 18, 2008Date of Patent: September 28, 2010Assignee: Arkema Inc.Inventors: James T. Goldbach, Robert J. Umpleby
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Patent number: 7803867Abstract: The invention relates to an aqueous-based fluoropolymer coating that is especially useful for use over flat or low-slope flexible surfaces, and more specifically for flat or low-slope roofing. The coating can be factory or field applied. The coating offers the advantages of improved durability, lower dirt pick-up, stain resistance, water repellency, increased solar reflectivity duration, and mildew resistance.Type: GrantFiled: April 13, 2006Date of Patent: September 28, 2010Assignee: Arkema Inc.Inventors: Kevin Hanrahan, Kurt Wood, Lotfi Hedhli, Ravi Gupta, Wayne Skilton
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Patent number: 7794806Abstract: A subject matter of the invention is a coextrusion tie, which comprises: 5 to 35% by weight of a polymer (A) itself composed of a blend of 80 to 20% by weight of a metallocene polyethylene (A1) with a density of between 0.863 and 0.915 and of 20 to 80% by weight of a non-metallocene LLDPE polyethylene (A2) with a density of between 0.900 and 0.950, the blend of polymers (A1) and (A2) being cografted; 95 to 65% by weight of metallocene polyethylene (B) homo- or copolymer, the comonomer of which comprises 3 to 20 carbon atoms, preferably 4 to 8 carbon atoms, the density of which is between 0.863 and 0.915 and the MFI of which is between 0.5 and 30, preferably between 3 and 15, g/10 min; the total forming 100%, the blend of (A) and (B) being such that its MFI is between 0.1 and 15, preferably between 1 and 13, g/10 min.Type: GrantFiled: September 26, 2003Date of Patent: September 14, 2010Assignee: Arkema FranceInventors: Jean-Laurent Pradel, Fabrice Chopinez, Damien Rauline, Patrice Robert
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Patent number: 7781529Abstract: The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.Type: GrantFiled: June 18, 2008Date of Patent: August 24, 2010Assignee: Arkema Inc.Inventors: James T. Goldbach, David A. Mountz
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Patent number: 7767757Abstract: The present invention relates to a thermoset material with improved impact resistance comprising, by weight: •99 to 20% of a thermoset resin, •1 to 80% of an impact modifier comprising at least one copolymer chosen from copolymers comprising A-B-C and A-B blocks, in which: each block is connected to the other by means of a covalent bond or of an intermediate molecule connected to one of the blocks via a covalent bond and to the other block via another covalent bond, A is a copolymer of methyl methacrylate and of at least one water-soluble monomer, C is either (i) a PMMA (homopolymer or copolymer) this PMMA comprising optionally a water-soluble monomer or (ii) a polymer based on vinyl monomers or mixture of vinyl monomers, B is incompatible or partially compatible with the thermoset resin and incompatible with the A block and the optional C block and its glass transition temperature Tg is less than the operating temperature of the thermoset material.Type: GrantFiled: January 18, 2006Date of Patent: August 3, 2010Assignee: Arkema FranceInventors: Olivier Guerret, Pierre Gerard, Jean-Pierre Pascault, Anthony Bonnet
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Patent number: 7750110Abstract: The invention relates to a composition, and structures having a layer made of said composition, in which the composition is, by weight, the total being 100%: 50 to 100% of at least one polyamide A1 of formula X.Y/Z or 6.Y2/Z in which: X denotes the residues of an aliphatic diamine having from 6 to 10 carbon atoms, Y denotes the residues of an aliphatic dicarboxylic acid having from 10 to 14 carbon atoms, Y2 denotes the residues of an aliphatic dicarboxylic acid having from 15 to 20 carbon atoms and Z denotes at least one unit chosen from the residues of a lactam, the residues of an ?,?-aminocarboxylic acid, the unit X1, Y1 in which X1 denotes the residues of an aliphatic diamine and Y1 denotes the residues of an aliphatic dicarboxylic acid, the weight ratios Z/(X+Y+Z) and Z/(6+Y2+Z) being between 0 and 15%; 0 to 40% of a plasticizer; 0 to 50% of an impact modifier; and 0 to 50% of a polyamide A2.Type: GrantFiled: October 5, 2005Date of Patent: July 6, 2010Assignee: Arkema FranceInventors: Philippe Blondel, Thibaut Montanari, Annett Linemann, Nicolas Amouroux, Henri Decraemer
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Patent number: 7750113Abstract: The invention relates to a supramolecular polymer containing units which are linked by hydrogen bonds, said units being monomers of prepolymers comprising at least one functional group selected from the functional groups (1) and (3) and a second functional group (5) wherein A denotes oxygen, sulphur or NH and X is any unit; the hydrogen bonds in the supramolecular polymer being formed between two identical or different functional groups chosen from the functional groups (1) to (5). The inventive polymers can be used alone, i.e. in the form of a composition which is essentially made from said polymers and, optionally, stabilizers, antioxidants, etc. or in the form of a mixture with other polymers or other products.Type: GrantFiled: March 19, 2008Date of Patent: July 6, 2010Assignee: Arkema FranceInventors: Francois-Genes Tournilhac, Corinne Soulie-Ziakovic, Ludwik Leibler, Laurent Lachaize
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Patent number: 7745535Abstract: The invention relates to an amphiphilic multiblock copolymer capable of forming non-covalent crosslinks. The non-water soluble copolymer, having a hydrophilic middle block and hydrophobic end blocks, has a high water transmission or permeation. The copolymer can be used in applications requiring absorption and/or transmission of fluids, the preferred fluids being water or hydrophilic liquids such as glycerin, glycols, and alcohols. One specific use of the amphiphilic multiblock copolymer is as a hydrogel material.Type: GrantFiled: July 21, 2006Date of Patent: June 29, 2010Assignee: Arkema Inc.Inventors: Scott Schmidt, Peter Callais, Noah Macy, Michael Mendolia
