Abstract: An apparatus and method are disclosed for automatically monitoring the sodium concentration of a sodium amalgam by means of a wet chemical analysis in which a mineral acid is reacted with a sample of the sodium amalgam to generate an amount of hydrogen gas proportional to the amount of sodium in the amalgam sampled. The amount of such hydrogen gas produced is detected and displayed in units of sodium concentration. A thermal conductivity detector is preferred as the means for determining the amount of hydrogen gas produced.
Type:
Grant
Filed:
April 28, 1980
Date of Patent:
April 27, 1982
Assignee:
Olin Corporation
Inventors:
Italo A. Capuano, Patricia A. Turley, Edward W. DuBord
Abstract: A process for electrically by-passing one of a series of electrolytic cells without interrupting current flow through the remaining cells is disclosed. The process includes inserting two conductors between the cells, remotely moving the conductors into pressurized contact with the cell preceding and the cell following the cell being disconnected and closing a switch to electrically connect the two conductors thereby by-passing the cell being disconnected.
Abstract: A method of varying the flow in a flow conduit from both the anolyte disengager and the catholyte disengager to each appropriately corresponding electrode is provided to selectively vary the flow rate of electrolyte fluids through the disengagers to the appropriate electrodes to thereby control the level of foaming of the electrolyte fluids within the disengagers to prevent the blowover of foam during the separation of entrained gas from the electrolyte fluids therein.
Type:
Grant
Filed:
January 21, 1981
Date of Patent:
March 30, 1982
Assignee:
Olin Corporation
Inventors:
David B. Wright, Sanders H. Moore, Morton S. Kircher
Abstract: Described are biodegradable surfactants useful as agricultural emulsifiers and having the formula: ##STR1## wherein R is a linear, alkyl hydrocarbon chain having an average from about 6 to about 10 carbon atoms; R' is a linear, alkyl hydrocarbon of 1 to about 4 carbon atoms; R" is a linear, alkyl hydrocarbon of from 1 to about 4 carbon atoms; x is an integer from about 8 to about 12; y is an integer from about 19 to about 25; and z is an integer from about 2 to 7.
Abstract: Disclosed are selected poly(oxyalkylated) hydrazines of the formula: ##STR1## wherein R is selected from hydrogen, lower alkyl groups having from 1 to 4 carbon atoms, phenyl and mixtures thereof; and the sum of w, x, y, and z is from about 4 to about 20. These compounds are shown to be effective corrosion inhibitors for hydraulic fluids.
Abstract: A remote controlled intercell connector bar jack is disclosed. The jack can have a first contactor and a second contactor spaced apart by a piston and cylinder assembly. The assembly can be remotely expanded or contracted to move the contactors away from each other or towards each other, respectively. The first contactor contacts a movable intercell connector while the second contactor contacts a fixed object such as the wall of one of two adjacent cells connected by the intercell connector. The second contactor can be a plate adapted to rest against a wall of a cell to which the intercell connector is attached and the first contactor adapted to rest against the intercell connector so that the intercell connector is jacked away from the cell wall when the assembly is remotely expanded.
Abstract: Disclosed is the use of aluminum tris(-O-ethyl phosphonate) as an ammonium nitrification inhibitor. This compound can be spread upon or mixed with the soil or applied with nitrogen-containing fertilizers to inhibit ammonium nitrification in the soil.
Abstract: An improved frame component for a frame of an electrode useful in a filter press cell having a channel or U-shaped configuration comprising an outer planar wall attached orthogonally to first and second planar side walls with a multiplicity of spaced rigid reinforcing members attached to first and second side walls.
Abstract: A novel electrode is disclosed for a filter press cell operating at medum pressure. This novel electrode comprises two vertical planar foraminous surfaces positioned in parallel and spaced apart, having at least one pair of conductor rods and a frame. The frame has two side members, a top member, and a bottom member, and is attached to the planar surfaces whereby a chamber is formed between the planar surfaces bounded by the frame. The foraminous surface has a tensile strength in the range from about 50 to about 300 pounds per lineal inch measured in the weakest direction of the foraminous surface. One conductor rod of each pair is attached to the frame along with one of the foraminous surfaces. At least one process connection for conveying process material into and out of the chamber is also provided in the frame.
Abstract: A method of assembling an electrolytic membrane cell is disclosed. The method includes the steps of assembling a vertical stack of horizontal electrode frames with a horizontal membrane sheet between each pair of frames, then applying pressure to vertically compress the vertical stack, then rotating the compressed vertical stack from a vertical orientation to a horizontal orientation in which orientation of the stack is called a "pack" and then connecting the pack into an electrical circuit and to raw material supply lines and product withdrawal lines and then electrically operating the pack while maintaining the pack in a horizontal orientation.
