Abstract: Organic hydroperoxides are decomposed by drying a reaction mixture containing the organic hydroperoxide and an organic solvent such that said dried reaction mixture comprises approximately 1 weight percent or less of water and contacting the dried reaction mixture with a metal organic ligand catalyst under hydroperoxide decomposition conditions. An organic co-solvent for the hydroperoxide may also be used. Particularly effective catalysts are cobalt acetylacetonates and ruthenium acetylacetonates and combinations thereof.
Type:
Grant
Filed:
March 3, 1995
Date of Patent:
August 27, 1996
Assignee:
Sun Company, Inc. (R&M)
Inventors:
Manoj V. Bhinde, James E. Lyons, Paul E. Ellis, Jr.