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Patent number: 7718740Abstract: The invention relates to a mixture comprising by weight, to give a total of 100%, 99-10% a polyamide block and polyether block copolymer (A) predominately consisting of lauryl lactam radicals, 1-99% at least on type of polymer (B) selected from polyamides other than polyamide 12, copolyamides which do not consist of the lauryl lactam radicals and the polyamide block and polyether block copolymers whose polyamide blocks do not predominantly consist of the lauryl lactam radicals. The articles, for example, films, foils, strings and tubes made from the inventive mixture are also disclosed.Type: GrantFiled: April 12, 2006Date of Patent: May 18, 2010Assignee: Arkema FranceInventors: Frederic Malet, Thibaut Montanari, Christophe Lacroix
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Patent number: 7717139Abstract: The present invention relates to polyamide/polyolefin blends containing carbon nanotubes. The invention also relates to structures comprising at least one layer of these blends and optionally at least one layer of another material. These structures may be in the form of bottles, tanks, containers, hoses, pipes and vessels of any kind. These structures may be manufactured using the standard techniques for thermoplastics, such as injection moulding, extrusion-blow moulding and coextrusion.Type: GrantFiled: February 18, 2004Date of Patent: May 18, 2010Assignee: Arkema FranceInventor: Benoit Brule
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Patent number: 7700700Abstract: This invention relates to a heterogeneous copolymer composition of polyvinylidene fluoride with one or more perfluoroalkyl ethers. These copolymers have excellent low temperature impact properties, while maintaining a high melting point.Type: GrantFiled: January 26, 2007Date of Patent: April 20, 2010Assignee: Arkema Inc.Inventors: Roice Wille, Gregory O'Brien
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Patent number: 7700124Abstract: The invention is a water/oil emulsion including a porous powder, the particles of the powder having the following characteristics: an apparent specific surface of 1 to 299 m2/g, measured by nitrogen absorption according to the ISO 9277 BET method; a linseed oil absorption of between 45 g/100 g of powder and 160 g/100 g of powder, measured according to ISO 787-5. The mean diameter of the particles of the powder is between 2 ?m and 100 ?m, preferably from 2 to 50 ?m, more advantageously still from 2 to 20 ?m. The powder is chosen from a powder formed of polyamides, of polyesteramides, of polyurethanes, of poly(methyl methacrylate)s, of acrylic polymers, of polyesters, of silicones, of polyethylenes and of silicas. The invention further relates to the use of the emulsion for obtaining a make-up and/or care product for the skin which is nonshiny, nonoily, nonsticky and/or nontacky, as well as the use of the fine powder for improving the feel and/or the appearance of a cosmetic emulsion.Type: GrantFiled: November 8, 2005Date of Patent: April 20, 2010Assignee: Arkema FranceInventors: Karine Loyen, Sophie Kohler
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Patent number: 7666946Abstract: The invention relates to a blend of one or more biopolymers with one or more acrylic copolymers, for the purpose of improving the properties of the biopolymer(s). The biopolymer composition comprises 85-99.9 weight percent of biopolymer(s) and 0.1 to 15 weight percent of one or more acrylic copolymers.Type: GrantFiled: December 14, 2006Date of Patent: February 23, 2010Assignee: Arkema Inc.Inventors: Jeffrey Brake, Sri Seshadri
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Patent number: 7651623Abstract: The present invention relates to a process for the removal of solvent from a polymer emulsion or suspension, by use of a decanter centrifuge (10). The decanter centrifuge (10) provides an efficient thickening method. The process is especially useful for emulsion or suspension polymer compositions having high levels of solvent (low polymer solids) that could benefit from a thickening or dewatering step prior to drying in a dryer (14).Type: GrantFiled: March 13, 2006Date of Patent: January 26, 2010Assignee: Arkema Inc.Inventor: Jeffrey Yen
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Patent number: 7649066Abstract: The present invention describes linear or star block copolymers, their process of preparation and their use in adhesive compositions, in particular as pressure-sensitive adhesive. The copolymers of the invention are prepared by controlled radical polymerization by nitroxides; they exhibit at least one soft block with a Tg of less than 0° C. and at least one hard block with a Tg of greater than ambient temperature.Type: GrantFiled: December 8, 2004Date of Patent: January 19, 2010Assignee: Arkema FranceInventors: Stéphanie Magnet, Olivier Guerret, Nicolas Passade Boupat, Christian Laurichesse, Nour Eddine El Bounia
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Patent number: 7642313Abstract: The invention relates to the use of inorganic fluoride compounds as fillers for use in fluoropolymers, such as polyvinylidene fluoride (PVDF) and its copolymers. The filled fluoropolymer is especially useful in articles where limited combustion and low smoke are required—such as in cables and conduits. The invention also relates to a filled PVDF as a means of lowering costs and improving performance properties in any application.Type: GrantFiled: June 21, 2005Date of Patent: January 5, 2010Assignee: Arkema Inc.Inventor: James Joseph Henry