Abstract: A process for producing 2,6-dichloro-3-nitropyridine by reacting 2,6-dichloropyridine with nitric acid in the presence of about 10-65% strength by weight oleum.
Abstract: Disclosed are selected poly(oxyalkylated) 1,3,4-thiadiazoles of the formula: ##STR1## wherein each R is individually selected from hydrogen and methyl; and the sum of y and z is from 2 to about 30. These compounds are shown to be effective corrosion inhibitors in corrosive liquids such as acid metal-treating baths.
Abstract: Disclosed are selected poly(oxyalkylated) pyrazoles of the formula: ##STR1## wherein R and R' are independently selected from lower alkyl groups having 1 to 4 carbon atoms; each R" is individually selected from hydrogen and methyl; and n is from 2 to about 20. These compounds are shown to be effective corrosion inhibitors in corrosive liquids such as acids, antifreezes and hydraulic fluids.
Abstract: Disclosed is the use of selected N-(2,6-dimethylphenyl)-alanine methyl ester compounds as ammonium nitrification inhibitors. These compounds can be spread upon or mixed with the soil or applied with nitrogen-containing fertilizers to inhibit ammonium nitrification in the soil.
Abstract: Novel grease compositions are described which comprise:(a) A major amount of a shielded polysilicate compound selected from the group consisting of alkoxysilane cluster compounds, alkoxysilanol cluster compounds, alkoxysilane ester compounds, alkoxysilane multiple cluster compounds, silicone-bridged alkoxysilane double cluster compounds, distillation residues containing these compounds and mixtures thereof; and(b) an amount of at least one grease thickener sufficient to thicken said shielded polysilicate compound to a grease consistency.
Type:
Grant
Filed:
March 31, 1980
Date of Patent:
October 13, 1981
Assignee:
Olin Corporation
Inventors:
Karl O. Knollmueller, Robert J. Fairbrother, David F. Gavin
Abstract: An apparatus and method are disclosed for automatically monitoring the sodium concentration of a sodium amalgam by means of a wet chemical analysis in which a mineral acid is reacted with a sample of the sodium amalgam to generate an amount of hydrogen gas proportional to the amount of sodium in the amalgam sampled. The amount of such hydrogen gas produced is detected and displayed in units of sodium concentration. A thermal conductivity detector is preferred as the means for determining the amount of hydrogen gas produced.
Type:
Grant
Filed:
May 31, 1979
Date of Patent:
October 13, 1981
Assignee:
Olin Corporation
Inventors:
Italo A. Capuano, Patricia A. Turley, Edward W. DuBord
Abstract: Disclosed is the improvement to the Craig process for producing 2-bromopyridine by the diazotization-bromination reaction of 2-aminopyridine with HBr in the presence of Br.sub.2 and a diazotization agent wherein the improvement is to conduct the reaction in the additional presence of H.sub.2 SO.sub.4 and to employ a molar ratio of HBr:2-aminopyridine in the range from about 1:1 to about 3.5:1 and to employ a molar ratio of H.sub.2 SO.sub.4 :HBr in the range from about 2:8 to about 8:2.
Abstract: An intercell connector system is disclosed. The system includes two adjacent terminals attached to two adjacent cells and intercell connector selectively overlapping the adjacent ends of the terminals. The intercell connector includes a conductive first member and a second member which are held together by a fastening device which can be selectively loosened and tightened. When the fastening device is loosened, the two members are adapted to be moved out of engagement with one of the terminals thereby disconnecting the electrical circuit between the terminals.
Abstract: Disclosed is a process for producing a calcium sulfate product containing low amounts of radium comprising the steps of:(a) adding at least one sequestering agent to a substantially homogeneous radium-containing monocalcium phosphate (MCP) solution, the amount of the sequestering agent added being at least the stoichiometric amount necessary to complex with the radium in the MCP solution;(b) reacting the treated MCP solution with H.sub.2 SO.sub.4 to form a monocalcium phosphate/phosphoric acid solution, to precipitate a first calcium sulfate product, and to precipitate at least a portion of the radium, the amount of said H.sub.2 SO.sub.4 being up to about 50% of the stoichiometric amount necessary to react with the total CA.sup.++ present in the MCP solution;(c) separating the monocalcium phosphate/phosphoric acid solution from the radium-containing calcium sulfate precipitate;(d) then reacting the monocalcium phosphate/phosphoric acid solution with H.sub.2 SO.sub.