Abstract: A process for removing nickel, cobalt, molybdenum, and vanadium from spent hydroprocessing catalyst particles by roasting the catalyst at between 400.degree. C. and 600.degree. C. and leaching the catalyst particles with an aqueous solution of ammonia and an ammonium salt.
Abstract: A method of recovering metal values from an aqueous stream. The metal values are preferably obtained from leaching spent hydroprocessing catalysts, and include nickel, cobalt, vanadium and molybdenum. The metal values are extracted, isolated and purified by liquid, liquid extraction techniques.
Abstract: An olefin oligomerization catalyst containing nickel sulfate on a porous support, activated by calcining in an oxidizing atmosphere, followed by inert gas treatment at a lower but elevated temperature, is useful for oligomerizing propylene and butenes.
Abstract: A crystalline silicaceous material, referred to as zeolite SSZ-19 or SSZ-19, having the characteristic X-ray diffraction lines of Table I is prepared with a reaction mixture containing an organic template component which can be a cycloalkyl trimethylammonium compound, a 1-azoniaspiroalkyl compound, a 1-azoniabicyclo [2.2.2] octane lower alkyl compound, or a 2,2-methyl lower alkyl trimethylammonium compound. The products are useful as catalysts and adsorbents.
Abstract: A crystalline zeolite, SSZ-16, is prepared from organic nitrogen-containing species derived from 1,4-di(1-azoniabicyclo[2.2.2]octane) lower alkane compounds.
Abstract: A highly efficient process for producing olefins using intermediate pore size zeolites is disclosed. The use of a specific range of silica:alumina mole ratios (175:1 to about 300:1) at pressure over 30 psia has been found to decrease catalyst deactivation rates for these intermediate pore size catalysts.
Abstract: A process for recovering the metal values from spent hydroprocessing catalyst particles. The metal values will include at least one metal of Group VIII of the Periodic Table and at least one metal of Group Vb or Group VIb of the Periodic Table. The spent catalyst particles are first roasted at between 400.degree. C. and 600.degree. C. and then contacted with a first aqueous solution of ammonia and an ammonium salt forming a first pregnant liquor. The once-leached spent hydroprocessing catalysts are contacted with a second aqueous solution of sulfur dioxide forming a second pregnant liquor. The metal values are precipitated from the second pregnant liquor with hydrogen sulfide and the precipitate is roasted with unroasted spent hydroprocessing catalysts. The metal values of Group Vb and Group VIb in the first pregnant liquor are transferred into a first organic solution by liquid ion exchange.
Abstract: Lubricating oils containing borated fatty acid esters of glycerol and a succinimide have been found to reduce fuel consumption in an internal combustion engine.
Abstract: The anti-wear properties of lubricating oil compositions containing overbased calcium sulfonate are improved when a metal diisopropyl dithiophosphate-succinimide complex is added to the oil. Oil compositions containing this combination are useful as crankcase lubricants.
Abstract: An olefin oligomerization catalyst containing nickel sulfate on a porous support, activated by calcining in an oxidizing atmosphere, followed by inert gas treatment at a lower but elevated temperature, is useful for oligomerizing propylene and butenes.
Abstract: Oil-insoluble zinc salts of cyclic dithiophosphates are rendered oil soluble when combined to form a complex with alkenyl or alkyl mono- or bis-succinimides. Oil compositions containing this combination are useful as crankcase lubricants.
Abstract: A method of recovering metal values from an aqueous stream. The metal valves are preferably obtained from leaching spent hydroprocessing catalysts, and include cobalt, nickel, molybdenum and vanadium. The metal values are extracted, isolated, and purified by liquid extraction techniques.
Abstract: Novel glycolate diesters of dithiophosphoric acid and salts of such esters suitable as additives in oil compositions are disclosed. Oil compositions containing the salts of such esters show improved extreme pressure/anti-wear and antioxidant properties.
Abstract: A desulfurizing and dewaxing process which can be performed in a single reaction vessel is disclosed.The desired lowering of oil partial pressure for dewaxing zone is accomplished by adding diluent gas to the HDS-zone effluent, thus obviating the need for other means to maintain differing oil partial pressures between serial catalyst zones.
Type:
Grant
Filed:
October 8, 1982
Date of Patent:
March 13, 1984
Assignee:
Chevron Research Company
Inventors:
Hazel C. Olbrich, Dennis J. O'Rear, John A. Zakarian
Abstract: A method of stripping an organic extraction solvent containing quaternary alkyl ammonium complexes. The extraction solvent is contacted with an aqueous stripping solution having at least 75 g/l bicarbonate ion, while maintained at between pH 7 and 9 at a temperature of no more than 50.degree. C.
Abstract: A method of recovering metal values from an aqueous stream. The metal values are preferably obtained from leaching spent hydroprocessing catalysts, and include nickel, cobalt, vanadium and molybdenum. The metal values are extracted, isolated and purified by liquid, liquid extraction techniques.
Abstract: A process for separating metal values from an aqueous stream containing vanadium, molybdenum, nickel and cobalt. Vanadium is first precipitated, and then nickel, cobalt, and molybdenum are removed by serial ion exchange.
Abstract: A process for enhancing recovery of cobalt from spent hydroprocessing catalysts when the spent catalyst particles are first roasted at between 400.degree. C. and 600.degree. C. and then contacted with a first aqueous solution of ammonia and an ammonium salt to recover nickel, cobalt, molybdenum and vanadium. The once-leached spent hydroprocessing catalysts are contacted with a second aqueous solution of sulfur dioxide. The metal values are precipitated with hydrogen sulfide and the precipitate is roasted with unroasted spent hydroprocessing catalysts.
Abstract: A continuous process is provided for the production of para alkyl phenols. In the process a mixture of phenol, olefin and strong organic acid, is reacted for a brief period of time. The resulting reaction mixture is quenched, and the para alkyl phenol recovered.